Method and device for separating a mixture containing carbon dioxide by means of distillation

Patent metadata

Field	Value
Publication number	US-9903648-B2
Application number	US-201314384191-A
Country	US
Kind code	B2
Filing date	Mar 5, 2013
Priority date	Mar 13, 2012
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

According to certain embodiments of the invention, a gas containing at least 50% of carbon dioxide is cooled in a first exchanger so as to produce a cooled fluid, a liquid derived from the cooled fluid is sent to a distillation column to be separated therein, a head gas is withdrawn from the distillation column and reheated in the first exchanger, a vat liquid, which is richer in carbon dioxide than the gas containing at least 50% of carbon dioxide, is withdrawn and at least a portion thereof is heated in the first exchanger, at least a first portion of the vat liquid is vaporized in the first exchanger in order to produce a vaporized portion, the vaporized portion is sent back to the column and an NOx removal column is supplied with the liquefied cycle gas produced by vaporizing and reliquefying the vat liquid from the column.

First claim

The invention claimed is:

1. A process for the separation of a gas comprising carbon dioxide by distillation, the process comprising the steps of:
i) cooling the gas comprising carbon dioxide in a first exchanger to produce a first cooled fluid, wherein the gas comprising carbon dioxide is at least 50% carbon dioxide;
ii) withdrawing the cooled fluid from an intermediate level of the first exchanger and introducing the first cooled fluid to a stripping column under conditions effective for producing a liquid enriched in NOx at the bottom of the stripping column and a gas purified of NOx at the top of the stripping column;
iii) withdrawing the liquid enriched in NOx from the bottom of the stripping column;
iv) withdrawing the gas purified of NOx and cooling and partially condensing the gas purified of NOx in the first exchanger to form a second cooled fluid;
v) introducing a liquid derived from the second cooled fluid to a distillation column for separation therein;
vi) withdrawing a top gas from the distillation column and cheating the top gas in the first exchanger, wherein the top gas is enriched in oxygen and/or carbon monoxide with respect to the gas comprising carbon dioxide;
vii) withdrawing a bottom liquid from the distillation column, wherein the bottom liquid is enriched in carbon dioxide with respect to the gas comprising carbon dioxide, wherein the bottom liquid is at a third pressure;
viii) vaporizing a first portion of the bottom liquid in the first exchanger to produce a vaporized portion and returning the vaporized portion to the distillation column;
ix) mixing a second portion of the bottom liquid with an expanded liquefied cycle gas to form a mixed cycle gas;
x) dividing the mixed cycle gas into at least a first fraction and a second fraction and vaporizing the first fraction and the second fraction in the first exchanger, wherein the first fraction is at a first pressure that is lower than the third pressure when vaporized in the first exchanger, wherein the second fraction is at a second pressure that is equal to or lower than the third pressure when vaporized in the first exchanger;
xi) pressurizing the vaporized first fraction to the third pressure and combining the first fraction with at least the vaporized second fraction to form a final gas mixture;
xii) compressing the final gas mixture in a compressor and then condensing the compressed final gas mixture to form a liquid cycle fluid;
xiii) dividing the liquid cycle fluid into a liquid product and a liquefied cycle gas;
xiv) cooling the liquefied cycle gas in the first exchanger and expanding a first portion of the liquefied cycle gas to the third pressure to form the expanded liquefied cycle gas; and
xv) feeding the top of the stripping column with a second portion of the liquefied cycle gas.

2. A process as claimed in claim 1 , wherein the stripping column comprises an absence of a bottom reboiler or top condenser.

3. A process as claimed in claim 1 , wherein the distillation column comprises an absence of a bottom reboiler.

4. A process as claimed in claim 1 , wherein all of the bottom liquid from the distillation column is vaporized solely in the first exchanger.

5. The process as claimed in claim 1 , wherein the heated top gas from step vi) is mixed with the gas comprising carbon dioxide upstream of the first exchanger.

6. The process as claimed in claim 1 , wherein a gas derived from the second cooled fluid from step iv) is heated in the first exchanger and is reduced in pressure in a turbine.

7. The process as claimed in claim 1 , wherein the gas comprising carbon dioxide originates from an oxy-combustion boiler and a the liquid enriched in NOx from the bottom of the stripping column is returned to the oxy-combustion boiler.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Briglia Alain
• Darde Arthur
• Lockwood Frederick
• Traversac Xavier

Classifications

• F25J2200/78

  Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column · CPC title

• F25J2270/80

  Quasi-closed internal or closed external carbon dioxide refrigeration cycle · CPC title

• F25J2205/04

  in the feed line, i.e. upstream of the fractionation step · CPC title

• F25J2220/84

  Separating high boiling, i.e. less volatile components, e.g. NOx, SOx, H2S · CPC title

• F25J2245/02

  Recycle of a stream in general, e.g. a by-pass stream · CPC title