Positive electrode active material of power storage device, power storage device, electrically propelled vehicle, and method for manufacturing power storage device

Patent metadata

Field	Value
Publication number	US-9899678-B2
Application number	US-201615091770-A
Country	US
Kind code	B2
Filing date	Apr 6, 2016
Priority date	Apr 28, 2010
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

An object is to improve the characteristics of a power storage device such as a charging and discharging rate or a charge and discharge capacity. The grain size of particles of a positive electrode active material is nano-sized so that a surface area per unit mass of the active material is increased. Specifically, the grain size is set to greater than or equal to 10 nm and less than or equal to 100 nm, preferably greater than or equal to 20 nm and less than or equal to 60 nm. Alternatively, the surface area per unit mass is set to 10 m 2 /g or more, preferably 20 m 2 /g or more. Further, the crystallinity of the active material is increased by setting an XRD half width to greater than or equal to 0.12° and less than 0.17°, preferably greater than or equal to 0.13° and less than 0.16°.

First claim

What is claimed is:

1. A positive electrode active material comprising lithium iron phosphate,
wherein a grain size of the positive electrode active material is greater than or equal to 10 nm and less than or equal to 100 nm,
wherein a surface area per unit mass of the positive electrode active material measured by the BET method is greater than or equal to 24 m 2 /g and less than or equal to 27.5 m 2 /g, and
wherein an X-ray diffraction half width of the positive electrode active material is greater than or equal to 0.13° and less than 0.16°.

2. A power storage device comprising the positive electrode active material according to claim 1 , comprising:
a positive electrode including the positive electrode active material;
a negative electrode; and
an electrolyte between the positive electrode and the negative electrode.

3. The power storage device according to claim 2 ,
wherein a rate characteristic of the power storage device is 0.85 or more,
wherein the rate characteristic is defined by a rate of a discharge capacity in a case where a discharge rate is 10 C with respect to a discharge capacity in a case where a discharge rate is 2 C, and
wherein discharging n times in an hour is expressed as n C.

4. An electrically propelled vehicle comprising the power storage device according to claim 2 .

5. A positive electrode active material comprising lithium iron phosphate,
wherein a grain size of the positive electrode active material is greater than or equal to 10 nm and less than or equal to 100 nm,
wherein a surface area per unit mass of the positive electrode active material measured by the BET method is greater than or equal to 24 m 2 /g and less than or equal to 27.5 m 2 /g,
wherein an X-ray diffraction half width of the positive electrode active material is greater than or equal to 0.13° and less than 0.16°, and
wherein the positive electrode active material is covered by a material containing carbon.

6. A power storage device comprising the positive electrode active material according to claim 5 , comprising:
a positive electrode including the positive electrode active material;
a negative electrode; and
an electrolyte between the positive electrode and the negative electrode.

7. The power storage device according to claim 6 ,
wherein a rate characteristic of the power storage device is 0.85 or more,
wherein the rate characteristic is defined by a rate of a discharge capacity in a case where a discharge rate is 10 C with respect to a discharge capacity in a case where a discharge rate is 2 C, and
wherein discharging n times in an hour is expressed as n C.

8. An electrically propelled vehicle comprising the power storage device according to claim 6 .

Assignees

• Semiconductor Energy Lab

Inventors

• Kawakami Takahiro
• Yamakaji Masaki

Classifications

• B60L50/64

  Constructional details of batteries specially adapted for electric vehicles · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/5825 Primary

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title