Thermal and/or acoustic insulation materials shaped from silica

Patent metadata

Field	Value
Publication number	US-9903109-B2
Application number	US-201514834044-A
Country	US
Kind code	B2
Filing date	Aug 24, 2015
Priority date	Jun 30, 2003
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

Thermal and/or acoustic insulation materials based on dried precipitated silica, having a total pore volume of from 1 to 5 cm3/g and optionally containing reinforcing fillers and/or opacifying agents, are prepared by: (A) filtering an aqueous dispersion D containing precipitated silica particles in a filter press, whereby a compacted filter cake is obtained; and then (B) drying the filter cake in the compacted state as obtained after step (A).

First claim

The invention claimed is:

1. A method of preparing a thermal and/or acoustic insulation material based on dried precipitated silica, comprising:
(A) filtering an aqueous dispersion D containing precipitated silica particles in a filter press, whereby a compacted filter cake is obtained by a compacting operation performed at a pressure of about 7 bar or less; and
(B) drying the filter cake in the compacted state as obtained after step (A) wherein the thermal and/or acoustic insulation material has a content of dried precipitated silica comprising at least 50% by weight of the insulation material and wherein the thermal and/or acoustic insulation material has a total pore volume of between 1 cm 3 /g and 5 cm 3 /g, at least 40% of the total pore volume consists of pores smaller than 1,000 nm and at least 50% of the pore volume of pores smaller than 1,000 nm consists of pores smaller than 100 nm.

2. The method of claim 1 , wherein the compacting operation is performed at a pressure of between about 2 and about 7 bar.

3. The method of claim 1 , wherein step (A) comprises:
(A1) a filtration operation at a pressure of about 0.5 to about 2 bar; and
(A2) the compacting operation carried out on the filter cake obtained at a pressure of between about 2 and about 7 bar.

4. The method of claim 1 , wherein the compacted filter cake obtained after step (A) has a solids content of between 10 and 35% by weight.

5. The method of claim 1 , wherein the aqueous dispersion D used in step (A) contains a precipitated silica which, once dried, has a BET specific surface area of between 80 and 400 m 2 /g and a CTAB specific surface area of between 80 and 350 m 2 /g.

6. The method of claim 1 , wherein the aqueous dispersion D used in step (A) further contains a reinforcing filler.

7. The method of claim 6 , wherein said reinforcing filler comprises reinforcing fibers selected from aluminum silicate fibers, alumina fibers, mineral wool fibers, glass fibers, quartz fibers, ceramic fibers, polymer fibers and cellulose fibers.

8. The method of claim 6 , wherein the (silica/reinforcing filler) mass ratio within the aqueous dispersion D is between 75/25 and 99/1 by weight.

9. The method of claim 1 , wherein the aqueous dispersion D used in step (A) further contains an opacifying agent capable of reflecting, absorbing and/or dispersing at least part of the infrared radiation.

10. The method of claim 9 , wherein the opacifying agent is selected from the group consisting of chromium oxide, zirconium oxide, iron oxide, titanium dioxide, manganese dioxide, ilmenite, quartz powder, silicon carbide, boron carbide, tantalum carbide, carbon black and graphite.

11. The method of claim 9 , wherein the (silica/opacifying agent) mass ratio is between 50/50 and 99/1 within the aqueous dispersion D.

12. The method of claim 1 , wherein step (B) is carried out by allowing the compacted filter cake obtained after step (A) to dry at a temperature of between 10 and 30° C.

13. The method of claim 1 , wherein step (B) is carried out by subjecting the compacted filter cake obtained after step (A) to a progressive temperature rise from room temperature up to a temperature of at least 100° C., at a rate of temperature rise of less than 2° C. per minute, optionally with the temperature being held at one, two or more intermediate temperature levels.

14. The method of claim 1 , wherein the pressure in step (A) is less than about 6 bar.

15. The method of claim 1 , wherein the insulation material comprises at least 75% by weight of the dried filter cake.

16. The method of claim 1 , wherein the insulation material has a total pore volume of at least 2.0 cm 3 /g, and wherein at least 70% of the total pore volume consists of pores smaller than 1,000 nm.

17. The method of claim 1 , wherein at least 70% of the pore volume of pores smaller than 1,000 nm consists of pores smaller than 100 nm.

Assignees

• Rhodia Operations
• Rhodia Chimie Sa

Inventors

• Hernandez Julien
• Enjalbert Catherine

Classifications

• E04B1/74 Primary

  Heat, sound or noise insulation, absorption, or reflection (forms of, or arrangements in, rooms for influencing or directing sound E04B1/99); Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls (fire protection E04B1/94; elements chiefly adapted for structural purposes E04C1/00 - E04C3/00; chiefly adapted for surface coverings E04F13/00; as underlayers for floor coverings E04F15/18; closures for wall or like openings E06B) · CPC title

• C04B14/062

  Microsilica, e.g. colloïdal silica (preparing microsilica slurries or suspensions C04B18/148) · CPC title

• C04B20/0048

  Fibrous materials · CPC title

• C04B2103/56

  Opacifiers · CPC title

• C04B40/0071

  making use of a rise in pressure · CPC title