Method and system for enhancing the mass transfer rate of a soluble gas

Patent metadata

Field	Value
Publication number	US-9908777-B2
Application number	US-201414782343-A
Country	US
Kind code	B2
Filing date	Apr 15, 2014
Priority date	Apr 15, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

A method for enhancing the mass transfer rate of a soluble gas from a gaseous phase to an aqueous phase using a membrane including a catalyst. The method comprises wetting the membrane with a liquid such that a film of the liquid forms on at least a portion of the membrane, the film contacting at least a portion of the catalyst. The method further comprises exposing the wetted membrane to at least one soluble gas, wherein at least a portion of the soluble gas dissolves into the liquid.

First claim

What is claimed is:

1. A method for enhancing the mass transfer rate of a soluble gas from a gaseous phase to an aqueous phase using a membrane including a catalyst, the method comprising:
wetting the membrane with a liquid such that a film of the liquid forms on at least a portion of the membrane, the film being defined at least in part by a boundary layer opposite the membrane and contacting at least a portion of the catalyst; and
exposing the wetted membrane to at least one soluble gas, wherein at least a portion of the soluble gas dissolves into the liquid through the boundary layer.

2. The method of claim 1 , wherein exposing the wetted membrane to at least one soluble gas further comprises:
exposing the wetted membrane to carbon dioxide, ammonia, or other soluble gases.

3. The method of claim 1 , wherein wetting the membrane further comprises:
flowing the liquid over the membrane.

4. The method of claim 1 , wherein wetting the membrane further comprises:
moving at least a portion of the membrane into a supply of liquid.

5. The method of claim 4 , wherein exposing the wetted membrane to at least one soluble gas further comprises:
moving at least a portion of the membrane out of the supply of liquid.

6. The method of claim 1 , further comprising:
removing the catalyst from the membrane after the catalyst has degraded; and
attaching an additional amount of the catalyst to the membrane.

7. A system for enhancing the mass transfer rate of a soluble gas from a gaseous phase to an aqueous phase, comprising:
a membrane configured to allow the formation of a film of aqueous solution thereon, the membrane including a first surface and a second surface opposite the first surface and including an amount of a catalyst configured to increase the rate of mass transfer of at least one soluble gas from a gaseous phase to an aqueous phase in an aqueous solution when the at least one soluble gas and the catalyst are exposed to the film of aqueous solution; and

a liquid supplying apparatus configured to wet the first and second surfaces of the membrane for forming the film on the membrane.

8. The system of claim 7 , wherein at least a portion of the membrane is formed from filaments, strands, or fibers of the catalyst.

9. The system of claim 7 , wherein the catalyst further comprises a metal.

10. The system of claim 7 , wherein the catalyst further comprises a zinc-based material or nickel-based material.

11. The system of claim 9 , wherein the catalyst further comprises a zinc-oxide material.

12. The system of claim 7 , further comprising:
a supply of the liquid configured to capture liquid from the membrane.

13. The system of claim 7 , wherein the membrane further comprises a plurality of fibers of at least one material and the catalyst is in the form of at least one filament woven with at least some of the fibers.

14. The system of claim 7 , wherein the catalyst is bonded to the membrane with a strength sufficient to withstand at least shear forces of water flowing over the membrane.

15. The system of claim 7 , wherein the membrane is in contact with water and carbon dioxide.

16. A method for enhancing the mass transfer rate of a soluble gas from a gaseous phase to an aqueous phase using a membrane including a catalyst, the method comprising:
wetting the membrane with a liquid such that a film of the liquid forms on at least a portion of the membrane, the film contacting at least a portion of the catalyst;
exposing the wetted membrane to at least one soluble gas, wherein at least a portion of the soluble gas dissolves into the liquid;
removing the catalyst from the membrane after the catalyst has degraded; and
attaching an additional amount of the catalyst to the membrane.

17. A system for enhancing the mass transfer rate of a soluble gas from a gaseous phase to an aqueous phase, comprising:
a membrane configured to allow the formation of a film of aqueous solution thereon, the membrane including an amount of a catalyst configured to increase the rate of mass transfer of at least one soluble gas from a gaseous phase to an aqueous phase in an aqueous solution when the at least one soluble gas and the catalyst are exposed to the film of aqueous solution, wherein at least a portion of the membrane is formed from filaments, strands, or fibers of the catalyst; and
a liquid supplying apparatus configured to wet the membrane for forming the film on the membrane.

Assignees

• Univ Ohio

Inventors

• Bayless David James

Classifications

• B01D2251/304

  of sodium · CPC title

• B01D53/62

  Carbon oxides · CPC title

• B01J23/755

  Nickel · CPC title

• B01J35/065

  Operations & Transport · mapped topic

• B01D2252/103

  Water · CPC title