Particles for electrophoretic displays

Patent metadata

Field	Value
Publication number	US-9908963-B2
Application number	US-201414783971-A
Country	US
Kind code	B2
Filing date	Mar 18, 2014
Priority date	Apr 12, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

This invention relates to polymer particles, a process for their preparation, the use of these particles for the preparation of an electrophoretic device, electrophoretic displays comprising such particle, and new copolymer stabilizers.

First claim

The invention claimed is:

1. A polymer particle for use in electrophoretic devices comprising at least one stabiliser and monomer units of at least one monomer, optionally at least one polymerisable dye, optionally of at least one charged co-monomer, and optionally of at least one crosslinking co-monomer, wherein the stabiliser is a copolymer of methyl methacrylate, octadecyl acrylate, and at least one co-monomer, wherein the stabiliser comprises as co-monomer a (meth)acrylic acid ester of a branched alcohol.

2. The polymer particle according to claim 1 , wherein the stabiliser is a block copolymer.

3. The polymer particle according to claim 1 , wherein the stabiliser comprises as co-monomer ethyl hexyl acrylate.

4. The polymer particle according to claim 1 , wherein the stabiliser is a block copolymer
PMMA n -b-P(ODA m -co-EHA p ) wherein n is the number of methyl methacrylate units, m is the number of octadecyl acrylate units, and p is the number of ethyl hexyl acrylate units and n is in the range of 5-200, m is in the range of 40-150, and p is in the range of 1-80.

5. The polymer particle according to claim 1 , wherein the stabiliser comprises a polymerisable group.

6. The polymer particle according to claim 1 , wherein the at least one polymerisable dye comprises a chromophore, at least one polymerisable group, optionally at least one linker group, and optionally at least one charged group.

7. A process for the preparation of the polymer particle for use in electrophoretic devices, comprising
a) polymerising at least one monomer, at least one stabiliser, at least one initiator, optionally at least one polymerisable dye, optionally at least one charged co-monomer, and optionally at least one crosslinking co-monomer,
b) optionally colouring the polymer particles by incorporation of at least one dye and/or at least one pre-polymerised dye and/or at least one polymerisable dye, and
c) c) optionally washing and isolating the polymer particles, wherein the stabiliser is a copolymer of methyl methacrylate, octadecyl acrylate, and at least one co-monomer, and wherein the stabiliser comprises as co-monomer a (meth)acrylic acid ester of a branched alcohol.

8. The process according to claim 7 wherein the polymerisation is a dispersion polymerisation in at least one non-aqueous, non-polar solvent.

9. A method for the preparation of an electrophoretic fluid and a mono, bi or polychromal electrophoretic device comprising utilizing the polymer particles according to claim 1 .

10. An electrophoretic fluid comprising the polymer particle according to claim 1 .

11. An electrophoretic display device comprising the polymer particle according to claim 1 .

12. The electrophoretic display device according to claim 11 , wherein an electrophoretic fluid is applied by a technique selected from inkjet printing, slot die spraying, nozzle spraying, and flexographic printing, or any other contact or contactless printing or deposition technique.

13. A block copolymer of the formula PMMA n -b-P(ODA m -co-EHA p ) wherein n is the number of methyl methacrylate units, m is the number of octadecyl acrylate units, and p is the number of ethyl hexyl acrylate units and n is in the range of 5-200, m is in the range of 40-150, and p is in the range of 1-80.

14. The block copolymer according to claim 13 , wherein the block copolymer comprises a polymerisable group.

Assignees

• Merck Patent Gmbh
• Univ Of Kent
• Mereck Patent Gmbh

Inventors

• Farrand Louise D
• Topping Claire
• Belsey Kate
• Holder Simon

Classifications

• C08F265/06 Primary

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08F287/00

  Macromolecular compounds obtained by polymerising monomers on to block polymers · CPC title

• C08F2/14

  Organic medium · CPC title

• G02F2001/1678

  characterised by the composition or particle type · CPC title

• C08F299/04 Primary

  from polyesters · CPC title