Carbon nanotube-sulfur composite comprising carbon nanotube aggregates, and method for preparing same

Patent metadata

Field	Value
Publication number	US-9911975-B2
Application number	US-201415029911-A
Country	US
Kind code	B2
Filing date	Oct 8, 2014
Priority date	Oct 18, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

The present application relates to a carbon nanotube-sulfur composite including a carbon nanotube aggregate, and a method for preparing the same.

First claim

The invention claimed is:

1. A positive electrode, comprising:
(1) a current collector; and (2) a mixture applied to the current collector; said mixture comprising:
(a) a carbon nanotube-sulfur composite comprising:
a carbon nanotube aggregate; and
sulfur or a sulfur compound positioned on an external surface and in an inside of the carbon nanotube aggregate,
wherein a tap density of the carbon nanotube aggregate is 0.27 g/cc or more and 1 g/cc or less; and
(b) a binder,
wherein the carbon nanotube-sulfur composite is attached to the current collector through the binder, and
wherein the carbon nanotube aggregate has a porosity of 10% or more and 70% or less based on a total volume of the aggregate, said porosity is achieved by including a metal catalyst or a metal oxide catalyst in a content of 0.1 wt % or more and 10 wt % or less based on the total weight of the carbon nanotube aggregate.

2. The positive electrode of claim 1 , wherein sulfur or the sulfur compound is positioned in a region of less than 100% of the entire external surface of the carbon nanotube aggregate.

3. The positive electrode of claim 1 , wherein in the carbon nanotube-sulfur composite, a content ratio of the carbon nanotube aggregate and sulfur or the sulfur compound is 10 to 50:50 to 90 based on wt %.

4. The positive electrode of claim 1 , wherein a diameter of the carbon nanotube aggregate is 500 micrometers or less.

5. A lithium-sulfur battery comprising:
a positive electrode for a lithium-sulfur battery according to claim 1 ;
a negative electrode; and
a separation membrane positioned between the positive electrode and the negative electrode.

6. The positive electrode of claim 1 , wherein the metal catalyst is at least one selected from the group consisting of Fe, Ni, Co, Cr, Ni/Ti, Co/Ti and Fe/Ti, and wherein the metal oxide catalyst is at least one selected from the group consisting of Fe 2 O 3 , Al 2 O 3 , and CuO.

7. A method for preparing a carbon nanotube-sulfur composite, comprising:
impregnating sulfur or a sulfur compound on an external surface and in an inside of a carbon nanotube aggregate,
wherein the impregnating of sulfur or the sulfur compound is performed by mixing the carbon nanotube aggregate and sulfur or sulfur compound powder to form a mixture, and then heating the mixture to impregnate molten sulfur or sulfur compound in the carbon nanotube aggregate,
wherein a heating temperature is 115° C. or more and 180° C. or less, and
wherein a tap density of the carbon nanotube aggregate is 0.01 g/cc or more and 1 g/cc or less.

8. The method of claim 7 , wherein sulfur or the sulfur compound is positioned in a region of less than 100% of the entire external surface of the carbon nanotube aggregate.

9. The method of claim 7 , further comprising:
adjusting a size of a diameter of the carbon nanotube aggregate to 50 micrometers or less before, after, or before and after the impregnating of sulfur or the sulfur compound.

10. The method of claim 9 , wherein in the adjusting of the size, the diameter of the carbon nanotube aggregate is adjusted to 1 micrometer or more and 10 micrometers or less.

11. The method of claim 9 , wherein the adjusting of the size is performed by using a dry ball mill method, a dry jet mill method, or a dry Dyno mill method.

12. The method of claim 9 , wherein after the adjusting of the size, the carbon nanotube aggregate has a porosity of 10% or more and 70% or less based on a total volume of the aggregate.

13. The method of claim 7 , wherein a content ratio of the carbon nanotube aggregate and sulfur or the sulfur compound is 10 to 50:50 to 90 based on wt %.

14. The method of claim 7 , wherein the mixture is formed by dissolving sulfur or the sulfur compound in an organic solvent, and then adding the carbon nanotube aggregate to grow sulfur or the sulfur compound.

15. The method of claim 7 , wherein the mixture is formed by mixing the carbon nanotube aggregate and sulfur or sulfur compound powder, and then performing impregnating by a ball mill method.

16. The method of claim 7 , further comprising:
preparing the carbon nanotube aggregate (S 01 ) before the impregnating of sulfur or the sulfur compound,
wherein the preparing of the carbon nanotube aggregate (S 01 ) includes preparing a carbon nanotube, and in the preparing of the carbon nanotube, a catalyst amount is 0.1% to 10% based on a total weight of the generated carbon nanotube.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Min Seo
• Lee Seong Ho
• Jang Minchul
• Sung Da Young

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/133 Primary

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/043

  involving compressing or compaction · CPC title

• H01M10/052

  Li-accumulators · CPC title