Process for operating a simulated moving bed reactor

Patent metadata

Field	Value
Publication number	US-9914072-B2
Application number	US-201515316542-A
Country	US
Kind code	B2
Filing date	Jun 4, 2015
Priority date	Jun 6, 2014
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

The present disclosure provides for a process for supplying a first reactant and a second reactant (reactants) to a simulated moving bed reactor (SMBR) at each step of a sequential repeating injection cycle, where the SMBR includes zones each having an injection point and each containing a solid separation media; reacting the reactants in the SMBR during the sequential repeating injection cycle (cycle) to form a first product; separating the first product in the SMBR with the solid separation media; and changing an amount of one or both of the reactants injected at one or more of the injection points of the SMBR during a step of the cycle. Changing the amount of the reactants can be done at each step of the sequential repeating injection cycle. Changing the amount can include changing an inlet concentration of the reactants injected at one or more of the injection points during each step of the cycle.

First claim

We claim:

1. A process, comprising:
supplying a first reactant and a second reactant to a simulated moving bed reactor (SMBR) at each step of a sequential repeating injection cycle, where the SMBR includes zones each having an injection point and each containing a solid separation media;
reacting the first reactant and the second reactant in the SMBR during the sequential repeating injection cycle to form a first product;
separating the first product in the SMBR with the solid separation media; and
changing an amount of one or both of the first reactant and the second reactant injected at one or more of the injection points of the SMBR during a step of the sequential repeating injection cycle.

2. The process of claim 1 , where changing the amount of one or both of the first reactant and the second reactant is done at each step of the sequential repeating injection cycle.

3. The process of claim 1 , where each step of the sequential repeating injection cycle has a predetermined time (t step ), and where changing the amount of one or both of the first reactant and the second reactant begins once a first percentage of t step is reached.

4. The process of claim 3 , where the first percentage of t step is from 50 percent (%) to less than 100% of t step .

5. The process of claim 3 , where the first percentage of t step is from 65% to 67% of t step .

6. The process of claim 1 , where the amount of the first reactant is zero (0) relative a total amount of the first reactant and the second reactant injected at one or more of the injection points of the SMBR.

7. The process of claim 1 , where the amount of the first reactant is 100% relative a total amount of the first reactant and the second reactant injected at one or more of the injection points of the SMBR.

8. The process of claim 1 , where changing the amount of one or both of the first reactant and the second reactant is done two or more times during a step of the sequential repeating injection cycle.

9. The process of claim 1 , where changing the amount of one or both of the first reactant and the second reactant is done as a step change.

10. The process of claim 1 , where changing the amount of one or both of the first reactant and the second reactant is done as a linear change.

11. The process of claim 1 , where changing the amount includes changing an inlet concentration of one or more of the first reactant and the second reactant injected at one or more of the injection points of the SMBR during each step of the sequential repeating injection cycle.

12. The process of claim 1 , where supplying the first reactant to the SMBR includes supplying the first reactant to the SMBR at a stoichiometric excess sufficiently large that the first reactant acts as a desorbent for both a raffinate stream and an extract stream of the SMBR.

13. The process of claim 12 , including reacting the second reactant in a stoichiometric deficit relative to the first reactant to extinction in the SMBR.

14. The process of claim 1 , including supplying a portion of at least one of the raffinate steam and the extract stream to at least one of the zones of the SMBR.

15. The process of claim 1 , where the solid separation media also acts as a catalyst for the reaction of the first reactant and the second reactant.

16. The process of claim 1 , where reacting the first reactant and the second reactant in the SMBR during the sequential repeating injection cycle forms the first product and a second product; and
where separating the first product in the SMBR with the solid separation media further includes separating the first product from the second product in the SMBR with the solid separation media.

Assignees

• Georgia Tech Res Inst

Inventors

• Kawajiri Yoshiaki
• Bommarius Andreas S
• Oh Jungmin
• Agrawal Gaurav
• Sreedhar Balamurali

Classifications

• C07C67/08

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• B01D15/1857 Primary

  Reactive simulated moving beds · CPC title

• C07C67/56

  by solid-liquid treatment; by chemisorption · CPC title

• C07C69/14

  of monohydroxylic compounds · CPC title