Tunable infrared reflectance by phonon modulation

Patent metadata

Field	Value
Publication number	US-9909233-B1
Application number	US-201715711122-A
Country	US
Kind code	B1
Filing date	Sep 21, 2017
Priority date	Sep 21, 2017
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

The present invention pertains to the use of mobile coherent interfaces in a ferroelectric material to interact with optical phonons and, ultimately, to affect the material's optical properties. In altering the optical phonon properties, the optical properties of the ferroelectric material in the spectral range near-to the phonon mode frequency can dramatically change. This can result in a facile means to change to the optical response of the ferroelectric material in the infrared.

First claim

We claim:

1. A method to tune the infrared reflectance of a ferroelectric material, comprising:
providing at least one ferroelectric layer of a ferroelectric material on a substrate, wherein the at least one ferroelectric layer comprises a plurality of ferroelectric domain walls that are mobile under an applied electric field; and
applying an electric field across the at least one ferroelectric layer, thereby altering the volumetric concentration of the plurality of ferroelastic domain walls and causing a shift in the wavelength of a minimum in the infrared reflectance.

2. The method of claim 1 , wherein the ferroelectric material comprises lead zirconate titanate.

3. The method of claim 1 , wherein the ferroelectric material comprises lead magnesium niobate-lead titanate, lead lanthanum zirconate titanate, lead niobate zirconate titanate, lead indium niobate-lead titanate, bismuth ferrite, bismuth samarium ferrite, bismuth cobalt ferrite, barium titanate, barium strontium titanate, barium calcium zirconate titanate, barium titanate zirconate, bismuth sodium niobate, or bismuth sodium niobate-barium titanate.

4. The method of claim 1 , wherein the at least one ferroelectric layer comprises a ferroelectric bilayer heterostructure.

5. The method of claim 4 , wherein the ferroelectric bilayer heterostructure comprises a rhombohedral symmetry lead zirconate titanate layer and a tetragonal symmetry lead zirconate titanate layer.

6. The method of claim 1 , wherein the thickness of the at least one ferroelectric layer is less than 3 microns.

7. The method of claim 1 , further comprising an optical grating, nanoantenna, or metasurface on the top surface of the at least one ferroelectric layer.

Assignees

• Nat Tech & Eng Solutions Sandia Llc

Inventors

• Ihlefeld Jon F
• Sinclair Michael B
• Beechem Iii Thomas E

Classifications

• C09K13/00

  Etching, surface-brightening or pickling compositions (for glass C03C15/00, {C03C25/66; for mortars, concrete, artificial or natural stone or ceramics C04B41/5338}; for metallic material C23F, C23G1/00, C25F1/00; {for semi-conductors H10P52/40}) · CPC title

• C30B29/32 Primary

  Titanates; Germanates; Molybdates; Tungstates · CPC title

• B24B37/042

  operating processes therefor · CPC title

• C30B29/24

  with formula AMeO3, wherein A is a rare earth metal and Me is Fe, Ga, Sc, Cr, Co or Al, e.g. ortho ferrites · CPC title

• C30B29/30

  Niobates; Vanadates; Tantalates · CPC title