Infrared shielding sheet, method for manufacturing the same, and use of the same

Patent metadata

Field	Value
Publication number	US-9908306-B2
Application number	US-201414890434-A
Country	US
Kind code	B2
Filing date	May 16, 2014
Priority date	May 16, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

An infrared shielding sheet includes a laminated film formed by alternately laminating a high refractive index resin layer containing fine particles and a low refractive index resin layer containing fine particles. At least one of the low refractive index resin layers has a value of 0.1 or more that is obtained by subtracting a refractive index at an arbitrary wavelength from 780 to 2500 nm from a refractive index at a wavelength of 550 nm. The low refractive index resin layer has a refractive index lower than a refractive index of the high refractive index resin layer at any wavelength in a range from 550 nm to the arbitrary wavelength inclusive.

First claim

The invention claimed is:

1. An infrared shielding sheet comprising a laminated film formed by alternately laminating at least one high refractive index resin layer containing fine particles and at least one low refractive index resin layer containing fine particles,
wherein at least one of the at least one low refractive index resin layer contains the fine particles in an amount of from 40 to 95 wt. %, and has a value of 0.1 or more that is obtained by subtracting a refractive index at an arbitrary wavelength from 780 to 2500 nm from a refractive index at a wavelength of 550 nm, and
the at least one low refractive index resin layer has a refractive index lower than a refractive index of the at least one high refractive index resin layer at any wavelength in a range from 550 nm to the arbitrary wavelength inclusive.

2. The infrared shielding sheet according to claim 1 ,
wherein the at least one low refractive index resin layer has a refractive index lower than a refractive index of the at least one high refractive index resin layer at an arbitrary wavelength from 780 to 2500 nm, and
at least one of the at least one high refractive index resin layer and/or at least one of the at least one low refractive index resin layer have/has a coefficient of QWOT of 1.5 or more related to an optical thickness in an arbitrary wavelength from 780 to 2500 nm.

3. The infrared shielding sheet according to claim 1 ,
wherein each of the at least one high refractive index resin layer and the at least one low refractive index resin layer has a surface resistance of 1 kΩ/□ or more, and
a total number of the at least one high refractive index resin layer and the at least one low refractive index resin layer is 4 or more.

4. The infrared shielding sheet according to claim 1 ,
having a visible light transmittance of 50% or more and a haze of 8% or less.

5. The infrared shielding sheet according to claim 1 , wherein at least one of the at least one high refractive index resin layer contains at least one kind of fine particles selected from a group consisting of titanium oxide, zirconium oxide, hafnium oxide, tantalum oxide, tungsten oxide, niobium oxide, cerium oxide, lead oxide, zinc oxide, diamond, boride, and nitride.

6. The infrared shielding sheet according to claim 1 , wherein a content of the fine particles in the at least one high refractive index resin layer is 95 wt. % or less based on a total of the at least one high refractive index resin layer.

7. The infrared shielding sheet according to claim 1 , wherein a content of the fine particles in the at least one low refractive index resin layer is 95 wt. % or less based on a total of the at least one low refractive index resin layer.

8. The infrared shielding sheet according to claim 1 , further comprising at least one selected from a group consisting of a cholesteric liquid crystal film, a birefringence multilayer film, and infrared absorption coloring matter.

9. The infrared shielding sheet according to claim 1 , further comprising a transparent support,
wherein the laminated film is formed on the transparent support.

10. A method for manufacturing the infrared shielding sheet according to claim 1 , comprising a step of forming the at least one high refractive index resin layer and the at least one low refractive index resin layer by application method.

11. The infrared shielding sheet according to claim 1 ,
wherein the at least one high refractive index resin layer has a value of 0.1 or less that is obtained by subtracting a refractive index at an arbitrary wavelength from 780 to 1500 nm from a refractive index at the wavelength of 550 nm, and
the at least one low refractive index resin layer has a value of 0.1 or more that is obtained by subtracting a refractive index at an arbitrary wavelength from 780 to 1500 nm from the refractive index at the wavelength of 550 nm.

12. The infrared shielding sheet according to claim 11 ,
wherein each of the at least one high refractive index resin layer and the at least one low refractive index resin layer has a surface resistance of 1 kΩ/□ or more,
a total number of the at least one high refractive index resin layer and the at least one low refractive index resin layer is 3 or more, and
each of the at least one high refractive index resin layer and the at least one low refractive index resin layer at an arbitrary wavelength from 780 to 1500 nm has a optical thickness in a range from 195 to 375 nm.

13. The infrared shielding sheet according to claim 1 , wherein at least one of the at least one low refractive index resin layer contains at least one kind of fine particles selected from a group consisting of tin oxide, indium oxide, zinc oxide, and tungsten oxide.

14. The infrared shielding sheet according to claim 13 , wherein at least one of the at least one low refractive index resin layer contains at least one kind of fine particles selected from a group consisting of antimony-doped tin oxide, tin-doped indium oxide, gallium-doped zinc oxide, oxygen-deficient tungsten oxide, and cesium-doped tungsten oxide.

15. The infrared shielding sheet according to claim 13 ,
wherein at least one of the at least one low refractive index resin layer contains at least one kind of non-hollow fine particles selected from the group, and
at least one of the at least one low refractive index resin layer includes hollow fine particles.

16. The infrared shielding sheet according to claim 13 , wherein at least one of the at least one low refractive index resin layer contains silica fine particles.

17. The infrared shielding sheet according to claim 16 , wherein the silica fine particles are hollow silica fine particles.

18. An interlayer film for laminated glass comprising:
the infrared shielding sheet according to claim 1 ; and
an interlayer film that is formed on at least one of outermost layers of the infrared shielding sheet.

19. The interlayer film for laminated glass according to claim 18 , wherein the interlayer film contains polyvinyl butyral.

20. A laminated glass comprising:
the interlayer film for laminated glass according to claim 18 ; and
a plurality of glass plates,
wherein the interlayer film for laminated glass is interposed between the plurality of glass plates.

21. A window member comprising the laminated glass according to claim 20 .

Assignees

• Nippon Kayaku Kk

Inventors

• Hara Yukihiro
• Arifuku Michiharu
• Saito Shoko
• Kang Myeongjin
• Kiyoyanagi Noriko

Classifications

• C08J2433/00

  Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers · CPC title

• B32B2264/102

  Oxide or hydroxide · CPC title

• B32B2264/10

  Inorganic particles · CPC title

• G02B5/26

  Reflecting filters (G02B5/28 takes precedence) · CPC title

• B32B17/1055

  characterized by the resin layer, i.e. interlayer · CPC title