Lubricant for marine engine

Patent metadata

Field	Value
Publication number	US-9896639-B2
Application number	US-201414888477-A
Country	US
Kind code	B2
Filing date	May 6, 2014
Priority date	May 7, 2013
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

The present disclosure relates to a lubricant for marine engines including at least one base oil, at least one overbased detergent, at least one neutral detergent and at least one fatty amine.

First claim

The invention claimed is:

1. A cylinder lubricant having a BN determined according to the standard ASTM D-2896 greater than or equal to 50 milligrams of potash per gram of lubricant, comprising:
at least one lubricant base oil,
at least one detergent based on alkali or alkaline-earth metals, overbased with metallic carbonate salts,
from 5 to 15% by weight of at least one neutral detergent, with respect to the total weight of the cylinder lubricant, and
a mixture of fatty amines comprising at least one fatty amine of formula (I)
R 1 —[NR 2 (CH 2 ) 3 ] 3 —NH 2    (I)

in which:
R 1 represents a linear or branched, alkyl or alkenyl group, comprising at least 14 carbon atoms,
R 2 represents a hydrogen atom or a —(CH 2 ) 2 OH group,
the content by weight of fatty amine of formula (I) being greater than or equal to 90% with respect to the total weight of the mixture of fatty amines,
the fatty amine having a BN determined according to the standard ASTM D-2896 ranging from 150 to 600 milligrams of potash per gram of amine,
the percentage by mass of fatty amine with respect to the total weight of the lubricant being selected so that the BN provided by this compound represents a contribution ranging from 10 to 60 milligrams of potash per gram of lubricant to the total BN of the cylinder lubricant, and
the percentage by mass of the overbased detergent with respect to the total weight of the lubricant being selected so that the BN provided by the metallic carbonate salts represents a contribution ranging from 30 to 70 milligrams of potash per gram of lubricant to the total BN of the cylinder lubricant.

2. The cylinder lubricant according to claim 1 in which the content by weight of fatty amine of formula (I) is strictly less than 100% with respect to the total weight of the mixture of fatty amines.

3. The cylinder lubricant according to claim 1 in which the content by weight of fatty amine of formula (I) ranges from 90 to 99.9% with respect to the total weight of the mixture of fatty amines.

4. The cylinder lubricant according to claim 1 having a BN determined according to the standard ASTM D-2896 ranging from 50 to 100 milligrams of potash per gram of lubricant.

5. The cylinder lubricant according to claim 1 in which the percentage by mass of fatty amine with respect to the total weight of the lubricant is selected so that the BN provided by this compound represents a contribution of 10 to 30 milligrams of potash per gram of lubricant.

6. The cylinder lubricant according to claim 1 in which the percentage by mass of fatty amine with respect to the total weight of the lubricant is selected so that the BN provided by this compound represents at least 10%.

7. The cylinder lubricant according to claim 1 in which the percentage by mass of the mixture of fatty amines with respect to the total weight of the cylinder lubricant ranges from 2 to 10%.

8. The cylinder lubricant according to claim 1 in which R 1 represents a linear or branched alkyl or alkenyl group comprising from 14 to 22 carbon atoms.

9. The cylinder lubricant according to claim 1 in which R 2 represents a hydrogen atom.

10. The cylinder lubricant according to claim 1 in which the mixture of fatty amines is presented in the form:
of at least one fatty amine of formula (I) in which R 1 represents a linear or branched, alkyl or alkenyl group comprising from 14 to 16 carbon atoms and R 2 represents a hydrogen atom,
of at least one fatty amine of formula (I) in which R 1 represents a linear or branched, alkyl or alkenyl group comprising at least 18 carbon atoms and R 2 represents a hydrogen atom, and
of at least one fatty amine of formula (I) in which R 1 represents a linear or branched, alkyl or alkenyl group comprising at least 20 carbon atoms and R 2 represents a hydrogen atom.

11. The cylinder lubricant according to claim 1 in which the mixture of fatty amines is presented in the form:
of at least one fatty amine of formula (I) in which R 1 represents a linear or branched alkenyl group comprising from 16 to 20 carbon atoms and R 2 represents a hydrogen atom, and
of at least one fatty amine of formula (I) in which R 1 represents a linear or branched alkyl group comprising from 16 to 20 carbon atoms, and R 2 represents a hydrogen atom.

12. The cylinder lubricant according to claim 1 in which the overbased and neutral detergents are selected from the carboxylates, sulphonates, salicylates, naphthenates, phenates, and the mixed detergents combining at least two of these types of detergents.

13. The cylinder lubricant according to claim 1 in which the percentage by mass of the overbased detergent and of the neutral detergent, with respect to the total weight of lubricant, is selected so that the organic BN provided by the detergent soaps represents a contribution of at least 10 milligrams of potash per gram of lubricant to the total BN of the cylinder lubricant.

14. The cylinder lubricant according to claim 1 in which the percentage by mass of the overbased detergent with respect to the total weight of lubricant ranges from 8 to 30% or the neutral detergent with respect to the total weight of lubricant ranges from 5 to 10%.

15. The cylinder lubricant according to claim 1 also comprising an additional compound selected from:
the primary, secondary or tertiary fatty monoalcohols, the alkyl chain of which is linear or branched, and comprising at least 12 carbon atoms,
the esters of saturated fatty monoacids comprising at least 14 carbon atoms and of alcohols comprising at most 6 carbon atoms.

16. The cylinder lubricant according to claim 1 , the kinematic viscosity of which, measured according to the standard ASTM D445 at 100° C. ranges from 12.5 to 26.1 cSt.

17. A method for lubricating a cylinder in a marine engine combusting a fuel oil, the method comprising contacting the cylinder with a single lubricant comprising:
at least one lubricant base oil,
at least one detergent based on alkali or alkaline-earth metals, overbased with metallic carbonate salts,
from 5 to 15% by weight of at least one neutral detergent, with respect to the total weight of the cylinder lubricant, and
a mixture of fatty amines comprising at least one fatty amine of formula (I)
R 1 —[NR 2 (CH 2 ) 3 ] 3 —NH 2    (I)

in which:
R 1 represents a linear or branched, alkyl or alkenyl group, comprising at least 14 carbon atoms,
R 2 represents a hydrogen atom or a —(CH 2 ) 2 OH group,
the content by weight of fatty amine of formula (I) being greater than or equal to 90% with respect to the total weight of the mixture of fatty amines,
the fatty amine having a BN determined according to the standard ASTM D-2896 ranging from 150 to 600 milligrams of potash per gram of amine,
the percentage by mass of fatty amine with respect to the total weight of the lubricant being selected so that the BN provided by this compound represents a contribution ranging from 10 to 60 milligrams of potash per gram of lubricant to the total BN of the cylinder lubricant, and
the percentage by mass of the overbased detergent with respect to the total weight of the lubricant being selected so that the BN provided by the metallic carbonate salts represents a contribution ranging from 30 to 70 milligrams of potash per gram of lubricant to the total BN of the cylinder lubricant,
wherein the fuel oil includes a sulphur content of less than 1% by weight with respect to the total weight of the fuel oil or a sulphur content ranging from 1 to 3.5% by weight with respect to the total weight of the fuel oil.

18. The

Assignees

• Total Marketing Services

Inventors

• Lancon Denis
• Doyen Valerie

Classifications

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2040/252

  Diesel engines · CPC title

• C10N2070/02

  Concentrating of additives · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2010/04

  Groups 2 or 12 · CPC title