Polymer compositions

Patent metadata

Field	Value
Publication number	US-9896617-B2
Application number	US-201514927078-A
Country	US
Kind code	B2
Filing date	Oct 29, 2015
Priority date	Oct 31, 2014
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A method of enhancing oil recovery in a subterranean reservoir is disclosed. In one embodiment, the method comprises providing a wellbore and a polymer suspension. The polymer suspension comprises a powder polymer having an average molecular weight of 0.5 to 30 Million Daltons suspended in a water soluble solvent having an HLB of greater than or equal to 8 and selected from a group, at a weight ratio of 20:80 to 80:20. The method comprises providing an aqueous fluid, mixing a sufficient amount of the polymer suspension in the aqueous fluid for the polymer to be hydrated resulting an injection solution in less than or equal to 4 hours, and injecting the injection solution into the wellbore. The injection solution contains a polymer concentration ranging from 100 ppm to 50,000 ppm and has a filter ratio of less than 1.5 at 15 psi using a 1.2 μm filter.

First claim

The invention claimed is:

1. A method of enhancing oil recovery in a subterranean reservoir, the method comprising
providing a wellbore in fluid communication with the subterranean reservoir;
providing a polymer suspension, wherein the polymer suspension comprises a powder polymer having an average molecular weight of 0.5 to 30 Million Daltons suspended in a water soluble solvent at a weight ratio of powder polymer to water soluble solvent ranging from 20:80 to 80:20, wherein the water soluble solvent has a HLB of greater than or equal to 8 and comprises a mixture of non-ionic and anionic surfactants, and wherein the polymer suspension contains less than or equal to 3 wt. % water;
providing an aqueous fluid selected from any of surface water, water recovered from a production well, sea water, synthetic water, produced reservoir brine, reservoir brine, fresh water, produced water, water, saltwater, brine, synthetic brine, synthetic seawater brine, and mixtures thereof;
mixing a sufficient amount of the polymer suspension in the aqueous fluid for the polymer to be hydrated resulting in an injection solution in less than or equal to 4 hours, the injection solution containing a polymer concentration ranging from 100 ppm to 50,000 ppm and having a filter ratio of less than 1.5 at 15 psi using a 1.2 μm filter;
injecting the injection solution into the wellbore into the subterranean reservoir.

2. The method of claim 1 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid is via a mixing tank or an in-line mixer.

3. The method of claim 1 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid for the polymer to be hydrated resulting in an injection solution in less than or equal to 2 hours.

4. The method of claim 3 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid for the polymer to be hydrated resulting in an injection solution in less than or equal to 1 hour.

5. The method of claim 1 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid resulting in an injection solution having a filter ratio of less than or equal to 1.2 at 15 psi using a 1.2 μm filter.

6. The method of claim 5 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid resulting in an injection solution having a filter ratio of less than or equal to 1.05 at 15 psi using a 1.2 μm filter.

7. The method of claim 1 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid resulting in an injection solution having a turbidity of less than or equal to 20 NTU.

8. The method of claim 7 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid resulting in an injection solution having a turbidity of less than or equal to 15 NTU.

9. The method of claim 8 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid resulting in an injection solution having a turbidity of less than or equal to 10 NTU.

10. The method of claim 1 , wherein after the powder polymer is suspended in the water soluble solvent for a period of at least 2 hours with a turbidity decrease of at least 25%.

11. The method of claim 10 , wherein after the powder polymer is suspended in the water soluble solvent for a period of at least 2 hours with a turbidity decrease of at least 50%.

12. The method of claim 11 , wherein after the powder polymer is suspended in the water soluble solvent for a period of at least 2 hours with a turbidity decrease of at least 75%.

13. The method of claim 1 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid is for less than or equal to 2 hours for an injection solution.

14. The method of claim 13 , wherein the mixing of a sufficient amount of the polymer suspension in the aqueous fluid is for less than or equal to 1 hour for an injection solution.

15. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent for less than or equal to 24 hours, for a stable polymer suspension containing less than or equal to 3 wt. % water.

16. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the powder polymer is a biopolymer that is a polysaccharide.

17. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the powder polymer is a biopolymer or a synthetic polymer.

18. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the powder polymer is a synthetic polymer selected from the group of polyacrylamides, partially hydrolyzed polyacrylamides, hydrophobically-modified associative polymers, copolymers of polyacrylamide and one or both of 2-acrylamido 2-methylpropane sulfonic acid and salts thereof and N-vinyl pyrrolidone, single-, co-, or ter-polymers of N-vinyl pyrrolidones, polyacrylic acid, polyvinyl alcohol, and mixtures thereof.

19. The method of claim 1 , wherein the anionic surfactant is present in an amount of less than or equal to 5 wt. % as a stabilizer.

20. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the water soluble solvent further comprises isopropyl alcohol (IPA), n-propyl alcohol, isobutyl alcohol (IBA), methyl-isobutyl alcohol, secondary butyl alcohol (SBA), ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol monobutyl ether, and mixtures thereof.

21. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the water soluble solvent is selected from ethoxylated surfactants, nonylphenol ethoxylates, alcohol ethoxylates, internal olefin sulfonates, isomerized olefin sulfonates, alkyl aryl sulfonates, medium alcohol (C10 to C17) alkoxy sulfates, alcohol ether [alkoxy]carboxylates, alcohol ether [alkoxy]sulfates, alkyl sulfonate, a-olefin sulfonates (AOS), dihexyl sulfosuccinates, alkylpolyalkoxy sulfates, sulfonated amphoteric surfactants, and mixtures thereof.

22. The method of claim 1 , wherein providing the polymer suspension comprises mixing the powder polymer into the water soluble solvent and wherein the water soluble solvent further comprises a co-solvent selected from the group of an ionic surfactant, non-ionic surfactant, anionic surfactant, cationic surfactant, nonionic surfactant, amphoteric surfactant, ketones, esters, ethers, glycol ethers, glycol ether esters, lactams, cyclic ureas, alcohols, aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, nitroalkanes, unsaturated hydrocarbons, halocarbons, alkyl aryl sulfonates (AAS), a-olefin sulfonates (AOS), internal olefin sulfonates (IOS), alcohol ether sulfates derived from propoxylated Ci 2 -C 2 o alcohols, ethoxylated alcohols, mixtures of an alcohol and an ethoxylated alcohol, mixtures of anionic and cationic surfactants, disulfonated surfactants, aromatic ether polysulfonates, isomerized olefin sulfonates, alkyl aryl sulfonates, medium alcohol (C10 to C17) alkoxy sulfates, alcohol ether [alkoxy]carboxylates, alcohol ether [alkoxy]sulfates, primary amines, secondary amines, tertiary amines, quate

Assignees

• Chevron Usa Inc

Inventors

• Dwarakanath Varadarajan
• Dean Robert M
• Kim Do Hoon
• Alexis Dennis Arun
• Thach Sophany
• Malik Taimur
• Poulsen Anette
• Subrahmanyan Sumitra

Classifications

• C09K8/68

  containing organic compounds · CPC title

• E21B43/26

  by forming crevices or fractures · CPC title

• C09K8/588 Primary

  characterised by the use of specific polymers {(polymeric surfactants C09K8/584)} · CPC title

• C09K8/584

  characterised by the use of specific surfactants · CPC title

• C09K8/88

  macromolecular compounds · CPC title