Polyphase biodegradable compositions containing at least one polymer of vegetable origin

Patent metadata

Field	Value
Publication number	US-9902844-B2
Application number	US-201113814420-A
Country	US
Kind code	B2
Filing date	Aug 5, 2011
Priority date	Aug 6, 2010
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

Polyphase biodegradable compositions having a good resistance to ageing comprising a continuous phase comprising at least one hydrophobic polyester and at least one dispersed phase of polymer of vegetable origin. The hydrophobic polyester constituting the continuous phase is incompatible with the polymer of vegetable origin. The compositions comprise a plasticizer comprising at least 75% of a mixture of diglycerol, triglycerol and tetraglycerol.

First claim

The invention claimed is:

1. A film produced from a polyphase biodegradable composition having a good resistance to aging comprising:
(a) a continuous phase comprising at least one hydrophobic polyester,
(b) at least one dispersed phase comprising at least one polymer of vegetable origin,

in which the hydrophobic polyester of the continuous phase is an aliphatic aromatic polyester of the diacid-diol type with a content of aromatic units of from 45 to 70 mol % and is incompatible with the polymer of vegetable origin, said polymer of vegetable origin being starch, said composition comprising 2 to 70% by weight, with respect to the weight of the polymer of vegetable origin, of a plasticizer comprising at least 75 wt %, with respect to the total weight of said plasticizer, of a mixture of diglycerol, triglycerol and tetraglycerol, and less than 10% by weight of glycerin; wherein:
the composition comprises from 45 to 98% by weight of component (a) and from 2 to 55% by weight of component (b) with respect to the sum of components (a) and (b);
the aliphatic-aromatic polyester comprises as the aliphatic acid an acid selected from the group consisting of adipic acid, succinic acid, azelaic acid, sebacic acid, undecandioic acid, dodecandioic acid and brassylic acid;
the aliphatic-aromatic acid comprises terephthalic acid as the aromatic acid;
the composition comprises from 1 to 40% by weight of a further dispersed phase comprising a polyhydroxyalkanoate which is rigid in comparison with the hydrophobic polyester of the continuous phase, with a Young's modulus of more than at least 300%; and
wherein the polymer composition exhibits an Elmendorf tear strength of more than 60 N/mm in the transverse direction upon filming.

2. The polyphase biodegradable composition according to claim 1 , in which the hydrophobic polyester is biodegradable according to standard EN 13432.

3. The polyphase biodegradable composition according to claim 1 in which the starch is flour, natural starch, chemically and/or physically modified starch, hydrolysed starch, destructured starch, gelatinised starch, plasticised starch, thermoplastic starch or mixtures thereof.

4. The polyphase biodegradable composition according to claim 1 in which the polyhydroxyalkanoate is a polymer or copolymer of polylactic acid containing at least 75% of L-lactic or D-lactic acid or combinations thereof having a molecular weight M w of more than 70,000 and a Young's modulus of more than 1,500 MPa.

5. The polyphase biodegradable composition according to claim 1 in which the plasticiser comprises at least 90% of a mixture of diglycerol, triglycerol and tetraglycerol.

6. The polyphase biodegradable composition according to claim 5 in which said mixture contains more than 50% by weight of diglycerol with respect to the sum of the di-, tri- and tetraglycerol.

7. The polyphase biodegradable composition according to claim 1 in which the diglycerol comprises at least 70% by weight of alpha-alpha diglycerol.

8. Bags and envelopes in general produced using the film according to claim 1 , being selected from the group consisting of extruded and thermoformed bags and envelopes, laminated with board, aluminium, plastics or bioplastics, and multiply perforated bags and envelopes.

Assignees

• Capuzzi Luigi
• Novamont Spa

Inventors

• Capuzzi Luigi

Classifications

• Y10T428/1334

  Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.] · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• Y10T428/1338

  Elemental metal containing · CPC title

• C08K5/06

  Ethers; Acetals; Ketals; Ortho-esters · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title