Consumer goods product comprising functionalised lignin oligomer

Patent metadata

Field	Value
Publication number	US-9907742-B2
Application number	US-201615189016-A
Country	US
Kind code	B2
Filing date	Jun 22, 2016
Priority date	Jun 24, 2015
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

The present invention relates to a consumer goods product comprising a consumer goods product ingredient and a non-crosslinked functionalized lignin oligomer, wherein the functionalized lignin oligomer: (a) has an average number of lignin monomers of from 3 to 8; (b) comprises a polyethylene glycol functional group; (c) comprises a functionalization content between 90 and 0.5% lignin (m/m), wherein the consumer goods product ingredient is an emulsifier, and wherein the lignin oligomer is in the form of an emulsion, and wherein the consumer goods product is in the form of an oral care composition or a detergent composition.

First claim

What is claimed is:

1. A consumer goods product comprising a consumer goods product ingredient and a non-cross linked functionalised lignin oligomer, wherein the functionalised lignin oligomer:
(a) has an average number of lignin monomers of from about 3 to about 8;
(b) comprises a polyethylene glycol functional group;
(c) comprises a functionalisation content between about 90 and about 0.5% lignin (m/m),

wherein the consumer goods product ingredient is an emulsifier, and wherein the lignin oligomer is in the form of an emulsion,
and wherein the consumer goods product is in the form of an oral care composition or a detergent composition.

2. A consumer goods product according to claim 1 , wherein the functionalised lignin oligomer is non-crosslinked and comprises a functional group having the structure comprising the functional group:
lignin_backbone-O-L-‘PEG’

wherein ‘lignin_backbone’ is the lignin structural backbone;
wherein L is a linker; and
wherein ‘PEG’ is a polyethylene glycol,
wherein L has the chemical structure:

wherein R 1 and R 2 are independently selected from H and linear or branched, saturated or unsaturated, substituted or unsubstituted C 1 to C 18 alkyl;
wherein X is independently selected from R 1 , R 2 , hydroxyl, amine, ether and ester;
wherein L′ is a linking structural motif selected from linear or branched, saturated or unsaturated, substituted or unsubstituted C 1 to C 18 alkyl;
wherein ‘PEG’ is a polyethylene glycol;
or

wherein —C′-motif is a connecting motif selected from: —C(═O)—, —OC(═O)—, —C(═O)NR′—,
wherein R′ is selected from H, or C 1 -C 6 alkyl;
wherein L′ is a linking structural motif selected from linear or branched, saturated or unsaturated, substituted or unsubstituted C 1 to C 18 alkyl;
wherein ‘PEG’ is a polyethylene glycol.

3. A consumer goods product according to claim 1 , wherein the functionalised lignin oligomer is non-cross linked and comprises a functional group being linked via one of the following structural features:
(R 1 )(R 1 ′)C═C(R 2 )—N(R 2 )(R 3 ′)

wherein R 1 , R 1 ′ and R 2 are independently selected from hydrogen or lignin backbone, wherein at least one of R 1 , R 1 ′ and R 2 is lignin backbone,
wherein R 3 and R 3 ′ are both independently selected from saturated or unsaturated, linear or branched, substituted or unsubstituted C 1 -C 32 alkyl, wherein at least one of R 3 or R 3 ′ is bound to the ‘PEG’ polyethylene glycol;
or
(R 1 )(R 2 )C═N—R 3

wherein both R 1 and R 2 are independently selected from hydrogen or lignin backbone, wherein at least one of R 1 or R 2 is lignin backbone,
wherein R 3 is independently selected from saturated or unsaturated, linear or branched, substituted or unsubstituted C 1 -C 32 alkyl, wherein R 3 is bound to the ‘PEG’ polyethylene glycol.

4. A consumer goods product according to claim 1 , wherein the lignin oligomer comprises at least two different linking motifs.

5. A consumer goods product according to claim 1 , wherein the polyethylene glycol has a weight average molecular weight of from about 1,500 Da to about 10,000 Da.

6. A consumer goods product according to claim 1 , wherein the lignin oligomer has a weight average molecular weight ( M w ) in the range of from about 800 Da to about 5,000 Da.

7. A consumer goods product according to claim 1 , wherein the lignin oligomer has a number average molecular weight ( M n ) in the range of from about 800 Da to about 1,200 Da.

8. A consumer goods product according to claim 1 , wherein the lignin oligomer has an ester content in the range of from about 0.0 mmol/g to about 0.1 mmol/g.

9. A consumer goods product according to claim 1 , wherein the lignin oligomer is derived from corn, sugar cane, wheat and any combination thereof.

10. A consumer goods product according to claim 1 , wherein the consumer goods product comprises an emollient and/or humectant.

11. A consumer goods product according to claim 1 , wherein the consumer goods product comprises chitin and/or chitin derivatives.

Assignees

• Procter & Gamble

Inventors

• Massey Brooker Anju Deepali
• Vaccaro Mauro
• Scialla Stefano
• Crestini Claudia
• Lange Heiko

Classifications

• C11D7/44

  Vegetable products · CPC title

• C11D3/382

  Vegetable products, e.g. soya meal, wood flour, sawdust · CPC title

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title

• A61Q5/02 Primary

  Preparations for cleaning the hair · CPC title

• A61K8/736

  Chitin; Chitosan; Derivatives thereof · CPC title