Method for manufacturing silver particles

Patent metadata

Field	Value
Publication number	US-9901985-B2
Application number	US-201414891725-A
Country	US
Kind code	B2
Filing date	May 20, 2014
Priority date	May 24, 2013
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

The present invention provides a method for producing silver particles, the method capable of adjusting the particle diameter to be within the range of several tens of nanometers to several hundreds of nanometers and also producing silver particles with a uniform particle diameter. The present invention relates to a method for producing silver particles by heating of a reaction system containing a thermally-decomposable silver-amine complex precursor, including a process of producing a silver-amine complex, a process of adding an organic compound having an amide (carboxylic amide) as a skeleton to a reaction system, and a process of heating the reaction system, in which a water content in the reaction system before the heating is 20 to 100 parts by weight relative to 100 parts by weight of the silver compound. The present invention can produce uniform silver particles while the particle diameter is controlled.

First claim

The invention claimed is:

1. A method for producing silver particles by use of a thermally-decomposable silver-amine complex as a precursor and heating of a reaction system containing the precursor, comprising:
a process (a): mixing a thermally-decomposable silver compound with an amine to produce a silver-amine complex as a precursor, and to form a reaction system comprising the precursor;
a process (b): adding an organic compound, which has an amide as a skeleton, represented by a following formula to the reaction system

(R is hydrogen, hydrocarbon, an amino group, or a combination thereof; R′ and R″ are hydrogen or hydrocarbon);
a process (c): setting the water content in the reaction system, wherein the reaction system comprises water and the water content in the reaction system is set at is 20 to 100 parts by weight relative to 100 parts by weight of the silver compound; and
a process (d): heating the reaction system, whereby the produced silver particles have diameters such that the ratio of standard deviation of the particle diameters to the average particle diameter is about 0.3 or less.

2. The method for producing silver particles according to claim 1 , wherein the thermally-decomposable silver compound in the process (a) is any one of silver oxalate, silver nitrate, silver acetate, silver carbonate, silver oxide, silver nitrite, silver benzoate, silver cyanate, silver citrate, and silver lactate.

3. The method for producing silver particles according to claim 2 , wherein the total number of carbon atoms in the amine in the process (a) is 5 to 10.

4. The method for producing silver particles according to claim 2 , wherein at least one of urea, a urea derivative, N,N-dimethylformamide, and N,N-diethylformamide is added as the organic compound in the process (b).

5. The method for producing silver particles according to claim 2 , wherein the organic compound in the process (b) is added at 0.1 times or more silver ions in the silver compound in terms of a molar ratio.

6. The method for producing silver particles according to claim 2 , wherein a heating temperature in the process (d) is equal to or higher than a decomposition temperature of the silver-amine complex.

7. The method for producing silver particles according to claim 1 , wherein the total number of carbon atoms in the amine in the process (a) is 5 to 10.

8. The method for producing silver particles according to claim 7 , wherein at least one of urea, a urea derivative, N,N-dimethylformamide, and N,N-diethylformamide is added as the organic compound in the process (b).

9. The method for producing silver particles according to claim 7 , wherein the organic compound in the process (b) is added at 0.1 times or more silver ions in the silver compound in terms of a molar ratio.

10. The method for producing silver particles according to claim 7 , wherein a heating temperature in the process (d) is equal to or higher than a decomposition temperature of the silver-amine complex.

11. The method for producing silver particles according to claim 1 , wherein at least one of urea, a urea derivative, N,N-dimethylformamide, and N,N-diethylformamide is added as the organic compound in the process (b).

12. The method for producing silver particles according to claim 11 , wherein the organic compound in the process (b) is added at 0.1 times or more silver ions in the silver compound in terms of a molar ratio.

13. The method for producing silver particles according to claim 11 , wherein a heating temperature in the process (d) is equal to or higher than a decomposition temperature of the silver-amine complex.

14. The method for producing silver particles according to claim 1 , wherein the organic compound in the process (b) is added at 0.1 times or more silver ions in the silver compound in terms of a molar ratio.

15. The method for producing silver particles according to claim 14 , wherein a heating temperature in the process (d) is equal to or higher than a decomposition temperature of the silver-amine complex.

16. The method for producing silver particles according to claim 1 , wherein a heating temperature in the process (d) is equal to or higher than a decomposition temperature of the silver-amine complex.

17. The method for producing silver particles according to claim 1 , further comprising adding water in the reaction system during process (a).

18. The method for producing silver particles according to claim 1 , further comprising adding water in the reaction system during process (b).

19. The method for producing silver particles according to claim 1 , further comprising adding water in the reaction system during process (c).

20. The method for producing silver particles according to claim 1 , further comprising removing water from the reaction system during process (c).

Assignees

• Tanaka Precious Metal Ind

Inventors

• Makita Yuichi
• Ohshima Yuusuke
• Matsuda Hidekazu
• Nakamura Noriaki
• Taniuchi Junichi
• Kubo Hitoshi

Classifications

• B22F1/056

  Submicron particles having a size above 100 nm up to 300 nm · CPC title

• B22F1/054

  Nanosized particles · CPC title

• B22F2304/054

  Particle size between 1 and 100 nm · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F9/30 Primary

  with decomposition of metal compounds, e.g. by pyrolysis · CPC title