Iron oxide magnetic nanoparticle powder and method of producing the same, iron oxide magnetic nanoparticle thin film containing the iron oxide magnetic nanoparticle powder and method of producing the same

Patent metadata

Field	Value
Publication number	US-9916922-B2
Application number	US-201414787186-A
Country	US
Kind code	B2
Filing date	Apr 24, 2014
Priority date	Apr 26, 2013
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

There is provided an iron oxide magnetic nanoparticle powder having a ferromagnetic property even if the particles have an average particle size of 15 nm or less, preferably 10 nm or less, and a method of producing the same, an iron oxide magnetic nanoparticle thin film containing the iron oxide magnetic nanoparticle powder and a method of producing the same, wherein the iron oxide magnetic nanoparticles having an ε-Fe 2 O 3 single phase, having the average particle size of 15 nm or less, and further 10 nm or less, are generated by using β-FeO(OH) (iron oxide hydroxide) nanoparticles as a starting material, and coating the (iron oxide hydroxide) nanoparticles with silicon oxide, and applying heat treatment thereto under an atmospheric air, and further the iron oxide magnetic nanoparticle thin film is obtained by using the iron oxide magnetic nanoparticles.

First claim

The invention claimed is:

1. An iron oxide magnetic nanoparticle powder, containing iron oxide magnetic nanoparticles having ε-Fe 2 O 3 single phase, an average particle size from 5.2 nm to 10.6 nm, and a variation of the particle size from 1.7 nm to 3.3 nm.

2. The iron oxide magnetic nanoparticle powder according to claim 1 , wherein the ε-Fe 2 O 3 single phase does not contain a substituted element.

3. The iron oxide magnetic nanoparticle powder according to claim 1 , having a coercive force of 0.35 kOe or more.

4. The iron oxide magnetic nanoparticle powder of claim 1 , containing an iron oxide magnetic nanoparticle powder having α-Fe 2 O 3 phase and/or an iron oxide magnetic nanoparticle powder having γ-Fe 2 O 3 phase, in addition to the ε-Fe 2 O 3 single phase.

5. An iron oxide magnetic nanoparticle thin film containing the iron oxide magnetic nanoparticle powder of claim 1 .

6. The iron oxide magnetic nanoparticle thin film and according to claim 5 , further containing SiO 2 .

7. A method of producing an iron oxide magnetic nanoparticle powder having ε-Fe 2 O 3 single phase, an average particle size from 5.2 nm, to 10.6 nm, and a variation of the particle size from 1.7 nm to 3.3 nm,
wherein β-FeO(OH) nanoparticles are coated with silicon oxide, and thereafter the β-FeO(OH) nanoparticles coated with the silicon oxide are subjected to heat treatment in an oxidizing atmosphere.

8. The method of producing the iron oxide magnetic nanoparticle powder according to claim 7 , wherein an atmospheric air is used as the oxidizing atmosphere.

9. The method of producing the iron oxide magnetic nanoparticle powder according to claim 7 , wherein particles having an average particle size of 15 nm or less are used as the β-FeO(OH) nanoparticles.

10. A method of producing an iron oxide magnetic nanoparticle thin film containing iron oxide magnetic nanoparticles having an ε-Fe 2 O 3 single phase, an average particle size from 5.2 nm, to 10.6 nm, and a variation of the particle size from 1.7 nm to 3.3 nm,
wherein the iron oxide magnetic nanoparticle thin film is obtained by coating a surface of a substrate with a dispersion liquid containing β-FeO(OH) nanoparticles coated with silicon oxide, and thereafter applying heat treatment thereto in an oxidizing atmosphere.

11. The method of producing the iron oxide magnetic nanoparticle thin film according to claim 10 , wherein an atmospheric air is used as the oxidizing atmosphere.

Assignees

• Univ Tokyo
• Dowa Electronics Materials Co Ltd

Inventors

• Ohkoshi Shin-Ichi
• YOSHIKIYO Marie
• Namai Asuka
• Tokoro Hiroko
• TARORA Waka
• Yoshida Takayuki
• Tanaka Manabu

Classifications

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01G49/06 Primary

  Ferric oxide [Fe2O3] · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C01P2004/84

  one phase coated with the other · CPC title