Production of fibre composite component part based on steel and polyurethane

Patent metadata

Field	Value
Publication number	US-9902095-B2
Application number	US-201514705485-A
Country	US
Kind code	B2
Filing date	May 6, 2015
Priority date	May 6, 2014
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A method of producing a fiber composite component part, contains the following steps: a) providing two or more steel sheets; b) providing at least one textile fabric; c) providing an anhydrous mixture having one or more than one hardener containing a uretdione having an NCO functionality of not less than two, one or more than one binder having hydroxyl groups to an OH functionality of three to six, and one or more than one cobinder having oxirane groups; d) coating the textile fabric with the mixture; e) applying energy to the mixture-coated fabric for the purpose of performing a first crosslinking reaction to react hardener, binder and cobinder to form a thermoplastic polymer adhering to the textile fabric; f) hot pressing the steel sheets and the textile fabric together with the thermoplastic polymer adhering thereto into a sandwich such that the thermoplastic polymer joins the steel sheets together while enclosing the textile fabric; g) forming the sandwich into a shaped article; h) heat treating the shaped article to obtain the fiber composite component part, wherein the thermoplastic polymer undergoes a second crosslinking reaction to convert into a thermoset polymer.

First claim

The invention claimed is:

1. A method of producing a fibre composite component part, comprising:
a) preparing an anhydrous mixture comprising:
at least one hardener comprising a uretdione having an NCO functionality of not less than two,
at least one binder having hydroxyl groups and an OH functionality of three to six, and
at least one cobinder having oxirane groups:

b) coating a textile fabric with the anhydrous mixture, to obtain a mixture-coated fabric;
c) applying energy to the mixture-coated fabric to obtain a first crosslinking reaction of the hardener, binder and cobinder to form a thermoplastic polymer adherred to the textile fabric;
d) hot pressing two steel sheets and the textile fabric together with the thermoplastic polymer adherred thereto into a sandwich such that the thermoplastic polymer contacts a metal surface of the steel sheets and joins the steel sheets together while enclosing the textile fabric;
e) forming the sandwich into a shaped article; and
f) heat treating the shaped article to obtain the fibre composite component part, wherein the thermoplastic polymer undergoes a second crosslinking reaction to convert into a thermoset polymer.

2. The method according to claim 1 , wherein the anhydrous mixture is a dry pulverulent mixture and is sprinkled onto the textile fabric in the coating b).

3. The method according to claim 1 , wherein the anhydrous mixture is a solution an organic solvent, and coating b) further comprises impregnating the textile fabric with the solution, and subsequently removing the solvent from the textile fabric by evaporation.

4. The method according to claim 3 , wherein the evaporation of the solvent and the application of energy to the mixture to obtain the first crosslinking reaction c) is carried out in one operation by heating at a temperature of 80° C. to 160° C., where heating time is in the range from 10 minutes to 30 minutes.

5. The method according to claim 1 , wherein hot-pressing the steel sheets and the textile fabric together with the thermoplastic polymer adherent thereto into the sandwich d) is at a temperature of 80° C. to 180° C., a duration time for the heating is from 3 minutes to 20 minutes.

6. The method according to claim 1 , wherein the forming of the sandwich into the shaped article is carried out at a temperature of 20° C. to 160° C.

7. The method according to claim 1 , wherein the heat treatment of the shaped article for the purpose of performing the second crosslinking reaction takes place at a temperature of 170° C. to 210° C., wherein said heat treatment of the shaped article takes place at a temperature which is not less than 20° C. higher than the temperature at which the first crosslinking reaction is carried out, wherein the thermal treatment is carried out for a period of 20 minutes to 60 minutes.

8. The method according to claim 1 , wherein the steel sheets comprise a steel such that the heat treatment of the shaped article causes a phase structure change of the steel and/or rearrangement entailing an increase in the strength of the steel.

9. The method according to claim 1 , wherein the steel sheets comprise a corrosion-resistant coat.

10. The method according to claim 1 , wherein the hardener is free of a blocking agent and comprises a uretdione of a diisocyanate selected from the group consisting of isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), diisocyanatodicyclohexylmethane (H12MDI), 2-methylpentane diisocyanate (MPDI), 2,2,4-trimethylhexamethylene diisocyanate/2,4,4-trimethylhexamethylene diisocyanate (TMDI) mixture, and norbornane diisocyanate (NBDI).

11. The method according to claim 1 , wherein the binder comprises at least one polyol compound.

12. The method according to claim 1 , wherein the binder comprises at least one polyester with an OH number of between 25 and 400, with an acid number of not more than 2 mg KOH/g and with a molar mass of between 1000 and 4000 g/mol.

13. The method according to claim 1 , wherein the binder comprises at least one polycaprolactone with an OH number between 540 and 25, with an acid number between 0.5 and 1 mg KOH/g and with a molar mass is between 240 and 1000 g/mol.

14. The method according to claim 1 , wherein an epoxy equivalent weight (EEW) of the cobinder is from 182 to 940 g/eq.

15. The method according to claim 1 , wherein the cobinder comprises an epoxy resin selected from the group consisting of epoxy resin based on bisphenol A diglycidyl ether, epoxy resin based on bisphenol F diglycidyl ether and a cycloaliphatic compound.

16. The method according to claim 1 , wherein the anhydrous mixture is free from a substance that has a catalytic effect on the first and/or second crosslinking reaction.

17. The method according to claim 1 , wherein the textile fabric comprises a woven fabric, a non-crimp fabric, a knitted fabric or a nonwoven fabric of carbon fibre, glass fibre or aramid fibre.

18. The method according to claim 1 , wherein operations a) to f), up to and including the stage of the sandwich being obtained, are carried out as a continuous roll-to-roll process.

19. The method according to claim 1 , wherein the sandwich obtained as per step f) is immediately or only after a pause of 1 to 6 months formed into a shaped article as per step g).

Assignees

• Evonik Degussa Gmbh

Inventors

• Stapperfenne Uwe
• Reemers Sandra
• Hallack Markus

Classifications

• B32B2305/18

  Fabrics, textiles · CPC title

• B29L2009/003

  comprising a metal layer · CPC title

• B32B37/203

  One or more of the layers being plastic · CPC title

• B32B27/40

  comprising polyurethanes · CPC title

• C08G18/4045

  Mixtures of compounds of group C08G18/58 with other macromolecular compounds · CPC title