Method for accelerated degradation of thermoplastics

Patent metadata

Field	Value
Publication number	US-9897551-B2
Application number	US-201514598308-A
Country	US
Kind code	B2
Filing date	Jan 16, 2015
Priority date	Jan 23, 2013
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A method of determining degradation of a thermoplastic when exposed to light and heat includes illuminating the thermoplastic with a desired wavelength of light at a desired irradiance while maintaining the thermoplastic at a desired temperature. The method is useful to measure the discoloration rate of transparent, translucent and opaque thermoplastics such as polycarbonates, the discoloration rate being determined by transmission or reflectance spectra of transmitted or reflected white light through or from the thermoplastic.

First claim

What is claimed:

1. A method for determining degradation of a thermoplastic, the method comprising:
illuminating a plurality of samples of thermoplastic, for a period of time, with light having a peak intensity centered at a wavelength from about 400 nm to about 500 nm and an irradiance from about 400 W/m 2 to about 150,000 W/m 2 ;
measuring the temperatures of the plurality of samples of the thermoplastic, wherein the temperature of each of the at least two samples of the thermoplastic is measured by a separate thermocouple associated with that sample;
calculating an average temperature of the thermoplastic using the temperatures of the plurality of samples of the thermoplastic;
maintaining the average temperature of the thermoplastic at a temperature from about 23° C. to about 175° C. during the period of time; and
repeating the illuminating and maintaining steps for a plurality of successive periods of time.

2. The method of claim 1 , further comprising repeating the illuminating and maintaining steps for a plurality of successive time periods for a plurality of different thermoplastic formulations; and evaluating the degradation of the plurality of different thermoplastic formulations.

3. The method of claim 2 , wherein evaluating the degradation comprises visually inspecting the thermoplastic, measuring a degree of discoloration of the thermoplastic, or both.

4. The method of claim 1 , wherein the average temperature of the thermoplastic is maintained at a temperature from about 90° C. to about 130° C.

5. The method of claim 3 , wherein measuring the degree of discoloration of the thermoplastic comprises:
(1) illuminating the thermoplastic with white light, a portion of the white light being transmitted through the thermoplastic; and
generating a transmission spectrum from the portion of the white light transmitted through the thermoplastic; or
(2) illuminating the thermoplastic with white light, a portion of the white light being reflected from the thermoplastic; and
generating a reflectance spectrum of the portion of the white light reflected from the thermoplastic;
or (1) and (2).

6. The method of claim 3 , further comprising comparing the degrees of discoloration measured after successive periods of time with one another.

7. A method for determining a discoloration rate of a plurality of polycarbonate samples, the method comprising:
illuminating the plurality of polycarbonate samples with light having a peak intensity centered at a wavelength from about 400 nm to about 500 nm and an irradiance from about 400 W/m 2 to about 150,000 W/m 2 for a first period of time;
measuring the temperatures of each of at least some of the polycarbonate samples by a separate thermocouple associated with that sample and calculating an average temperature of the thermoplastic using the temperatures of the at least some of the polycarbonate samples; and
maintaining the average temperature at a temperature from about 23° C. to about 175° C. during the first period of time.

8. The method of claim 7 , further comprising evaluating a degree of discoloration of the polycarbonate after the first period of time has elapsed.

9. The method of claim 7 , further comprising:
repeating said illuminating, maintaining and measuring steps for a plurality of polycarbonate samples of different formulations; and
comparing the discoloration of said plurality of different polycarbonate formulations with one another.

10. The method of claim 7 , wherein evaluating said degradation comprises visually inspecting the polycarbonate.

11. The method of claim 7 , wherein evaluating the degradation comprises measuring a degree of discoloration of the polycarbonate.

12. The method of claim 11 , wherein measuring the degree of discoloration of the polycarbonate comprises:
(1) illuminating the polycarbonate with white light, a portion of the white light being transmitted through the polycarbonate; and
generating a transmission spectrum from the portion of the white light transmitted through the polycarbonate; or
(2) illuminating the transparent polycarbonate with white light, a portion of the white light being reflected from the transparent polycarbonate; and
generating a reflectance spectrum of the portion of the white light reflected from the transparent polycarbonate;
or (1) and (2).

13. The method of claim 7 , further comprising:
repeating the illuminating and maintaining steps for a second period of time;
after the second period of time has elapsed, measuring a degree of discoloration of the transparent polycarbonate.

14. The method of claim 13 , further comprising comparing the degree of discoloration measured after the first period of time with the degree of discoloration after the second period of time.

15. A method for determining a discoloration rate of a plurality of samples of transparent polycarbonate, the method comprising:
illuminating the plurality of samples of transparent polycarbonate with light having a peak intensity centered at a wavelength from about 400 nm to about 500 nm and an irradiance from about 50,000 W/m 2 to about 150,000 W/m 2 for a period of time;
measuring the temperatures of at least some of the plurality of samples of transparent polycarbonate by a separate thermocouple associated with that sample and calculating an average temperature of the thermoplastic using the temperatures of the at least some of the samples of the transparent polycarbonate;
maintaining the average temperature at a temperature from about 23° C. to about 175° C. during the first period of time;
repeating the illuminating and maintaining steps for a plurality of successive periods of time; and
after each the successive period of time, measuring a degree of discoloration of the transparent polycarbonate.

16. The method of claim 15 , further comprising measuring temperatures of at least two samples of the transparent polycarbonate; and calculating an average temperature of the transparent polycarbonate using the temperatures of the at least two samples of the transparent polycarbonate.

17. The method of claim 15 , further comprising:
repeating the illuminating, maintaining and measuring steps for a plurality of successive time periods for a plurality of different transparent polycarbonate formulations; and
comparing the discoloration of the plurality of different transparent polycarbonate formulations with one another.

18. The method of claim 1 , further comprising selecting a thermoplastic sample.

19. The method of claim 7 , further comprising selecting a polycarbonate formulation sample.

20. The method of claim 15 , further comprising selecting a transparent polycarbonate sample.

21. A method for determining degradation of a thermoplastic, the method consisting essentially of:
illuminating a plurality of thermoplastics, for a period of time, with light having a peak intensity centered at a wavelength from about 410 nm to about 480 nm and an irradiance from about 400 W/m 2 to about 150,000 W/m 2 ;
maintaining the average temperature of the thermoplastic at a temperature from about 23° C. to about 175° C. during the period of time; and
repeating the illuminating and maintaining steps for a plurality of successive periods of time.

22. The method of claim 21 , further comprising selecting a thermoplastic sample.

Assignees

• Sabic Global Technologies Bv

Inventors

• Hein Christopher Luke

Classifications

• G01K3/02

  giving means values; giving integrated values · CPC title

• G01N17/004 Primary

  to light · CPC title

• G01N21/25

  Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands · CPC title

• G01N21/95 Primary

  characterised by the material or shape of the object to be examined (G01N21/89 - G01N21/91, G01N21/94 take precedence) · CPC title

• G01N21/27

  using photo-electric detection (G01N21/31 takes precedence){; circuits for computing concentration (logarithmic circuits G06G7/24; photometric circuits in general G01J)} · CPC title