Acid-soluble cement compositions comprising cement kiln dust and/or a natural pozzolan and methods of use
US-9023150-B2 · May 5, 2015 · US
US9903184B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9903184-B2 |
| Application number | US-201514713752-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 15, 2015 |
| Priority date | Sep 9, 2005 |
| Publication date | Feb 27, 2018 |
| Grant date | Feb 27, 2018 |
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Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.
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What is claimed is: 1. A method of evaluating a plurality of spacer fluids for use in separating a drilling fluid and a cement composition in a well bore comprising: providing the cement composition; measuring a transition time and/or zero gel time of the cement composition; providing the plurality of spacer fluids wherein each one of the plurality of spacer fluids comprises at least one kiln dust selected from the group consisting of cement kiln dust, lime kiln dust, and combinations thereof; measuring a transition time and/or zero gel time of each of the spacer fluids; selecting a spacer fluid from the plurality of spacer fluids, the selected spacer fluid having a zero gel time that is greater than the zero gel time of the cement composition and a transition time that is less than the transition time of the cement composition; and using the selected spacer fluid to separate the drilling fluid and the cement composition in a well bore. 2. The method of claim 1 wherein the transition time of the selected spacer fluid is about 45 minutes or less at well bore conditions. 3. The method of claim 1 wherein the transition time of the selected spacer fluid is about 20 minutes or less at a temperature in a range of from about 40° F. to about 300° F. and a pressure in a range of from about 2,000 psi to about 10,000 psi. 4. The method of claim 1 wherein the zero gel time of the selected spacer fluid is about 4 hours or less at well bore conditions. 5. The method of claim 1 wherein at least one of the spacer fluids comprises at least one cementitious material selected from the group consisting of Portland cement, Portland cement interground with pumice, micro-fine cement, slag, fly ash, rice husk ash, pumicite, gypsum, and any combination thereof. 6. The method of claim 1 wherein the selected spacer fluid is foamed. 7. The method of claim 1 wherein the selected spacer fluid has a density in a range of from about 4 pounds per gallon to about 13 pounds per gallon. 8. The method of claim 1 wherein the kiln dust is present in the selected spacer fluid in an amount in a range of from about 1% to about 60% by weight of the selected spacer fluid. 9. The method of claim 1 wherein the selected spacer fluid comprises at least one additive selected from the group consisting of a free water control additive, a lightweight additive, a foaming agent, a supplementary cementitious material, a weighting agent of any suitable size, a viscosifying agent, a fluid loss control agent, a lost circulation material, a filtration control additive, a dispersant, a defoamer, a corrosion inhibitor, a scale inhibitor, a formation conditioning agent, a water-wetting surfactant, and any combination thereof. 10. The method of claim 1 wherein the selected spacer fluid comprises at least one additive selected from the group consisting of kiln dust, gypsum, fly ash, bentonite, hydroxyethyl cellulose, sodium silicate, a hollow microsphere, gilsonite, perlite, a gas, an organic polymer, a biopolymer, latex, ground rubber, a surfactant, crystalline silica, amorphous silica, silica flour, fumed silica, nano-clay, salt, fiber, hydratable clay, rice husk ash, micro-fine cement, metakaolin, zeolite, shale, pumicite, Portland cement, Portland cement interground with pumice, barite, slag, lime, and any combination thereof. 11. The method of claim 1 wherein the selected spacer fluid comprises at least one cementitious material selected from the group consisting of Portland cement, Portland cement interground with pumice, micro-fine cement, slag, fly ash, rice husk ash, pumicite, gypsum, and any combination thereof. 12. A method of evaluating a plurality of spacer fluids for use in separating a drilling fluid and a cement composition in a well bore comprising: providing the cement composition; measuring a transition time and zero gel time of the cement composition; providing the plurality of spacer fluids; measuring a transition time and zero gel time of each of the spacer fluids; selecting a spacer fluid from the plurality of spacer fluids, the selected spacer fluid having a zero gel time that is greater than the zero gel time of the cement composition and a transition time that is less than the transition time of the cement composition, wherein the selected spacer fluid comprises cement kiln dust; and using the selected spacer fluid to separate the drilling fluid and the cement composition in a well bore. 13. The method of claim 12 wherein the transition time of the selected spacer fluid is about 45 minutes or less at well bore conditions. 14. The method of claim 12 wherein at least one of the spacer fluids comprises at least one cementitious material selected from the group consisting of Portland cement, Portland cement interground with pumice, micro-fine cement, slag, fly ash, rice husk ash, pumicite, gypsum, and any combination thereof. 15. The method of claim 12 wherein the selected spacer fluid is foamed. 16. The method of claim 12 wherein the cement kiln dust is present in the selected spacer fluid in an amount in a range of from about 1% to about 60% by weight of the selected spacer fluid. 17. The method of claim 12 wherein the selected spacer fluid comprises at least one additive selected from the group consisting of a free water control additive, a lightweight additive, a foaming agent, a supplementary cementitious material, a weighting agent of any suitable size, a viscosifying agent, a fluid loss control agent, a lost circulation material, a filtration control additive, a dispersant, a defoamer, a corrosion inhibitor, a scale inhibitor, a formation conditioning agent, a water-wetting surfactant, and any combination thereof. 18. The method of claim 12 wherein the selected spacer fluid comprises at least one additive selected from the group consisting of kiln dust, gypsum, fly ash, bentonite, hydroxyethyl cellulose, sodium silicate, a hollow microsphere, gilsonite, perlite, a gas, an organic polymer, a biopolymer, latex, ground rubber, a surfactant, crystalline silica, amorphous silica, silica flour, fumed silica, nano-clay, salt, fiber, hydratable clay, rice husk ash, micro-fine cement, metakaolin, zeolite, shale, pumicite, Portland cement, Portland cement interground with pumice, barite, slag, lime, and any combination thereof. 19. The method of claim 12 wherein the selected spacer fluid comprises at least one cementitious material selected from the group consisting of Portland cement, Portland cement interground with pumice, micro-fine cement, slag, fly ash, rice husk ash, pumicite, gypsum, and any combination thereof. 20. A method of evaluating a plurality of spacer fluids for use in separating a drilling fluid and a cement composition in a well bore comprising: providing the cement composition; measuring a transition time and/or zero gel time of the cement composition; providing the plurality of spacer fluids, wherein at least of the plurality of spacer fluids comprises cement kiln dust; measuring a transition time and zero gel time of each of the spacer fluids; selecting a spacer fluid from the plurality of spacer fluids, the selected spacer fluid having a zero gel time that is greater than the zero gel time of the cement composition and a transition time that is less than the transition time of the cement composition, wherein the cement kiln dust is present in the selected spacer fluid in an amount in a range of from about 1% to about 60% by weight of the selected spacer fluid, wherein the transition time of the selected spacer fluid
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