UHMWPE fiber and method to produce

Patent metadata

Field	Value
Publication number	US-9909240-B2
Application number	US-201414533070-A
Country	US
Kind code	B2
Filing date	Nov 4, 2014
Priority date	Nov 4, 2014
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

Processes for preparing ultra-high molecular weight polyethylene fibers, and the fibers and articles produced therefrom. Exposed surfaces of the fibers are subjected to a treatment that enhances the surface energy at the fiber surfaces. Such treated surfaces are subsequently coated with a protective coating immediately after the treatment to increase the shelf life of the treatment. The coating comprises at least one poly(alkyl-oxide) polymer.

First claim

What is claimed is:

1. A process comprising:
a) providing one or more partially oriented fibers, each of said one or more partially oriented fibers having at least some exposed fiber surface areas that are at least partially free of a fiber surface finish;
b) treating the exposed fiber surface areas under conditions effective to enhance the surface energy of the fiber surface areas;
c) applying a protective coating onto at least a portion of the treated fiber surface areas to thereby form coated, treated fibers, said protective coating consisting of at least one ethylene oxide-polypropylene oxide copolymer;
and
d) passing the coated, treated fibers through one or more dryers to dry the coating on the coated, treated fibers while simultaneously stretching the coated, treated fibers as they travel through the one or more dryers, thereby forming highly oriented fibers having a tenacity of greater than 27 g/denier.

2. The process of claim 1 wherein said protective coating is present in an amount of from about 0.2% by weight up to about 3% by weight based on the weight of the fiber plus the weight of the protective coating.

3. The process of claim 1 wherein said fibers comprise polyethylene fibers or poly propylene fibers.

4. The process of claim 1 wherein the treating step of step b) comprises corona treating or plasma treating.

5. The process of claim 1 wherein the protective coating is applied onto the treated fiber surfaces immediately after treating step b) and prior to forming the fibers into a fabric.

6. The process of claim 1 wherein the protective coating is present in an amount of less than about 5% by weight based on the weight of the fiber plus the weight of the protective coating, and wherein following step d) the coated, treated fibers are formed into one or more fabric layers.

7. The process of claim 1 further comprising providing a plurality of fibers produced in step d), applying a polymeric binder material onto at least a portion of said fibers, and producing a woven or non-woven fabric from said plurality of fibers, wherein the protective coating is present in an amount of less than 5% by weight based on the weight of the fiber plus the weight of the protective coating wherein said polymeric binder material comprises from 5% to 30% by weight of the fibers plus the weight of the binder material.

8. The process of claim 1 wherein prior to step a) the partially oriented fibers have surface areas that are substantially covered by a fiber surface finish, and wherein a portion of said fiber surface finish is removed from the fiber surface areas to partially expose the underlying fiber surface areas, wherein a residual fiber surface finish remains on the fiber surfaces, wherein the protective coating is applied on top of said residual fiber surface finish.

9. The process of claim 8 wherein the fiber surface finish is only partially removed from the fiber surface areas to thereby expose from 50% to 99.0% of the underlying fiber surface areas.

10. The process of claim 1 wherein said partially oriented fibers have a tenacity of at least about 18 g/denier up to 27 g/denier, and wherein the protective coating is present in an amount of less than about 5% by weight based on the weight of the fiber plus the weight of the protective coating.

11. A process comprising:
a) providing one or more partially oriented fibers, each of said one or more partially oriented fibers having at least some exposed fiber surface areas that are at least partially free of a fiber surface finish;
b) treating the exposed fiber surface areas under conditions effective to enhance the surface energy of the fiber surface areas;
c) applying a protective coating onto at least a portion of the treated fiber surface areas to thereby form coated, treated fibers, said protective coating consisting of at least one ethylene oxide-polypropylene oxide copolymer and at least one surfactant; and
d) passing the coated, treated fibers through one or more dryers to dry the coating on the coated, treated fibers while simultaneously stretching the coated, treated fibers as they travel through the one or more dryers, thereby forming highly oriented fibers having a tenacity of greater than 27 g/denier.

12. The process of claim 11 wherein said protective coating is present in an amount of from about 0.2% by weight up to about 3% by weight based on the weight of the fiber plus the weight of the protective coating.

13. The process of claim 11 wherein said fibers comprise polyethylene fibers or poly propylene fibers.

14. The process of claim 11 wherein the treating step of step b) comprises corona treating or plasma treating.

15. The process of claim 11 wherein the protective coating is applied onto the treated fiber surfaces immediately after treating step b) and prior to forming the fibers into a fabric.

16. The process of claim 11 wherein the protective coating is present in an amount of less than about 5% by weight based on the weight of the fiber plus the weight of the protective coating, and wherein following step d) the coated, treated fibers are formed into one or more fabric layers.

17. The process of claim 11 further comprising providing a plurality of fibers produced in step d), applying a polymeric binder material onto at least a portion of said fibers, and producing a woven or non-woven fabric from said plurality of fibers, wherein the protective coating is present in an amount of less than 5% by weight based on the weight of the fiber plus the weight of the protective coating wherein said polymeric binder material comprises from 5% to 30% by weight of the fibers plus the weight of the binder material.

18. The process of claim 11 wherein prior to step a) the partially oriented fibers have surface areas that are substantially covered by a fiber surface finish, and wherein a portion of said fiber surface finish is removed from the fiber surface areas to partially expose the underlying fiber surface areas, wherein a residual fiber surface finish remains on the fiber surfaces, wherein the protective coating is applied on top of said residual fiber surface finish.

19. The process of claim 18 wherein the fiber surface finish is only partially removed from the fiber surface areas to thereby expose from 50% to 99.0% of the underlying fiber surface areas.

20. The process of claim 11 wherein said partially oriented fibers have a tenacity of at least about 18 g/denier up to 27 g/denier, and wherein the protective coating is present in an amount of less than about 5% by weight based on the weight of the fiber plus the weight of the protective coating.

Assignees

• Honeywell Int Inc

Inventors

• Ardiff Henry Gerard
• Klein Ralf
• Young John Armstrong
• Tam Thomas

Classifications

• D06M15/572

  Reaction products of isocyanates with polyesters or polyesteramides · CPC title

• D06M10/025 Primary

  Corona discharge or low temperature plasma · CPC title

• D06M15/53

  Polyethers (polyacetals D06M15/39) · CPC title

• C08J5/06

  using pretreated fibrous materials · CPC title

• D04H1/58 Primary

  by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives (in combination with needling D04H1/488) · CPC title