Metal-air battery

Patent metadata

Field	Value
Publication number	US-9899654-B2
Application number	US-201414779206-A
Country	US
Kind code	B2
Filing date	Mar 17, 2014
Priority date	Mar 29, 2013
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

In a metal-air battery ( 1 ), an interconnector ( 24 ) formed of ceramic having alkali resistance is provided on the surface of a porous positive electrode layer ( 2 ) on the side opposite to the surface that is in contact with an electrolyte layer ( 4 ). A liquid repellent layer ( 29 ) having liquid repellency to an electrolyte solution is further provided on the surface of the positive electrode layer ( 2 ) on which the interconnector ( 24 ) is formed, and covers this surface along with the interconnector ( 24 ). The metal-air battery ( 1 ) using an alkaline electrolyte solution can thus easily prevent leakage of the electrolyte solution by the interconnector ( 24 ) and the liquid repellent layer ( 29 ) while suppressing degradation of the interconnector ( 24 ).

First claim

The invention claimed is:

1. A metal-air battery comprising:
a negative electrode layer;
a porous positive electrode layer that opposes said negative electrode layer;
an electrolyte layer disposed between said negative electrode layer and said positive electrode layer and containing an alkaline electrolyte solution;
an interconnector formed of ceramic having alkali resistance and provided on part of a surface of said positive electrode layer on a side opposite to a surface of said positive electrode layer that is in contact with said electrolyte layer; and
a liquid repellent layer having liquid repellency to said electrolyte solution and covering, along with said interconnector, the surface of said positive electrode layer on which said interconnector is provided, said liquid repellent layer being formed on a region of the surface of said positive electrode layer, said region not being covered with said interconnector.

2. The metal-air battery according to claim 1 , wherein
said ceramic forming said interconnector has electrical conductivity of one siemens per centimeter or greater.

3. The metal-air battery according to claim 1 , wherein
said liquid repellent layer is formed to have a porous structure by applying fine particles of fluororesin to the surface of said positive electrode layer on which said interconnector is provided and by firing the fine particles at a processing temperature that is higher than or equal to a temperature lower by 100° C. than a melting point of said fine particles and that is lower than or equal to a temperature higher by 70° C. than said melting point.

4. The metal-air battery according to claim 1 , wherein
said liquid repellent layer covers an edge portion of said interconnector.

5. The metal-air battery according to claim 2 , wherein
said liquid repellent layer is formed to have a porous structure by applying fine particles of fluororesin to the surface of said positive electrode layer on which said interconnector is provided and by firing the fine particles at a processing temperature that is higher than or equal to a temperature lower by 100° C. than a melting point of said fine particles and that is lower than or equal to a temperature higher by 70° C. than said melting point.

6. The metal-air battery according to claim 2 , wherein
said liquid repellent layer covers an edge portion of said interconnector.

7. The metal-air battery according to claim 3 , wherein
said liquid repellent layer covers an edge portion of said interconnector.

8. The metal-air battery according to claim 5 , wherein
said liquid repellent layer covers an edge portion of said interconnector.

Assignees

• Hitachi Shipbuilding Eng Co

Inventors

• Shimizu Takehiro
• Aizawa Masanobu
• Nishiura Sousuke
• Kameyama Kazuya

Classifications

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M2/26 Primary

  Electricity · mapped topic

• Y02E60/128

  Cross-Sectional Technologies · mapped topic

• H01M12/06 Primary

  with one metallic and one gaseous electrode · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title