Inflatable object provided with a gas-tight layer containing a thermoplastic elastomer and a hydrocarbon-based resin

Patent metadata

Field	Value
Publication number	US-9914328-B2
Application number	US-201113640974-A
Country	US
Kind code	B2
Filing date	Apr 14, 2011
Priority date	Apr 21, 2010
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

A pneumatic object is provided with a layer that is airtight to inflation gases. The layer includes an elastomer composition having at least a thermoplastic elastomer (TPE), as a sole elastomer or as a predominant elastomer by weight, and a hydrocarbon resin. A glass transition temperature of the hydrocarbon resin is above 0° C. The TPE is a copolymer that includes at least a central polyisobutylene block. Optionally, the elastomer composition includes an extender oil. Also optionally, the elastomer composition includes a platy filler selected from a group that includes graphites and phyllosilicates, such as micas, clays, and talcs. The pneumatic object may be an inner tube or a pneumatic tyre for a motor vehicle.

First claim

The invention claimed is:

1. A pneumatic object comprising an elastomer layer airtight to inflation gases, wherein the elastomer layer includes:
as a sole elastomer, or as a predominant elastomer by weight, at least one thermoplastic elastomer (TPE), the TPE being a block copolymer that includes at least a central polyisobutylene block,
5 to 75 phr of an extender oil, the extender oil being selected from the group consisting of polyolefin oils, paraffinic oils, naphthenic oils, aromatic oils, mineral oils, and mixtures thereof, and
15 to 70 phr of a hydrocarbon resin having a glass transition temperature above 10° C., a softening point above 50° C., a number-average molecular weight between 200 and 3000 g/mol, and a polydispersity index less than or equal to 4.

2. The pneumatic object according to claim 1 , wherein the softening point of the hydrocarbon resin is from above 50° C. to 160° C.

3. The pneumatic object according to claim 1 , wherein a number-average molecular weight of the block copolymer is between 30,000 and 500,000 g/mol.

4. The pneumatic object according to claim 1 , wherein the block copolymer includes a block selected from the group consisting of polystyrene; polymethylstyrenes; poly(para-tert-butylstyrene); polychlorostyrenes; polybromostyrenes; polyfluorostyrenes; poly(para-hydroxystyrene); poly-acenaphthylene; polyindene; poly(2-methylindene); poly(3-methylindene); poly(4-methylindene); polydimethylindenes; poly(2-phenylindene); poly(3-phenylindene); poly(4-phenylindene); polyisoprene; polymers of esters of acrylic acid, crotonic acid, sorbic acid, and methacrylic acid; and polymers of derivatives of acrylamide, methacrylamide, acrylonitrile, and methacrylonitrile.

5. The pneumatic object according to claim 4 , wherein the block copolymer includes a block selected from the group consisting of polystyrene; polymethylstyrenes; poly(para-tert-butyl styrene); polychlorostyrenes; polybromostyrenes; polyfluorostyrenes; and poly(para-hydroxystyrene).

6. The pneumatic object according to claim 5 , wherein the block copolymer is a styrene/isobutylene/styrene copolymer.

7. The pneumatic object according to claim 6 , wherein the block copolymer includes between 5% and 50% by weight of styrene.

8. The pneumatic object according to claim 4 , wherein the block copolymer includes a block selected from the group consisting of polyacenaphthylene; polyindene; poly(2-methylindene); poly(3-methylindene); poly(4-methylindene); polydimethylindenes; poly(2-phenylindene); poly(3-phenylindene); poly(4-phenylindene); polyisoprene; polymers of esters of acrylic acid, crotonic acid, sorbic acid, and methacrylic acid; and polymers of derivatives of acrylamide, methacrylamide, acrylonitrile, and methacrylonitrile.

9. The pneumatic object according to claim 1 , wherein a glass transition temperature of the block copolymer is below −20° C.

10. The pneumatic object according to claim 9 , wherein the glass transition temperature of the block copolymer is below −40° C.

11. The pneumatic object according to claim 1 , wherein the extender oil is selected from a group that includes polybutene oils.

12. The pneumatic object according to claim 11 , wherein the extender oil is a polyisobutylene oil.

13. The pneumatic object according to claim 1 , wherein a number-average molecular weight of the extender oil is between 200 and 25,000 g/mol.

14. The pneumatic object according to claim 1 , further comprising a platy filler.

15. The pneumatic object according to claim 14 , wherein the platy filler is present in an amount of from 2% to 50% by volume.

16. The pneumatic object according to claim 14 , wherein the platy filler is selected from the group consisting of graphites; phyllosilicates; and mixtures thereof.

17. The pneumatic object according to claim 16 , wherein the platy filler is selected from the group consisting of graphites; talcs; micas; and mixtures thereof.

18. The pneumatic object according to claim 1 , wherein the elastomer layer has a thickness greater than 0.05 mm.

19. The pneumatic object according to claim 18 , wherein the elastomer layer has a thickness between 0.1 mm and 10 mm.

20. The pneumatic object according to claim 1 , wherein the elastomer layer is positioned on an inner wall of the pneumatic object.

21. The pneumatic object according to claim 1 , wherein the pneumatic object is at least partially formed of rubber.

22. The pneumatic object according to claim 21 , wherein the pneumatic object is a pneumatic tire.

23. The pneumatic object according to claim 1 , wherein the pneumatic object is an inner tube.

24. The pneumatic object according to claim 23 , wherein the inner tube is a pneumatic tire inner tube.

Assignees

• Abad Vincent
• Greiveldinger Marc
• Michelin & Cie

Inventors

• Abad Vincent
• Greiveldinger Marc

Classifications

• C08L2207/322

  Liquid component is processing oil · CPC title

• C08K5/01

  Hydrocarbons {(C08K5/0091 takes precedence)} · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• B60C5/14

  with impervious liner or coating on the inner wall of the tyre · CPC title

• C08L23/22

  Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins · CPC title