Process and plant for producing olefins from oxygenates

Patent metadata

Field	Value
Publication number	US-9902659-B2
Application number	US-201414768575-A
Country	US
Kind code	B2
Filing date	Feb 4, 2014
Priority date	Feb 18, 2013
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A process for producing olefins from oxygenates includes the following steps:
(i) heterogeneously catalyzed conversion of at least one oxygenate to a stream containing propylene, aromatics and cyclic olefins, (ii) at least partial hydrogenation of the aromatics and cyclic olefins to naphthenes, and (iii) at least partial recirculation of the naphthenes into the heterogeneously catalyzed conversion.

First claim

The invention claimed is:

1. A process for producing olefins from oxygenates, the process comprising the following steps:
(i) converting, by heterogeneous catalysis, at least one oxygenate to a stream containing propylene, aromatics, and cyclic olefins;
(ii) separating the stream containing propylene, aromatics, and cyclic olefins into a C 5− fraction containing propylene, a C 5+ fraction containing aromatics and cyclic olefins, and an aqueous fraction containing oxygenates, wherein at least parts of the C 5+ fraction are supplied to a hydrogenation in step (iii);
(iii) at least partially hydrogenating the at least parts of the C 5+ fraction containing aromatics and cyclic olefins to obtain naphthenes; and
(iv) at least partially recirculating the naphthenes into the heterogeneously catalyzed conversion in step (i).

2. The process according to claim 1 , wherein hydrogen is used as hydrogenating agent in step (iii).

3. The process according to claim 2 , wherein the hydrogenation is carried out such that parts of a product stream of the hydrogenation are recirculated into the hydrogenation, and that a ratio between the recirculated product stream of the hydrogenation and the at least parts of the C 5+ fraction containing aromatics and cyclic olefins lies between 1:10 and 10:1 and/or a molar excess of hydrogen lies between 200 and 5000% of the quantity theoretically necessary for the complete saturation of all contained double and aromatic bonds.

4. The process according to claim 2 , wherein after step (iv) hydrogen is separated from a product stream of the hydrogenation.

5. The process according to claim 1 , wherein from the aqueous fraction containing oxygenates, the oxygenates and water are separated.

6. The process according to claim 5 , wherein the separated oxygenates and/or the separated water are/is at least partly recirculated into step (i).

7. The process according to claim 6 , wherein the heterogeneously catalyzed conversion is effected in two stages, wherein in the first stage methanol is converted into dimethyl ether and in the second stage dimethyl ether is converted to a stream containing propylene, aromatics and cyclic olefins, and wherein methanol is recirculated to before the first stage and/or water is recirculated in the form of steam to before the second stage.

8. The process according to claim 1 , wherein step (ii) further comprising separating the C 5+ fraction into a C 7− fraction and a C 7+ fraction, and at least parts of the C 7+ fraction are supplied to step iii and at least parts of the C 7− fraction are recirculated to step (i).

9. A process for producing olefins from oxygenates, the process comprising the following steps:
(i) converting, by heterogeneous catalysis, at least one oxygenate to a stream containing propylene, aromatics, and cyclic olefins;
(ii) separating the stream containing propylene, aromatics, and cyclic olefins into a C 7− fraction containing propylene and a C 7+ fraction containing aromatics and cyclic olefins, wherein at least parts of the C 7+ fraction are supplied to a hydrogenation in step (iii);
(iii) at least partially hydrogenating the at least parts of the C 7+ fraction containing aromatics and cyclic olefins to obtain naphthenes; and
(iv) at least partially recirculating the naphthenes into the heterogeneously catalyzed conversion in step (i).

10. The process according to claim 9 , wherein at least parts of the C 7− fraction are recirculated into step (i).

11. The process according to claim 9 , wherein the heterogeneously catalyzed conversion is effected in two stages, wherein in the first stage methanol is converted into dimethyl ether and in the second stage dimethyl ether is converted to a stream containing propylene, aromatics and cyclic olefins, and wherein at least parts of the C 7− fraction are recirculated after the first stage and before the second stage.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Rothaemel Martin
• Olindo Roberta
• Haag Stephane
• Renner Thomas
• CASTILLO WELTER Frank

Classifications

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• B01J19/245

  placed in series · CPC title

• C10G45/44

  Hydrogenation of the aromatic hydrocarbons · CPC title

• C10G3/42

  Catalytic treatment · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title