Dispersion method for particles in nanocomposites and method of forming nanocomposites

Patent metadata

Field	Value
Publication number	US-9902819-B2
Application number	US-55894109-A
Country	US
Kind code	B2
Filing date	Sep 14, 2009
Priority date	Sep 14, 2009
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A method of manufacturing a nanocomposite includes exposing dry nanoparticles to a dry, solid matrix material or pellets in a container to form a combination which is then agitated by rotating about an axis transverse to a direction of gravity, at room temperature and without grinding objects, to cause a tumbling action between the pellets and the nanoparticles to thereby evenly disperse and coat the nanoparticles directly on outer surfaces of the pellets which remain in a solid phase and of the same size throughout rotating. The method also includes processing the resulting combination, particularly polypropylene pellets and carbon black nanoparticles, by heating to form a viscous combination which is then drawn to form a nanocomposite fiber having carbon black nanoparticles dispersed evenly throughout the polypropylene, with a resulting fiber having a diameter of 30 μm-100 μm and tensile strength of 300-1500% greater than a similar polypropylene fiber produced without the nanoparticles.

First claim

What is claimed is:

1. A method of manufacturing a nanocomposite comprising:
drying a plurality of solid pellets at approximately 125° F. for approximately 24 hours to generate dry solid pellets, wherein the pellets are polypropylene pellets;
exposing a plurality of dry nanoparticles of carbon black to the plurality of dry pellets in a container to form a combination of the nanoparticles and the pellets, the nanoparticles each having at least one dimension that is at most 100 nanometers, the pellets each being individually millimeters in width, and wherein the nanoparticles are at most 1% of the total weight of the combination;
rotating the container including the combination for approximately 24 hours at room temperature about an axis that is transverse to a direction of gravity to cause a tumbling action between the pellets and nanoparticles to thereby evenly disperse and coat the nanoparticles evenly and directly on outer surfaces of the pellets, the pellets remaining in a solid phase and remaining the same size throughout an entire duration of the rotating of the combination, wherein grinding objects are not included in the container during the rotating; and
heating the combination to form a viscous combination having the nanoparticles dispersed in the polypropylene pellets that is viscous; and
drawing the viscous combination to form a nanocomposite fiber having the nanoparticles dispersed evenly throughout the fiber, wherein the nanocomposite fiber has a diameter of from 30 μm to 100 μm and a tensile strength that is from 300% to 1500% greater than a tensile strength of a similar fiber created by the same method and with the same polypropylene pellets, but without nanoparticles.

2. The method of claim 1 , further comprising choosing an amount of the nanoparticles to be exposed to the pellets according to an affinity of the nanoparticles to disperse evenly on the pellets due to the rotating of the combination.

3. The method of claim 1 , further comprising choosing an amount of the nanoparticles to be exposed to the pellets according to a total outer surface area of the pellets to achieve a predetermined surface to volume ratio of the combination.

4. The method of claim 1 , further comprising choosing an amount of time for rotating the combination according to an affinity of the nanoparticles to disperse evenly on the pellets due to the rotating of the combination.

Assignees

• Filisko Frank
• Juggernauth Kaajal Raj
• Waas Anthony
• Filisko Doris
• Univ Michigan Regents

Inventors

• Filisko Frank
• Juggernauth Kaajal Raj
• Waas Anthony

Classifications

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• B29L2031/731

  Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres (cables B29L2031/707) · CPC title

• B29C47/54

  Operations & Transport · mapped topic

• B29C47/0014

  Operations & Transport · mapped topic

• C08J5/005 Primary

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title