Process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution

Patent metadata

Field	Value
Publication number	US-9914112-B2
Application number	US-201515112445-A
Country	US
Kind code	B2
Filing date	Jan 14, 2015
Priority date	Jan 24, 2014
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase in a reactor comprising a gas distributor ( 3 ), a reaction zone ( 5 ) and a fluidized bed ( 27 ), the gas leaving the reactor is treated in a condenser column ( 12 ) with an aqueous solution, the treated gas leaving the condenser column ( 12 ) is recycled at least partly to the fluidized bed ( 27 ), wherein the gas leaving the condenser column ( 12 ) comprises from 0.05 to 0.3 kg steam per kg dry gas and the steam content of the gas entering the gas distributor ( 3 ) is less than 80% of the steam content of the gas leaving the condenser column ( 12 ).

First claim

The invention claimed is:

1. A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and may be at least partly neutralized,
b) optionally one or more crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a),
e) optionally one or more water-soluble polymer, and
f) water,
in a surrounding heated gas phase in a reactor comprising a gas distributor ( 3 ), a reaction zone ( 5 ), and a fluidized bed ( 27 ), gas leaving the reactor is treated in a condenser column ( 12 ) with an aqueous solution, the treated gas leaving the condenser column ( 12 ) is recycled at least partly to the fluidized bed ( 27 ), wherein the treated gas leaving the condenser column ( 12 ) comprises from 0.05 to 0.3 kg steam per kg dry gas and a steam content of a drying gas entering the gas distributor ( 3 ) is less than 80% of the steam content of the treated gas leaving the condenser column ( 12 ).

2. A process according to claim 1 , wherein the treated gas leaving the condenser column ( 12 ) comprises from 0.09 to 0.15 kg steam per kg dry gas.

3. A process according to claim 1 , wherein the steam content of the drying gas entering the gas distributor ( 3 ) is less than 50% of the steam content of the treated gas leaving the condenser column ( 12 ).

4. A process according to claim 1 , wherein the treated gas leaving the condenser column ( 12 ) is recycled at least partly to the gas distributor ( 3 ) and the treated gas leaving the condenser column ( 12 ) that is recycled at least partly to the gas distributor ( 3 ) is further treated in a gas drying unit ( 37 ).

5. A process according to claim 4 , wherein the gas drying unit ( 37 ) comprises a gas cooler and a demister.

6. A process according claim 5 , wherein the temperature of the gas leaving the gas drying unit ( 37 ) is less than 45° C.

7. A process according claim 6 , wherein the temperature of the treated gas leaving the condenser column ( 12 ) is at least 45° C.

8. A process according to claim 1 , wherein the gas velocity inside the reaction zone ( 5 ) is from 0.5 to 1.2 m/s.

9. A process according to claim 1 , wherein temperature of the gas leaving the reaction zone ( 5 ) is from 110 to 120° C.

10. A process according to claim 1 , wherein the residence time of the water-absorbent polymer particles in the fluidized ( 27 ) bed is from 120 to 240 minutes.

11. A process according to claim 1 , wherein the gas velocity inside the fluidized bed ( 27 ) is from 0.5 to 1.5 m/s.

12. A process according to claim 1 , wherein temperature of the water-absorbent polymer particles in the fluidized bed ( 27 ) is from 60 to 100° C.

13. A process according to claim 1 , wherein the ethylenically unsaturated monomer which bears acid groups is an ethylenically unsaturated carboxylic acid.

14. A process according to claim 1 , wherein the formed water-absorbent polymer particles have a centrifuge retention capacity of at least 15 g/g.

15. A process according to claim 1 , wherein the gas is treated in the condenser column ( 12 ) with caustic.

16. A process according to claim 1 , wherein the liquid effluent of the condenser column ( 12 ) is recycled for preparing the monomer solution.

Assignees

• Basf Se

Inventors

• Bauer Stephan
• Herfert Norbert
• Freiberg Jürgen
• Schliwa Rudolf
• Possemiers Karl J
• Bayer Robert

Classifications

• B01J20/267 Primary

  Cross-linked polymers · CPC title

• C08L101/14

  the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels · CPC title

• B01J20/3085

  Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title

• C08L33/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title