Process for dissolving aluminum for recovering nuclear fuel

Patent metadata

Field	Value
Publication number	US-9896738-B2
Application number	US-201514724085-A
Country	US
Kind code	B2
Filing date	May 28, 2015
Priority date	May 28, 2015
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A process for controlling the dissolution of a metal in an acid bath is described. The metal may comprise aluminum and the acid bath may contain a metal catalyst that causes the metal to dissolve. In order to control the rate of dissolution and/or the amount of gas evolved during the process, an iron source is added to the bath. In one embodiment, the process can be used to dissolve aluminum contained in spent fuel assemblies for recovering a nuclear fuel, such as uranium.

First claim

What is claimed:

1. A process for dissolving aluminum during the recovery of a nuclear fuel comprising:
contacting a material containing aluminum and a nuclear fuel with an acid in the presence of a metal catalyst and an iron source, the acid and metal catalyst dissolving the aluminum, the iron source being present in an amount sufficient to decrease an off-gas stream rate during the dissolving process.

2. A process as defined in claim 1 , wherein the iron source is present in an amount sufficient to decrease hydrogen off-gas rate during the dissolving process.

3. A process as defined in claim 1 , wherein the acid comprises nitric acid.

4. A process as defined in claim 3 , wherein the material is initially contacted with nitric acid at a concentration of from about 4 molar to about 15 molar.

5. A process as defined in claim 3 , wherein the material is initially contacted with nitric acid at a concentration of from about 5 molar to about 8 molar.

6. A process as defined in claim 1 , wherein the iron source is present such that the molar ratio between iron and the catalyst is from about 3:1 to about 40:1.

7. A process as defined in claim 1 , wherein the iron source is present such that the molar ratio between iron and the catalyst is from about 11:1 to about 20:1.

8. A process as defined in claim 3 , wherein the nitric acid concentration after 95 wt % of the aluminum has dissolved is no less than 0.5 molar.

9. A process as defined in claim 2 , wherein the iron source is present in an amount sufficient to decrease the rate of hydrogen off-gas production by more than 10% by volume of the total off-gas produced.

10. A process as defined in claim 2 , wherein the iron source is present in an amount sufficient to decrease the rate of hydrogen off-gas production by more than 20% by volume of the total off-gas produced.

11. A process as defined in claim 1 , wherein the metal catalyst comprises mercury.

12. A process as defined in claim 1 , wherein the acid, the metal catalyst, and the iron source form a dissolution solution and wherein the metal catalyst comprises mercury and wherein mercury is present in the dissolution solution in an amount from about 0.001 molar to about 0.02 molar.

13. A process as defined in claim 1 , wherein the iron source comprises a ferrous metal, a ferrous salt, a ferric metal, a ferric salt, or mixtures thereof.

14. A process as defined in claim 1 , wherein the iron source comprises either ferrous sulfamate or ferrous nitrate.

15. A process as defined in claim 1 , wherein the material containing aluminum and a nuclear fuel comprises used nuclear fuel.

16. A process as defined in claim 1 , wherein the material containing aluminum and a nuclear fuel comprises an aluminum-uranium alloy or uranium aluminide dispersed in a continuous aluminum phase with an aluminum cladding.

17. A process as defined in claim 1 , wherein the nuclear fuel comprises uranium, plutonium, or mixtures thereof.

18. A process as defined in claim 1 , wherein the acid comprises nitric acid and the metal catalyst comprises mercury, the acid, metal catalyst and the iron source comprise a dissolution solution, the initial concentration of nitric acid in the dissolution solution being from about 5 molar to about 8 molar, the concentration of mercury being from about 0.001 molar to about 0.02 molar.

19. A process as defined in claim 1 , wherein the iron source is present during the process so that hydrogen off-gas production is maintained below 4% by volume in the off-gas stream.

20. A process as defined in claim 1 , wherein the acid, the metal catalyst and the iron source comprise a dissolution solution and wherein iron is present in the dissolution solution in an amount from about 2.5 g/L to about 20 g/L.

21. A process as defined in claim 1 , wherein the iron source comprises iron nitrate, iron fluoride, iron sulfate, iron phosphate, iron chloride, iron bromide, iron perchlorate, iron acetate, iron hydroxide, iron carbonate, or mixtures thereof.

Assignees

• Savannah River Nuclear Solutions Llc

Inventors

• Almond Philip M
• Daniel William E
• Rudisill Tracy S

Classifications

• Y02W30/882

  Cross-Sectional Technologies · mapped topic

• C22B21/0061

  using metals, e.g. Hg or Mn · CPC title

• G21C19/44 Primary

  of irradiated solid fuel · CPC title

• C22B21/0023 Primary

  from waste materials · CPC title

• Y02E30/30

  Nuclear fission reactors · CPC title