Resin composition for sealing organic electroluminescent element, sealing film for organic electroluminescent element, gas-barrier film for organic electroluminescent element, and organic electroluminescent element using these films

Patent metadata

Field	Value
Publication number	US-9913324-B2
Application number	US-201414566961-A
Country	US
Kind code	B2
Filing date	Dec 11, 2014
Priority date	Jun 15, 2012
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

A resin composition for sealing an organic electroluminescent element, containing: at least one epoxy compound; at least one polyester resin; and at least one Lewis acid compound or at least one compound which generates a Lewis acid, in which the content of the epoxy compound is from 10 to 200 parts by mass with respect to 100 parts by mass of the polyester resin.

First claim

The invention claimed is:

1. A resin composition for sealing an organic electroluminescent element, comprising:
at least one epoxy compound;
at least one polyester resin, which is a polyester resin compound having a cyclohexyl skeleton and no aromatic ring; and
at least one Lewis acid compound or at least one compound which generates a Lewis acid,
wherein the content of epoxy compound is from 10 to 200 parts by mass with respect to 100 parts by mass of polyester resin.

2. The resin composition for sealing the organic electroluminescent element according to claim 1 ,
wherein at least one of the epoxy compound is an epoxy compound having a cyclohexyl skeleton and no aromatic ring.

3. The resin composition for sealing the organic electroluminescent element according to claim 1 ,
wherein the Lewis acid compound is a boron trifluoride complex.

4. The resin composition for sealing the organic electroluminescent element according to claim 1 , satisfying:
E′ C <2,000 MPa and E′ B ×5≦ E′ B

wherein E′ B is a storage elastic modulus at room temperature in the B stage state of the resin composition for sealing the organic electroluminescent element (the partially cured state in which the resin composition containing the epoxy compound retains 80% or greater of calorific value in a differential scanning calorimetry), and E′ C is a storage elastic modulus at room temperature in the state after heat at 80° C. for 3 hours from the B stage state.

5. The resin composition for sealing the organic electroluminescent element according to claim 1 ,
wherein the resin composition for sealing the organic electroluminescent element in a B stage state has a glass transition temperature of 40° C. or higher.

6. The resin composition for sealing the organic electroluminescent element according to claim 1 ,
wherein a 40 μm-thick film prepared by curing the resin composition for sealing the organic electroluminescent element has a total luminous transmittance is 95% or greater.

7. The resin composition for sealing the organic electroluminescent element according to claim 1 , comprising at least one drying agent.

8. A sealing film for an organic electroluminescent element prepared from the resin composition according to claim 1 .

9. An organic electroluminescent element sealed with the sealing film for an organic electroluminescent element prepared from the resin composition according to claim 8 .

10. A gas-barrier film for an organic electroluminescent element having a laminate structure composed of at least two or more layers,
wherein at least one layer of the laminate structure is a resin layer prepared from the resin composition for sealing the organic electroluminescent element according to claim 1 and the other at least one layer of the laminate structure comprises a transparent plastics.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Mihara Naoaki
• Ishiguro Kunihiko
• Nakamura Toshimitsu
• Mieda Tetsuya

Classifications

• C08J2463/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• H10K50/844

  Encapsulations · CPC title

• C08L67/02 Primary

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title