Resin systems for making composite products

Patent metadata

Field	Value
Publication number	US-9909041-B2
Application number	US-201514852565-A
Country	US
Kind code	B2
Filing date	Sep 13, 2015
Priority date	May 3, 2012
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

Resin systems and methods for making and using same are provided. The resin system can include a first aqueous resin comprising at least two polymerized monomers and a second aqueous resin comprising at least two polymerized monomers. The first aqueous resin can be present in an amount of about 5 wt % to about 95 wt %, based on the total weight the resin system. The second aqueous resin can be present in an amount of about 5 wt % to about 95 wt %, based on the total weight the resin system. The at least two polymerized monomers of the first and second aqueous resins can be the same monomers.

First claim

What is claimed is:

1. A resin system, comprising:
a mixture of a first aqueous resin and a second aqueous resin, wherein the first aqueous resin comprises at least two polymerized monomers and the second aqueous resin comprises at least two polymerized monomers, wherein:
the first aqueous resin is present in an amount of about 5 wt % to about 95 wt %, based on a total weight the resin system,
the second aqueous resin is present in an amount of about 5 wt % to about 95 wt %, based on the total weight the resin system,
the at least two polymerized monomers of the first aqueous resin and the at least two polymerized monomers of the second aqueous resin are the same monomers,
a molar ratio, a weight average molecular weight, or a molar ratio and a weight average molecular weight of the first aqueous resin and the second aqueous resin are different from one another,
the first aqueous resin and the second aqueous resin are each in the form of an aqueous solution,
the first aqueous resin is selected from the group consisting of:
a first phenol-formaldehyde resin having a molar ratio of formaldehyde to phenol of about 1.5:1 to 2.1:1,
a first urea-formaldehyde resin having a molar ratio formaldehyde to urea of about 0.25:1 to about 1.5:1,
a first melamine-formaldehyde resin having a molar ratio of formaldehyde to melamine of about 0.25:1 to about 1.5:1,
a first resorcinol-formaldehyde resin having a molar ratio of formaldehyde to resorcinol of about 0.4:1 to about 2:1, and
a first melamine-urea-formaldehyde resin having a molar ratio of F:(M+U), wherein F is the moles of formaldehyde, M is the moles of melamine, U is the moles of urea, and the molar ratio of F:(M+U) is about 0.25:1 to about 2.1:1, and the second aqueous resin is selected from the group consisting of:
a second phenol-formaldehyde resin having a molar ratio of formaldehyde to phenol of 2.2:1 to about 2.6:1,
a second urea-formaldehyde resin having a molar ratio of formaldehyde to urea of about 0.25:1 to about 2.1:1,
a second melamine-formaldehyde resin having a molar ratio of formaldehyde to melamine of about 0.8:1 to about 2:1,
a second resorcinol-formaldehyde resin having a molar ratio of formaldehyde to resorcinol of about 0.4:1 to about 1:1 or about 1.6:1 to about 2:1, and
a second melamine-urea-formaldehyde resin having a molar ratio of F:(M+U), wherein F is the moles of formaldehyde, M is the moles of melamine, U is the moles of urea, and the molar ratio of F:(M+U) is about 0.8:1 to about 2.1:1.

2. The resin system of claim 1 , wherein:
the first aqueous resin is a first urea-formaldehyde resin having a molar ratio formaldehyde to urea of about 0.25:1 to about 1.5:1, and
the second aqueous resin is a second urea-formaldehyde resin having a molar ratio of formaldehyde to urea of about 0.25:1 to about 2.1:1.

3. The resin system of claim 1 , wherein:
the first aqueous resin is a first melamine-formaldehyde resin having a molar ratio of formaldehyde to melamine of about 0.25:1 to about 1.5:1, and
the second aqueous resin is a second melamine-formaldehyde resin having a molar ratio of formaldehyde to melamine of about 0.8:1 to about 2:1.

4. The resin system of claim 1 , wherein:
the first aqueous resin is a first resorcinol-formaldehyde resin having a molar ratio of formaldehyde to resorcinol of about 0.4:1 to about 2:1, and
the second aqueous resin is a second resorcinol-formaldehyde resin having a molar ratio of formaldehyde to resorcinol of about 0.4:1 to about 1:1 or about 1.6:1 to about 2:1.

