Systems and methods for ceramic matrix composites

Patent metadata

Field	Value
Publication number	US-9908820-B2
Application number	US-201514838856-A
Country	US
Kind code	B2
Filing date	Aug 28, 2015
Priority date	Sep 5, 2014
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

Methods for fabricating a ceramic matrix composite are disclosed. A fiber preform may be placed in a mold. An aqueous solution may be added to the fiber preform. The aqueous solution may include water, carbon nanotubes, and a binder. The preform may be frozen. Freezing the preform may cause the water to expand and separate fibers in the fiber preform. The carbon nanotubes may bond to the fibers. The preform may be freeze dried to remove the water. The preform may then be processed according to standard CMC process.

First claim

The invention claimed is:

1. A method for fabricating a composite material comprising:
adding a slurry to a fiber preform comprising a plurality of fiber tows, wherein the slurry is intermixed with carbon nanotubes;
freezing the fiber preform;
freeze drying the fiber preform; and
heat treating the fiber preform in the presence of a boron-bearing precursor and nitrogen gas to produce boron nitride nanotubes.

2. The method of claim 1 , wherein the freezing the fiber preform separates fibers in the plurality of fiber tows.

3. The method of claim 1 , wherein the slurry further comprises a binder.

4. The method of claim 1 , wherein the carbon nanotubes bond to fibers in the plurality of fiber tows.

5. The method of claim 1 , further comprising processing the fiber preform via at least one of slurry casting, chemical vapor infiltration, polymer infiltration and pyrolysis, or melt infiltration.

6. A method of manufacturing an aircraft component comprising:
inserting a fiber tow into a mold;
introducing an aqueous solution comprising water, carbon nanotubes, and a binder into the mold;
freezing the aqueous solution, wherein the freezing the aqueous solution separates fibers within the fiber tow;
freeze drying the aqueous solution, wherein the freeze drying removes at least a portion of the water from the mold;
processing the mold via at least one of slurry casting, chemical vapor infiltration, polymer infiltration and pyrolysis, or melt infiltration; and
heat treating the fiber tow in the presence of a boron-bearing precursor and nitrogen gas to produce boron nitride nanotubes.

7. The method of claim 6 , wherein the carbon nanotubes form an interfacial region surrounding the fibers.

8. The method of claim 6 , wherein the freezing comprises at least one of inserting the mold in a freezer, cooling the mold with liquid nitrogen, or cooling the mold with dry ice.

9. The method of claim 6 , wherein the carbon nanotubes and the fiber tow form a rigid preform.

10. The method of claim 1 , wherein the boron-bearing precursor is boron oxide.

11. The method of claim 10 , wherein the heat treating the fiber preform proceeds through the reaction B 2 O 3 +3C(CNTs)+N 2 →2BN(BNNTs)+3CO, wherein CNTs represent carbon nanotubes, and BNNTs represent boron nitride nanotubes.

12. The method of claim 6 , wherein the boron-bearing precursor is boron oxide.

13. The method of claim 12 , wherein the heat treating the fiber preform proceeds through the reaction B 2 O 3 +3C(CNTs)+N 2 →2BN(BNNTs)+3CO, wherein CNTs represent carbon nanotubes, and BNNTs represent boron nitride nanotubes.

Assignees

• United Technologies Corp

Inventors

• Sheedy Paul
• Jarmon David C

Classifications

• C04B35/76

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B2235/421

  Boron · CPC title

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B2235/606

  Drying · CPC title

• C04B35/83

  Carbon fibres in a carbon matrix · CPC title