Energy efficient naphthene recycle via the use of a side draw fractionation tower and partial condensation

Patent metadata

Field	Value
Publication number	US-9902666-B2
Application number	US-201415105693-A
Country	US
Kind code	B2
Filing date	Nov 20, 2014
Priority date	Dec 17, 2013
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

Processes for the energy efficient recycle of naphthenes in a paraxylene manufacturing process comprise partially condensing a reactor effluent and using a sidedraw tower apparatus. The naphthenes are efficiently separated into the sidedraw stream of the sidedraw tower apparatus. At least a portion of the sidedraw stream is directed to a paraxylene recovery section that produces a paraxylene product and a paraxylene lean stream comprising essentially all of the naphthenes in the sidedraw stream directed to the paraxylene recovery section. The paraxylene lean stream is recycled back to the reactor thereby preventing excessive loss of naphthenes from the processes.

First claim

What is claimed is:

1. A process for recycling naphthenes to a reactor, the process comprising:
reacting in the reactor a reactor feed stream comprising xylene isomers, ethylbenzene, C8 naphthenes, and hydrogen over an ethylbenzene isomerization catalyst at reactor conditions wherein at least a portion of the ethylbenzene in the reactor feed stream is converted to xylene isomers, such that a reactor effluent stream comprising xylene isomers and C8 naphthenes is produced;
cooling and separating the reactor effluent stream to form a first condensed liquid stream and a first vapor stream;
cooling and separating the first vapor stream to form a second condensed liquid stream and a second vapor stream;
providing the first condensed liquid stream and the second condensed liquid stream to a sidedraw tower apparatus to produce a sidedraw stream comprising C8 aromatics and C8 naphthenes;
recovering paraxylene from the sidedraw stream in a paraxylene recovery section; producing a paraxylene lean stream, wherein the paraxylene lean stream contains a portion of the C8 naphthenes; and
recycling the paraxylene lean stream to the reactor.

2. The process of claim 1 , wherein the first condensed liquid stream is provided to the sidedraw tower apparatus at a location below the sidedraw stream, and wherein the second condensed liquid stream is provided to the sidedraw tower apparatus at a location above the sidedraw stream.

3. The process of claim 1 , wherein a portion of the first condensed liquid stream is provided to a location above the sidedraw stream.

4. The process of claim 1 , wherein a portion of the second condensed liquid stream is provided to a location below the sidedraw stream.

5. The process of claim 1 , wherein a portion of the sidedraw stream is recycled to a location below the sidedraw stream.

6. The process of claim 1 , wherein the ethylbenzene isomerization catalyst comprises an acid catalyst and a strong hydrogenation catalyst capable of hydrogenating and dehydrogenating aromatic rings in the reactor feed stream to form a near equilibrium distribution of aromatics and naphthenes.

7. The process of claim 1 , further comprising
preheating a liquid stream comprising ethylbenzene, xylene isomers, and C8 naphthenes to form a preheated liquid stream;
combining the preheated liquid stream with a recycle gas stream comprising hydrogen to form the reactor feed stream; and
providing the reactor feed stream to the reactor.

8. The process of claim 7 , wherein the liquid stream is preheated with the sidedraw stream.

9. The process of claim 8 , wherein the liquid stream is preheated with the first vapor stream.

10. The process of claim 1 , further comprising recycling the second vapor stream to the reactor.

11. The process of claim 1 , wherein the mass of the first condensed liquid stream is less than about 70 percent of the sum the masses of the first condensed liquid stream and the second condensed liquid stream.

12. The process of claim 1 , further comprising separating greater than 70 percent of the C8 naphthenes in the reactor effluent stream into the paraxylene lean stream.

13. The process of claim 1 , wherein the sidedraw tower apparatus comprises a single distillation tower.

14. The process of claim 1 , wherein the sidedraw tower apparatus comprises more than one distillation tower.

15. The process of claim 1 , further comprising:
producing in the sidedraw tower apparatus an overhead vapor stream comprising light ends, an overhead liquid stream comprising C7-hydrocarbons, a bottoms stream comprising C9+ hydrocarbons, and the sidedraw stream comprising C8 aromatics and containing greater than 70 percent of the C8 naphthenes from the reactor effluent stream.

16. An apparatus for recycling naphthenes to a reactor, the apparatus comprising:
a preheater for preheating a liquid stream comprising ethylbenzene, xylene isomers, and C8 naphthenes to form a preheated liquid stream, wherein the preheated liquid stream is combined with a recycle gas stream comprising hydrogen to form a reactor feed stream;
a reactor for reacting the reactor feed stream to produce a reactor effluent stream comprising xylene isomers and C8 naphthenes;
a first cooling apparatus for cooling the reactor effluent stream to produce a cooled reactor effluent stream;
a first separator drum for separating the cooled reactor effluent stream into a first condensed liquid stream and a first vapor stream;
a second cooling apparatus for cooling the first vapor stream to produce a cooled first vapor stream comprising a vapor phase and liquid phase;
a second separator drum for separating the cooled first vapor stream into a second condensed liquid stream and a second vapor stream;
a sidedraw tower apparatus for receiving the first condensed liquid stream and the second condensed liquid stream and producing a sidedraw stream, wherein the sidedraw stream comprises C8 aromatics and greater than 70 percent of the C8 naphthenes;
a paraxylene recovery section for separating the sidedraw stream into a paraxylene product stream and a paraxylene lean stream, wherein the paraxylene lean stream comprises C8 naphthenes from the sidedraw stream; and
a recycling apparatus for recycling the paraxylene lean stream to the reactor.

17. The apparatus of claim 16 , wherein the sidedraw tower apparatus comprises a single distillation tower.

18. The apparatus of claim 16 ,
wherein the sidedraw tower apparatus comprises a bottom tower and a top tower, and
wherein an overhead vapor stream from the bottom tower is provided to the bottom of the top tower and the sidedraw stream is produced as a bottoms liquid stream of the top tower.

Assignees

• Bp Corp North America Inc

Inventors

• Amelse Jeffrey

Classifications

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07C5/277 Primary

  Catalytic processes · CPC title

• C07C5/2702 Primary

  Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• C07C7/09

  by fractional condensation · CPC title