Lithium ion batteries

Patent metadata

Field	Value
Publication number	US-9911970-B2
Application number	US-201414899779-A
Country	US
Kind code	B2
Filing date	Jun 26, 2014
Priority date	Jul 9, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

An improved method of making a cathode for use in a lithium ion battery is comprised of mixing a lithium metal oxide and lithium metal phosphate in a solvent, where both of these are comprised of primary particles that have been agglomerated into secondary particles of particular size and mixing is insufficient to break up the particles of the lithium metal phosphate, coating the mixture of step (A) on to a metal foil and removing the solvent to form the cathode. The lithium metal oxide is also desirably not broken either. The cathode may be one that has lithium metal oxide and a particular lithium metal phosphate wherein the majority of the metal is Mn.

First claim

The invention claimed is:

1. A method of forming a cathode comprising:
(a) mixing a lithium metal oxide and lithium metal phosphate in a solvent, wherein (i) the lithium metal phosphate has a D50 secondary particle size by number of 2 micrometers to 30 micrometers and a D50 primary particle size by number that is 25 to 1000 nanometers, (ii) the lithium metal oxide has a secondary particle size having a D50 by number of 2 to 30 micrometers and, (iii) the mixing is insufficient to break up the secondary particles of the lithium metal phosphate,
(b) coating the mixture of step (A) on to a metal foil; and
(c) removing the solvent to form the cathode wherein the lithium metal phosphate primary particles are soft bonded within the secondary particles and the lithium metal oxide secondary particles are at least partially hard bonded.

2. The method of claim 1 , further comprising pressing the cathode after removing the solvent.

3. The method of claim 2 , wherein the pressing is performed at a pressure insufficient to deform or break the lithium metal oxide secondary particles, but sufficient to deform the lithium metal phosphate secondary particles.

4. The method of claim 3 , wherein the pressing is performed at a pressure from 10 MPa to 250 MPa.

5. The method of claim 4 , wherein the lithium metal oxide has an average sphericity from 0.4 to 1.0 and the lithium metal phosphate has an average sphericity from 0.4 to 1.0.

6. The method of claim 5 , wherein the average sphericity of the lithium metal oxide to the average sphericity of the lithium metal phosphate has a ratio that is 0.4 to 2.5.

7. The method of claim 1 , wherein the mixing has a shear rate of at most 5000 sec-1.

8. The method of claim 1 , wherein the lithium metal oxide has a D50 primary particle size of 3 micrometers to 0.1 micrometers.

9. The method of claim 1 , wherein the D50 secondary particle size of the lithium metal phosphate to the D50 secondary particle size of the lithium metal oxide has a ratio that is 0.25 to 1.5.

10. The method of claim 6 , wherein the ratio is 0.5 to 1.5.

Assignees

• Dow Global Technologies Llc

Inventors

• Theivanayagam Murali G
• Hu Ing Feng
• Maeda Hideaki
• Lin Jui Ching

Classifications

• H01M4/1397

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title