Polycarbonate resin composition and molded article

Patent metadata

Field	Value
Publication number	US-9896569-B2
Application number	US-201314440152-A
Country	US
Kind code	B2
Filing date	Nov 5, 2013
Priority date	Nov 5, 2012
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

Provided are a polycarbonate resin composition containing a polycarbonate resin containing an aliphatic carbonate repeating unit (A) derived from an aliphatic dihydroxy compound and a specific glass filler, and a molded article.

First claim

The invention claimed is:

1. A polycarbonate resin composition, comprising:
a polycarbonate resin containing an aliphatic carbonate repeating unit (A) derived from an aliphatic dihydroxy compound; and
a glass filler;
wherein:
the polycarbonate resin has a refractive index at a wavelength of 589.3 nm of 1.490 to 1.550;
the glass filler has a refractive index at a wavelength of 589.3 nm of 1.500 to 1.540;
the glass filler contains 50 to 75 mass % of silicon dioxide (SiO 2 ), 0 to 30 mass % of aluminum oxide (Al 2 O 3 ), 0 to 20 mass % of boron oxide (B 2 O 3 ), 0 to 11 mass % of magnesium oxide (MgO), 0 to 25 mass % of calcium oxide (CaO), 0 to 10 mass % of zinc oxide (ZnO), 0 to 10 mass % of strontium oxide (SrO), 0 to 10 mass % of barium oxide (BaO), 0 to 15 mass % of sodium oxide (Na 2 O), 0 to 10 mass % of potassium oxide (K 2 O), 0 to 10 mass % of lithium oxide (Li 2 O), 0 to 10 mass % of titanium oxide (TiO 2 ), 0 to 1 mass % of iron oxide (Fe 2 O 3 ), and 0 to 2 mass % of fluorine (F 2 );
a total content of silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) in the glass filler is 50 to 93 mass %;
a total content of calcium oxide (CaO), zinc oxide (ZnO), strontium oxide (SrO), and barium oxide (BaO) in the glass filler is 0 to 25 mass %;
a total content of sodium oxide (Na 2 O), potassium oxide (K 2 O), and lithium oxide (Li 2 O) in the glass filler is 0 to 15 mass %;
a difference between a refractive index of the polycarbonate resin and a refractive index of the glass filler is 0.004 or less for light having a wavelength of 486.1 nm, is 0.002 or less for light having a wavelength of 589.3 nm, and is 0.002 or less for light having a wavelength of 656.3 nm;
the glass filler is present in an amount of 5 to 35 mass % with respect to a total amount of the polycarbonate resin and the glass filler; and
the polycarbonate resin composition has a haze value of 9.5% or less, the haze value being measured using a molded article formed from the polycarbonate resin composition having a thickness of 2 mm.

2. The polycarbonate resin composition according to claim 1 , wherein the polycarbonate resin contains the aliphatic carbonate repeating unit (A) derived from the aliphatic dihydroxy compound and an aromatic carbonate repeating unit (B) derived from an aromatic dihydroxy compound.

3. The polycarbonate resin composition according to claim 1 , wherein the aliphatic carbonate repeating unit (A) is represented by the following formula (I):

where X 1 represents a divalent aliphatic hydrocarbon group having 2 to 20 carbon atoms or a divalent alicyclic hydrocarbon group having 4 to 22 carbon atoms, and the divalent aliphatic hydrocarbon group and the divalent alicyclic hydrocarbon group may each contain at least one heteroatom selected from an oxygen atom, a nitrogen atom, and a sulfur atom, and at least one halogen atom selected from a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

4. The polycarbonate resin composition according to claim 2 , wherein the aromatic carbonate repeating unit (B) is represented by the following formula (II):

where X 2 represents a hydrocarbon residue containing an aromatic group.

5. The polycarbonate resin composition according to claim 2 , wherein the polycarbonate resin has a molar ratio (A/B) of the aliphatic carbonate repeating unit (A) to the aromatic carbonate repeating unit (B) of 95/5 to 0.5/99.5.

6. The polycarbonate resin composition according to claim 1 , wherein:
the polycarbonate resin has an Abbe number of 35 or more; and
a difference (nF-nC) between a refractive index (nF) of the polycarbonate resin for light having a wavelength of 486.1 nm and a refractive index (nC) thereof for light having a wavelength of 656.3 nm is 0.015 or less.

7. The polycarbonate resin composition according to claim 1 , wherein the polycarbonate resin has a glass transition temperature of 75 to 175° C.

8. The polycarbonate resin composition according to claim 1 , wherein the total content of sodium oxide (Na 2 O), potassium oxide (K 2 O), and lithium oxide (Li 2 O) in the glass filler is 0 to 10 mass %.

9. The polycarbonate resin composition according to claim 1 , wherein the glass filler has an Abbe number of 35 or more.

10. The polycarbonate resin composition according to claim 1 , wherein when the polycarbonate resin composition is molded into a flat plate shape, the flat plate has a total light transmittance of 75% or more.

11. A molded article, which is obtained by molding the polycarbonate resin composition of claim 1 .

12. The polycarbonate resin composition according to claim 1 , wherein the glass filler is present in an amount of 10 to 35 mass % with respect to the total amount of the polycarbonate resin and the glass filler.

13. The polycarbonate resin composition according to claim 1 , wherein the glass filler is present in an amount of 10 to 30 mass % with respect to the total amount of the polycarbonate resin and the glass filler.

14. The polycarbonate resin composition according to claim 1 , comprising:
the polycarbonate resin in an amount of 70 to 95 mass % with respect to the total amount of the polycarbonate resin and the glass filler; and
the glass filler in an amount of 5 to 30 mass % with respect to the total amount of the polycarbonate resin and the glass filler;
wherein:
the polycarbonate resin comprises at least one repeating unit (A) derived from at least one member selected from the group consisting of cyclohexanedimethanol, tricyclodecanedimethanol, and isosorbide, and at least one repeating unit (B) derived from bisphenol A; and
a molar ratio (A/B) of the repeating unit (A) to the repeating unit (B) is 100/0 to 40/60.

Assignees

• Idemitsu Kosan Co
• Asahi Fibreglass Co

Inventors

• Owada Takanori
• Sekine Keiji
• Noguchi Takenori

Classifications

• C08K3/40 Primary

  Glass · CPC title

• C03C13/00

  Fibre or filament compositions (manufacture of fibres or filaments C03B37/00) · CPC title

• C03C12/00

  Powdered glass (C03C8/02 takes precedence); Bead compositions · CPC title

• C03C3/118

  containing aluminium · CPC title

• C03C3/091

  containing aluminium · CPC title