Double-component modified molecular sieve with improved hydrothermal stability and production method thereof

Patent metadata

Field	Value
Publication number	US-9895686-B2
Application number	US-200913505219-A
Country	US
Kind code	B2
Filing date	Dec 1, 2009
Priority date	Oct 30, 2009
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.

First claim

What we claim is:

1. A method for preparing double-component modified molecular sieves with improved hydrothermal stability, wherein, according to said method, the molecular sieve is added to an aqueous solution containing phosphorus and allowed to react at pH of 2-7 at a reaction temperature of 90-160° C. under a reaction pressure of 0.2-0.8 MPa for 10-200 minutes, followed by filtering, drying and calcining, so as to obtain a phosphorus-modified molecular sieve; the phosphorus-modified molecular sieve is added into an aqueous solution containing silver ions and allowed to react at a reaction temperature of 0-100° C. for 30-150 minutes, followed by filtering, drying and calcining, so as to obtain a double-component modified molecular sieve, wherein the molecular sieve is one of ZSM type or β type, molecular sieve, and the silica to alumina ratio of the molecular sieve is in the range of 15-60, the weight ratio of the aqueous solution containing silver ions to the molecular sieve is in the range from 3:1 to 7:1, and the aqueous solution containing silver ions has a concentration of 0.01-0.1 mol/L
wherein the aqueous solution containing phosphorus is a solution of phosphoric acid, a solution of phosphorous acid, an aqueous solution of a soluble phosphate and/or an aqueous solution of a soluble phosphite, wherein, the soluble phosphate is one or more selected from triammonium phosphate, diammonium hydrogen phosphate, and ammonium dihydrogen phosphate,
wherein the aqueous solution containing silver ions is an aqueous solution of silver nitrate, an aqueous solution of silver acetate or both
wherein the aqueous solution containing phosphorus has a concentration of 0.05-1.0 mol/L.

Assignees

• Gao Xionghou
• Ji Dong
• Zhang Haitao
• Duan Hongchang
• Li Di
• Tan Zhengguo
• Su Yi
• Tang Zhicheng
• Wang Yi
• Ma Yanqing
• Sun Yanbo
• Petrochina Co Ltd

Inventors

• Gao Xionghou
• Ji Dong
• Zhang Haitao
• Duan Hongchang
• Li Di
• Tan Zhengguo
• Su Yi
• Tang Zhicheng
• Wang Yi
• Ma Yanqing
• Sun Yanbo

Classifications

• B01J29/041

  Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 · CPC title

• C07C2529/22

  Noble metals · CPC title

• B01J2229/40

  Special temperature treatment, i.e. other than just for template removal · CPC title

• B01J29/7415

  Zeolite Beta · CPC title

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title