Xylene separation process and apparatus

Patent metadata

Field	Value
Publication number	US-9896398-B2
Application number	US-201615262648-A
Country	US
Kind code	B2
Filing date	Sep 12, 2016
Priority date	Nov 20, 2014
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A simulated moving bed process using dual, parallel rotary valves configured or plumbed to be operated independently in which the step times of the rotary valves are staggered. In embodiments, the second rotary valve is programmed to step about halfway through the step time of the first rotary valve. Staggering the step time of the parallel rotary valves, rather than utilizing simultaneous stepping, results in increased net composite paraxylene concentration of the extract stream, allowing for increased capacity of the simulated moving bed process and/or reduced energy consumption.

First claim

What is claimed is:

1. An apparatus for the continuous simulated countercurrent adsorptive separation of para-xylene comprising plural adsorptive separation chambers fluidly connected with plural bedlines A 1 through A n+j , wherein n>2 and n+j is the total number of bedlines, which in turn are fluidly connected with a matrix of conduits to distribute plural input streams, including desorbent, a primary flush input and a secondary flush input, and at least two multicomponent feeds differing in the concentration of para-xylene, to said plural bedlines, and plural output streams, including a primary flush output and a secondary flush output, an extract comprising a para-xylene-enriched product, and raffinate, from said plural adsorptive separation chambers, wherein the plural input streams and plural output streams are distributed by a first and second rotary valve in fluid communication with the conduits, the improvement comprising staggering the step time of the first rotary valve from the step time of the second rotary valve.

2. The apparatus of claim 1 , wherein the second rotary valve steps about halfway through the step time of the first rotary valve.

3. The apparatus of claim 1 , wherein the second rotary valve steps prior to about halfway through the step time of the first rotary valve.

4. The apparatus of claim 1 , wherein the second rotary valve steps within about 10 seconds of the midpoint of the step time of the first rotary valve.

5. The apparatus of claim 1 , wherein the step time varies between the plural adsorptive separation chambers.

6. The apparatus of claim 1 , wherein the first rotary valve is operated at a different flow rate than the second rotary valve.

7. The apparatus of claim 1 , wherein the at least two multicomponent feeds are selected from an equilibrium mixture of xylenes, an enhanced para-xylene stream from a toluene disproportionation unit, an enhanced para-xylene stream from a toluene methylation unit, and filtrate from a crystallizer which is low in para-xylene.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Porter John R
• Bender Timothy P
• Pilliod Dana L

Classifications

• B01D15/1828

  characterised by process features · CPC title

• B01D15/1835

  Flushing · CPC title

• B01D15/1807

  using counter-currents, e.g. fluidised beds · CPC title

• C07C7/12 Primary

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• B01D15/1842

  characterised by apparatus features · CPC title