Method of making rod-shaped particles for use as proppant and anti-flowback additive

Patent metadata

Field	Value
Publication number	US-9896618-B2
Application number	US-201514946085-A
Country	US
Kind code	B2
Filing date	Nov 19, 2015
Priority date	Nov 19, 2015
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A method for forming rod-shaped particles includes inducing flow of a slurry of particles and a reactant through one or more orifices and into a coagulation solution, wherein the slurry exiting the one or more orifices is a continuous uninterrupted stream, coagulating the reactant in the coagulation solution to form stabilized rods, drying the stabilized rods and reducing a length of the dried stabilized rods.

First claim

What is claimed is:

1. A method for forming rod-shaped particles, the method comprising:
inducing flow of a slurry comprised of particles and a reactant through one or more orifices and into a coagulation solution, wherein the slurry exiting the one or more orifices is a continuous uninterrupted stream, and
wherein the one or more orifices is capable of moving vertically, laterally, or into and out of a surface of the coagulation solution during flowing of the slurry;
coagulating the reactant in the coagulation solution to form stabilized rods;
drying the stabilized rods; and
reducing a length of the dried stabilized rods.

2. The method according to claim 1 , wherein the inducing flow of the slurry is performed by applying a load to a piston in a container housing the slurry to force the slurry through the one or more orifices associated with an exit of the container, increasing pressure in the container housing the slurry to force the slurry through the one or more orifices associated with an exit of the container, decreasing a volume of the container housing the slurry to force the slurry through the one or more orifices associated with an exit of the container, or pumping the slurry from the container housing the slurry to force the slurry through the one or more orifices associated with an exit of the container.

3. The method according to claim 1 , wherein the method further comprises forming the slurry prior to inducing flow of the slurry by mixing the reactant and the particles.

4. The method according to claim 1 , wherein the particles are ceramic particles.

5. The method according to claim 4 , wherein the ceramic particles are alumina-containing particles.

6. The method according to claim 1 , wherein the reactant is an alginate and the coagulation solution comprises a calcium salt.

7. The method according to claim 1 , wherein the one or more orifices are located above the coagulation solution and the slurry exiting the one or more orifices remains in a continuous uninterrupted stream during falling to the coagulation solution.

8. The method according to claim 1 , wherein the one or more orifices are located in the coagulation solution.

9. The method according to claim 1 , wherein the one or more orifices have a geometrical shape and impart a corresponding geometrical cross-section to the rod-shaped particles.

10. The method according to claim 9 , wherein the imparted geometrical cross-section is selected from the group consisting of circular, elliptical, oval, quatrefoil, triangular and rectangular.

11. The method according to claim 1 , wherein the method further comprises applying an intermittent vibration to the one or more orifices to thereby vary a cross-sectional diameter of the continuous uninterrupted stream exiting the one or more orifices.

12. The method according to claim 1 , wherein the one or more orifices comprise one or more nozzles or one or more openings of a membrane.

13. The method according to claim 1 , wherein the method further comprises sintering the dried stabilized rods or the rod-shaped particles.

14. The method according to claim 1 , wherein the reducing the length of the dried stabilized rods comprises cutting the dried stabilized rods.

15. The method according to claim 1 , wherein the rod-shaped particles have an average length of 0.1 mm to 5 cm, an average diameter of 0.2 mm to 1 cm and an average length to diameter of at least 2:1.

16. A method for forming rod-shaped particles, the method comprising:
inducing flow of a slurry comprised of particles and a reactant through one or more orifices and into a coagulation solution,
wherein the one or more orifices is capable of moving vertically, laterally, or into and out of the coagulation solution;
applying a vibration to the one or more orifices when an amount of slurry that has passed through the one or more orifices is such that the slurry having exited through the one or more orifices has a predetermined length for the rod-shaped particles, wherein the vibration is sufficient to separate the exited slurry from the slurry flow at the one or more orifices;
coagulating the reactant in the coagulation solution to form stabilized rods; and
drying the stabilized rods to form the rod-shaped particles.

17. The method according to claim 16 , wherein the particles are ceramic particles.

Assignees

• Schlumberger Technology Corp

Inventors

• Huang Jiangshui
• Ortega Andrade Jose Alberto
• Lungwitz Bernhard Rudolf

Classifications

• C09K8/80 Primary

  Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open · CPC title

• C04B35/624

  Sol-gel processing · CPC title

• C04B2235/94

  Products characterised by their shape · CPC title

• C04B35/111

  Fine ceramics · CPC title

• C04B35/622

  Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products · CPC title