Porous ceramic article and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-9908260-B2
Application number	US-201414250524-A
Country	US
Kind code	B2
Filing date	Apr 11, 2014
Priority date	May 20, 2013
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

The present disclosure relates to porous ceramic articles and a method of making the same. The porous ceramic articles have microstructure of sinter bonded or reaction bonded large pre-reacted particles and pore network structure exhibiting large pore necks. The method of making the porous ceramic articles involves using pre-reacted particles having one or more phases. A plastic ceramic precursor composition is also disclosed. The composition includes a mixture of at least one of dense, porous, or hollow spheroidal pre-reacted particles and a liquid vehicle.

First claim

What is claimed is:

1. A method of making a porous ceramic article comprising pre-reacted particles, the method comprising:
forming green particles of at least 10 μm diameter;
calcining the green particles to form pre-reacted particles wherein the pre-reacted particles have a multiphase composition comprising two or more of silica, alumina, titania, cristobalite, mullite, rutile, SrTi 3 Al 8 O 19 , feldspar, aluminum titanate, and aluminum titanate solid solution pseudobrookite;
mixing the pre-reacted particles and a liquid vehicle to form a paste;
forming the paste into a wet green body;
drying the wet green body to form a dried green body; and
firing the dried green body to form the porous ceramic article, wherein
the pre-reacted particles comprise at least one of dense, porous, or hollow spheroidal particles.

2. The method of claim 1 , wherein forming green particles, comprises:
mixing at least two inorganic fine powders with liquid vehicle to make a slurry wherein the slurry comprises between 15% and 40% solids loading, and
spray-drying the slurry, and
wherein the inorganic fine powders comprise an average particle diameter in a range of 1×10 −9 to 5.0×10 −6 meters.

3. The method of claim 2 , wherein the inorganic fine powders comprise an average particle diameter in a range of 3.0×10 −8 to 2.0×10 −6 meters.

4. The method of claim 2 , wherein mixing fine powders comprises:
further adding organic additives, including at least one of binders, surfactants, and dispersants.

5. The method of claim 2 , wherein a first inorganic fine powder of the at least two inorganic fine powders comprises a source of alumina, silica, magnesia, titania, strontium oxide, barium oxide, calcium oxide, lanthanum oxide, boron oxide, cerium oxide, yttrium oxide, or other rare earth oxides, zirconium oxide, an alkali oxide, or iron oxide.

6. The method of claim 5 , wherein a second inorganic fine powder of the at least two inorganic fine powders comprises a source of alumina, silica, magnesia, titania, strontium oxide, calcium oxide, lanthanum oxide, boron oxide, cerium oxide, yttrium oxide, or other rare earth oxides, zirconium oxide, or an alkali oxide different from the first inorganic fine powder.

7. The method of claim 1 , wherein calcining green particles comprises forming the multiphase composition of the pre-reacted particles with phase combinations comprising:
alumina and silica,
alumina and mullite,
alumina and cristobalite,
alumina, cristobalite, and mullite,
aluminum titanate, alumina, and feldspar,
aluminum titanate, feldspar, and mullite,
aluminum titanate, alumina, feldspar, and mullite,
aluminum titanate, alumina, rutile, and feldspar,
aluminum titanate, alumina, titania, and feldspar,
aluminum titanate, alumina, rutile, feldspar, and mullite,
aluminum titanate, alumina, rutile, feldspar, and SrTi 3 Al 8 O 19 ,
aluminum titanate, alumina, rutile, feldspar, mullite, and SrTi 3 Al 8 O 19 , or
aluminum titanate, alumina, rutile, feldspar, mullite, SrTi 3 Al 8 O 19 , and quartz.

8. The method of claim 1 , wherein calcining green particles to form pre-reacted particles comprises forming at least one of sintered, partially reacted, and fully reacted particles.

9. The method of claim 1 , wherein forming the paste comprises extruding, casting, rolling, or pressing, the paste into a green honeycomb log, green trough log, or green disks.