5. The resin system of claim 1 , wherein:
the first aqueous resin is a first melamine-urea-formaldehyde resin having a molar ratio of F:(M+U), wherein F is the moles of formaldehyde, M is the moles of melamine, U is the moles of urea, and the molar ratio of F:(M+U) is about 0.25:1 to about 2.1:1, and
the second aqueous resin is a second melamine-urea-formaldehyde resin having a molar ratio of F:(M+U), wherein F is the moles of formaldehyde, M is the moles of melamine, U is the moles of urea, and the molar ratio of F:(M+U) is about 0.8:1 to about 2.1:1.

6. The resin system of claim 1 , wherein:
the first aqueous resin is selected from the group consisting of:
a first phenol-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000,
a first urea-formaldehyde resin having a weight average molecular weight of about 200 to about 3,500,
a first melamine-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000,
a first resorcinol-formaldehyde resin having a weight average molecular weight of about 200 to about 4,500, and
a first melamine-urea-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000, and

the second aqueous resin is selected from the group consisting of:
a second phenol-formaldehyde resin having a weight average molecular weight of about 2,750 to about 4,500,
a second urea-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000,
a second melamine-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000,
a second resorcinol-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000, and
a second melamine-urea-formaldehyde resin having a weight average molecular weight of about 200 to about 6,000.

7. The resin system of claim 1 , wherein the resin system has a viscosity of about 250 cP to about 1,500 cP at a temperature of 25° C.

8. The resin system of claim 1 , wherein the resin system has a solids content of about 30 wt % to about 70 wt %, based on a total weight of the resin system.

9. The resin system of claim 1 , further comprising about 1 wt % to about 30 wt % of an additive, based on the total weight of the resin system, wherein the additive comprises a filler, an extender, a surfactant, a formaldehyde scavenger, or any combination thereof.

10. The resin system of claim 1 , wherein the first aqueous resin is present in an amount of about 5 wt % to about 95 wt %, based on a combined solids weight of the first aqueous resin and the second aqueous resin.

11. The resin system of claim 1 , wherein the first aqueous resin is present in an amount of about 40 wt % to about 80 wt %, based on a combined solids weight of the first aqueous resin and the second aqueous resin.

12. A blended furnish, comprising:
a plurality of lignocellulose substrates; and
a resin system comprising a mixture of a first aqueous resin and a second aqueous resin, wherein the first aqueous resin comprises at least two polymerized monomers and the second aqueous resin comprises at least two polymerized monomers, wherein:
the first aqueous resin is present in an amount of about 5 wt % to about 95 wt %, based on a total weight the resin system,
the second aqueous resin is present in an amount of about 5 wt % to about 95 wt %, based on the total weight the resin system,
the at least two polymerized monomers of the first aqueous resin and the at least two polymerized monomers of the second aqueous resin are the same monomers,
a molar ratio, a weight average molecular weight, or a molar ratio and a weight average molecular weight of the first aqueous resin and the second aqueous resin are different from one another,
the first aqueous resin and the second aqueous resin are each in the form of an aqueous solution,
the first aqueous resin is selected from the group consisting of:
a first phenol-formaldehyde resin having a molar ratio of formaldehyde to phenol of about 1.5:1 to 2.1:1,
a first urea-formaldehyde resin having a molar ratio formaldehyde to urea of about 0.25:1 to about 1.5:1,
a first melamine-form

Assignees

• Georgia Pacific Chemicals Llc

Inventors

• Yeager Daniel C
• Breyer Robert A
• Knight James H
• Cannon Melissa J
• Baxter Paul S

Classifications

• C08L61/06

  of aldehydes with phenols · CPC title

• C09D161/06

  of aldehydes with phenols · CPC title

• C09J161/12

  with polyhydric phenols · CPC title

• Y10T428/31942

  Of aldehyde or ketone condensation product · CPC title

• C09J161/28

  with melamine · CPC title