Partially degradable particulates as time-released tracers for acidized and fractured gas wells
US-2024209729-A1 · Jun 27, 2024 · US
US9909403B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9909403-B2 |
| Application number | US-201314912309-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 20, 2013 |
| Priority date | Sep 20, 2013 |
| Publication date | Mar 6, 2018 |
| Grant date | Mar 6, 2018 |
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Fracturing methods include introducing a relatively high concentration of a surfactant in an initial portion of one or more fluids used in a fracturing treatment and then cutting or ramping back to a relatively low concentration of the surfactant in the remaining fluid used in the treatment. By using such a method, the volume of surfactant to provide superior treatment can be reduced significantly from the normal recommendations, leading to a high cost savings while still obtaining the desired effect upon cleanup.
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What is claimed is: 1. A method of fracturing a treatment zone of a subterranean formation penetrated by a well, the method comprising: (A) determining an adsorption coefficient for a surfactant on an exposed surface area in the treatment zone; (B) simulating fracturing of the treatment zone to estimate a total exposed surface area for a fracture in the treatment zone; (C) calculating a first amount of the surfactant to be adsorbed into the treatment zone; (D) continuously introducing a water-based fluid comprising the surfactant at a first surfactant concentration into the treatment zone during a fluid introduction time period at a sufficient rate and pressure to create or extend a fracture in the subterranean formation; and (E) once the first amount of the surfactant has been introduced into the treatment zone, decreasing the concentration of the surfactant in the fluid from the first surfactant concentration to a second surfactant concentration while continuously introducing the fluid into the treatment zone during the fluid introduction time period. 2. The method according to claim 1 , wherein the concentration of the surfactant is decreased from the first surfactant concentration to the second surfactant concentration continuously over at least a portion of the fluid introduction time period. 3. The method according to claim 1 , wherein the concentration of the surfactant is decreased from the first surfactant concentration to the second surfactant concentration at a variable rate over at least a portion of the fluid introduction time period. 4. The method according to claim 1 , wherein the first surfactant concentration and the second surfactant concentration are selected to minimize the total amount of the surfactant introduced into the treatment zone. 5. The method according to claim 1 , wherein the fluid additionally comprises: a polymeric viscosity-increasing agent, wherein the polymeric viscosity-increasing agent is water-soluble or water-hydratable. 6. The method according to claim 5 , wherein the fluid additionally comprises: a crosslinker for the polymeric viscosity-increasing agent. 7. The method according to claim 1 , wherein the fluid additionally comprises: a proppant. 8. A method of fracturing a treatment zone of a subterranean formation penetrated by a well, the method comprising: (A) determining an adsorption coefficient for a surfactant on an exposed surface area in the treatment zone; (B) simulating fracturing of the treatment zone to estimate a total exposed surface area for a fracture in the treatment zone; (C) calculating a first amount of the surfactant to be adsorbed into the treatment zone; (D) introducing a first water-based fluid comprising a first concentration of the surfactant into the treatment zone for a first fluid introduction time period, at least the first amount of the surfactant to be adsorbed into the treatment zone is introduced into the treatment zone during the first fluid introduction time period; and (E) immediately after the first fluid introduction time period, introducing a second water-based fluid comprising a second concentration of the surfactant into the treatment zone at a sufficient rate and pressure to create or extend a fracture in the subterranean formation, wherein the second concentration of the surfactant in the second fluid is lower than the first concentration of the surfactant in the first fluid. 9. The method according to claim 8 , wherein the first concentration and the second concentration are selected to minimize the total amount of the surfactant introduced into the treatment zone. 10. The method according to claim 8 , wherein the introducing of the first fluid is below a sufficient rate and pressure to create or extend a fracture in the subterranean formation. 11. The method according to claim 8 , wherein the introducing of the first fluid is at least at a sufficient rate and pressure to create or extend a fracture in the subterranean formation. 12. The method according to claim 8 , wherein the first fluid or the second fluid additionally comprises: a polymeric viscosity-increasing agent, wherein the polymeric viscosity-increasing agent is water-soluble or water-hydratable. 13. The method according to claim 8 , wherein the first fluid or the second fluid additionally comprises: a proppant. 14. The method according to claim 8 , wherein the second fluid is essentially the same as the first fluid except for the concentration of the surfactant. 15. The method according to claim 8 , additionally comprising: introducing a third water-based fluid comprising a third concentration of the surfactant into the treatment zone, wherein the third concentration of the surfactant in the third fluid is lower than the second concentration of the surfactant in the second fluid, and wherein the introducing of the third fluid is at least at a sufficient rate and pressure to create or extend a fracture in the subterranean formation. 16. The method according to claim 15 , additionally comprising: calculating the concentration of the surfactant to be adsorbed from the second fluid during the introducing of the second fluid into the treatment zone; and calculating the concentration of the surfactant to be adsorbed from the third fluid during the introducing of the third fluid into the treatment zone; the first concentration and the second concentration are selected to minimize the total amount of the surfactant introduced into the treatment zone. 17. The method according to claim 15 , wherein the third fluid is essentially the same as the second fluid except for the concentration of the surfactant.
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