Composition containing vinyl-group-containing compound

Patent metadata

Field	Value
Publication number	US-9914687-B2
Application number	US-201414780786-A
Country	US
Kind code	B2
Filing date	Mar 28, 2014
Priority date	Mar 29, 2013
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

First claim

The invention claimed is:

1. A composition comprising a vinyl-group-containing compound represented by the following general formula (1), and at least one other component selected from photopolymerization initiators, acid generating agents, base generating agents, and photopolymerizable monomers, which differs from the vinyl-group-containing compound represented by the general formula (1):

wherein W 1 and W 2 each independently represent a group represented by the following general formula (2), a group represented by the following general formula (4), or a hydroxyl group, provided that W 1 and W 2 do not simultaneously represent a hydroxyl group or the group represented by the following general formula (4); a ring Y 1 and a ring Y 2 , which may be the same or different, represent an aromatic hydrocarbon ring; R represents a single bond, an optionally substituted methylene group, an ethylene group that is optionally substituted and may contain a hetero atom between two carbon atoms, a group represented by —O—, a group represented by —NH—, or a group represented by —S—; R 3a and R 3b each independently represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 each independently represent an integer of 0 to 4,

wherein a ring Z represents a fused polycyclic aromatic hydrocarbon ring; X represents a single bond or a group represented by —S—; R 1 represents a single bond or an alkylene group having 1 to 4 carbon atoms; R 2 represents a monovalent hydrocarbon group, a hydroxyl group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a halogen atom, a nitro group, a cyano group, a mercapto group, a carboxyl group, an amino group, a carbamoyl group, a group represented by —NHR 4c , a group represented by —N(R 4d ) 2 , a (meth)acryloyloxy group, a sulfo group, or a group formed by substituting at least a part of hydrogen atoms bonded to carbon atoms contained in a monovalent hydrocarbon group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a group represented by —NHR 4c , or a group represented by —N(R 4d ) 2 with a monovalent hydrocarbon group, a hydroxyl group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a halogen atom, a nitro group, a cyano group, a mercapto group, a carboxyl group, an amino group, a carbamoyl group, a group represented by —NHR 4 , a group represented by —N(R 4d ) 2 , a (meth)acryloyloxy group, a mesyloxy group, or a sulfo group; R 4a to R 4d each independently represent a monovalent hydrocarbon group; and m is an integer of 0 or more, and

wherein a ring Z, X, R 1 , R 2 , and m are as defined above.

2. The composition according to claim 1 , wherein the ring Z is a naphthalene ring.

3. The composition according to claim 1 , wherein R 1 is a single bond.

4. A composition comprising a monovinyl-group- and mono(meth)acryloyloxy-group-containing compound represented by the following general formula (10), and at least one other component selected from photopolymerization initiators, acid generating agents, base generating agents, and photopolymerizable monomers, which differs from the compound represented by the general formula (10):

wherein any one of W 11 and W 12 represent a group represented by the following general formula (2) while the other represents a group represented by the following general formula (11) or (12); a ring Y 1 and a ring Y 2 , which may be the same or different, represent an aromatic hydrocarbon ring; R represents a single bond, an optionally substituted methylene group, an ethylene group that is optionally substituted and may contain a hetero atom between two carbon atoms, a group represented by —O—, a group represented by —NH—, or a group represented by —S—; R 3a and R 3b each independently represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; n1 and n2 each independently represent an integer of 0 to 4,

wherein a ring Z represents an aromatic hydrocarbon ring; X represents a single bond or a group represented by —S—; R 1 represents a single bond or an alkylene group having 1 to 4 carbon atoms; R 2 represents a monovalent hydrocarbon group, a hydroxyl group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a halogen atom, a nitro group, a cyano group, a mercapto group, a carboxyl group, an amino group, a carbamoyl group, a group represented by —NHR 4c , a group represented by —N(R 4d ) 2 , a (meth)acryloyloxy group, a sulfo group, or a group formed by substituting at least a part of hydrogen atoms bonded to carbon atoms contained in a monovalent hydrocarbon group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a group represented by —NHR 4c , or a group represented by —N(R 4d ) 2 with a monovalent hydrocarbon group, a hydroxyl group, a group represented by —OR 4a , a group represented by —SR 4b , an acyl group, an alkoxycarbonyl group, a halogen atom, a nitro group, a cyano group, a mercapto group, a carboxyl group, an amino group, a carbamoyl group, a group represented by —NHR 4c , a group represented by —N(R 4d ) 2 , a (meth)acryloyloxy group, a mesyloxy group, or a sulfo group; R 4a to R 4d each independently represent a monovalent hydrocarbon group; and m is an integer of 0 or more,

wherein R 5 represents a hydrogen atom or a methyl group; 1 represents an integer of 1 to 4; and a ring Z, X, R 1 , R 2 , and m are as defined above,

wherein a ring Z, X, R 1 , R 2 , R 5 , and m are as defined above.

5. The composition according to claim 4 , wherein the ring Z represents a benzene ring or a naphthalene ring.

6. The composition according to claim 4 , wherein R 1 represents a single bond.

7. A composition comprising a (meth)acryloyloxy-group-containing compound represented by the following general formula (19), and at least one other component selected from photopolymerization initiators, acid generating agents, base generating agents, and photopolymerizable monomers which differs from the compound represented by the general formula (19):

wherein W 13 and W 14 each independently represent a group represented by the following general formula (12), a hydroxyl group, or a (meth)acryloyloxy group, provided that at least one of W 13 and W 14 represents a group represented by the following general formula (12); a ring Y 1 and a ring Y 2 , which may be the same or different, represent an aromatic hydrocarbon ring; R represents a single bond, an optionally substituted methylene group, an ethylene group that is optionally substituted and may contain a hetero atom between two carbon atoms, a group represented by —O—, a group represented by —NH—, or a group represented by —S—; R 3a and R 3b each independently represent a cyano group, a halogen atom, or a m

Assignees

• Tokyo Ohka Kogyo Co Ltd

Inventors

• Shiota Dai
• Noda Kunihiro
• Chisaka Hiroki

Classifications

• C07C69/54

  Acrylic acid esters; Methacrylic acid esters · CPC title

• C08F16/12 Primary

  by an ether radical · CPC title

• C07C43/225

  containing halogen · CPC title

• G03F7/0045

  with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors · CPC title

• G03F7/027

  Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds (G03F7/075 takes precedence) · CPC title