Method for recovering low-temperature heat and application of the method to an aromatics complex

Patent metadata

Field	Value
Publication number	US-9908061-B2
Application number	US-201314646434-A
Country	US
Kind code	B2
Filing date	Oct 17, 2013
Priority date	Nov 22, 2012
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

A method for recovering heat available at low temperature in a process and its use in order to reduce the energy consumption of the said process, and application of this method to an aromatics complex in which the low-temperature heat is recovered at the head of distillation columns in the form of low-pressure steam and is reused to reboil other distillation columns in which the operating pressure has possibly been lowered.

First claim

The invention claimed is:

1. A method for recovering low-temperature heat between 100° C. and 180° C., from a low-temperature heat source in a refining or petrochemical process, called a “complex”, comprising at least one distillation column, (P 1 ), a unit of paraxylene adsorption (P 2 ), xylenes isomerization unit (P 3 ), and a transalkylation unit (P 4 ), the effluents coming out from these units being separated in a set of distillation columns noted from C1 to C11, the signification of these columns being as follows:
C1 reformate column, C2 xylenes column, C3 heavy aromatics column, C4 raffinate column, C5 extract column, C6 purification column, C7 deheptanisor, C8 striper, C9 benzene column, C10 toluene column, C11 stabilisation column, said method comprising the following stages:
1) generating low pressure steam at a pressure between 1 bar absolute and 7 bars absolute by exchange with at least one low-temperature heat source that is a group of distillation columns C3, C4 and C5 of the complex, forming a first set of columns E 1 ,
2) increasing the pressure of the generated steam in at least one compression stage, in order to produce medium pressure steam,
3) reducing the operating pressure of one or more distillation columns of the complex, so as to lower the temperature of a corresponding reboiler of that column below the temperature of the medium pressure steam obtained from stage 2,
4) using at least a part of the low pressure steam obtained directly from stage 1 as heat transporting fluid supplied to the reboiler of column C9, and at least a part of the medium pressure steam obtained from stage 2, after compression, as heat transporting fluid supplied to the reboilers of columns C7, C8, C10 and C11 of the complex, said columns forming a second set of columns E 2 distinct from E 1 .

2. The method for recovering heat according to claim 1 , in which part of the low pressure steam obtained from stage 1 is used to generate electricity.

3. The method for recovering heat according to claim 1 , in which stage 2 is carried out by means of a two-stage compressor.

4. The method for recovering heat according to claim 3 , in which stage 2 is carried out by means of an ejector using high pressure steam as motive fluid.

5. The method for recovering heat according to claim 1 , in which the low pressure steam obtained from stage 1, or the medium pressure steam obtained from stage 2, is used as heat transporting fluid in order to supply heat to combustion air of furnaces in air pre-heaters.

6. The heat recovery method according to claim 1 , comprising recovering heat from an aromatics complex with at least one extractive distillation unit (P 1 ), a paraxylene adsorption unit (P 2 ), a xylenes isomerisation unit (P 3 ) and a transalkylation unit (P 4 ), the effluents from the said units being separated in distillation columns denoted C1-C11 with the following meanings:
C1 reformate column, C2 xylenes column, C3 heavy aromatics column, C4 raffinate column, C5 extract column, C6 purification column, C7 deheptaniser, C8 stripper, C9 benzene column, C10 toluene column, C11 stabilization column, in which:
the low-temperature heat sources are distillation columns: C3, C4 or C5, which enable low pressure steam to be generated, said columns forming the set of columns E 1 ,
the columns to which the heat is supplied in the form of medium pressure steam after compression of low pressure steam generated by the set E 1 , or any sub-set thereof, and after reduction of operating pressure of the said columns C7, C8, C10, C11,
the column to which the heat generated by the set E 1 , or a sub-set thereof, is supplied without pressure reduction to the column C9, the columns C7, C8, C9, C10 and C11 forming the set E 2 .

Assignees

• Axens

Inventors

• Dunet Alain
• Prevost Isabelle
• Leflour Thierry

Classifications

• B01D3/007

  Energy recuperation; Heat pumps · CPC title

• B01D1/28 Primary

  with vapour compression · CPC title

• C10G45/58

  to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins (C10G32/00 takes precedence; improving or increasing the octane number or aromatic content of naphtha C10G35/00) · CPC title

• B01D1/2856

  The compressed vapour is used for heating a reboiler or a heat exchanger outside an evaporator · CPC title

• B01D3/146 Primary

  Multiple effect distillation · CPC title