10. The method of claim 1 , further comprising cutting the dried green body into a section and plugging the section before or after firing.

11. The method of claim 1 , wherein forming the paste comprises:
mixing the pre-reacted particles with at least one of an inorganic powder, organic powder, and inorganic binder, wherein
the liquid vehicle comprises at least one of water, alcohol, and an organic solvent.

12. The method of claim 1 , wherein forming green particles comprises at least one of spray-drying the slurry, spin drying the slurry, atomizing the slurry, breaking up a mix of inorganic fine powders with a polymer binder slurry, breaking up a dried cake of the slurry.

13. The method of claim 1 , wherein the spheroidal particles comprise at least one of spherical, toroidal, prolate spheroidal, and oblate spheroidal particles.

14. The method of claim 1 , further comprising:
before mixing is completed, adding to the pre-reacted particles and the liquid vehicle at least one of a source of alumina, silica, magnesia, titania, strontium oxide, calcium oxide, lanthanum oxide, boron oxide, cerium oxide, yttrium oxide, or other rare earth oxide, zirconium oxide, and one or more alkali oxides.

15. The method of claim 1 , wherein the porous ceramic article comprises a dominant phase (greater than 50 vol %) of AT solid solution pseudobrookite phase.

16. The method of claim 1 , wherein the mixing the pre-reacted particles and the liquid vehicle to form the paste further comprises adding a pore former having a particle size to match a particle size of the pre-reacted particles.

17. The method of claim 1 , wherein the mixing the pre-reacted particles and the liquid vehicle to form a paste further comprises adding a pore former comprising polymer beads.

18. The method of claim 1 , wherein the pre-reacted particles comprise alumina, 3% silica, and lanthanum oxide.

19. The method of claim 1 , wherein the calcining of the pre-reacted particles comprises rotary calcination at 1000° C. and 1650° C.

20. The method of claim 1 , wherein inorganic particles in the paste comprise:
pre-reacted particles having a composition comprising aluminum titatnate-feldspar , and
fine alumina particles having a particle size less than 1 μm.

21. A method of making a porous ceramic article, comprising:
forming green particles comprising a d50 of at least 14.84 μm and less than 53.05 μm;
calcining the green particles to form pre-reacted particles wherein the pre-reacted particles have a multiphase composition comprising two or more of silica, alumina, titania, cristobalite, mullite, rutile, SrTi 3 Al 8 O 19 , feldspar, aluminum titanate, and aluminum titanate solid solution pseudobrookite;
mixing the pre-reacted particles and a liquid vehicle to form a paste;
forming the paste into a wet green body;
drying the wet green body to form a dried green body; and
firing the dried green body to form the porous ceramic article comprising pores formed by spaces between the pre-reacted particles, wherein
the pre-reacted particles comprise at least one of dense, porous, or hollow spheroidal particles,
and
the porous ceramic article comprises a porosity of at least 50% and a median pore size (d50) of 10 μm to 30 μm.

22. The method of claim 21 , wherein the pre-reacted particles comprise at least two constituents of a complete porous ceramic article pre-cursor batch,
the at least two constituents are at least partially reacted, and
a first portion of the pre-reacted particles comprise a first composition and a second portion of the pre-reacted particles comprise a second composition different from the first composition.

23. The method of claim 21 , wherein the pre-reacted particles comprise a complete porous ceramic article pre-cursor batch, and
the pre-reacted particles are fully reacted.

Assignees

• Corning Inc

Inventors

• Backhaus Ricoult Monika
• Glose Christopher Raymond

Classifications

• C04B2235/3463

  Alumino-silicates other than clay, e.g. mullite · CPC title

• C04B2235/5472

  Bimodal, multi-modal or multi-fraction · CPC title

• C04B2235/3206

  Magnesium oxides or oxide-forming salts thereof · CPC title

• C04B2111/00793

  as filters or diaphragms · CPC title

• C04B2235/349

  Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite · CPC title