Dispersion of particulate clusters via the rapid vaporization of interstitial liquid

Patent metadata

Field	Value
Publication number	US-9895668-B2
Application number	US-201214233535-A
Country	US
Kind code	B2
Filing date	Jul 19, 2012
Priority date	Jul 20, 2011
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A process for dispersing agglomerates or clusters of particles utilizing pressure generated from volatilization of an interstitial liquid. More particularly, the method relates to infusing the particles with a first liquid, placing the infused particles in a second liquid or fluid having a higher boiling point than the first liquid and heating the composition to a temperature above the boiling point of the first liquid thereby resulting in breakage of the particles. Compositions including particles dispersed by interstitial liquid vaporization are also disclosed.

First claim

What is claimed is:

1. A method for dispersing clusters of particles, comprising the steps of:
infusing a cluster of particles with a liquid; and
generating an internal force within the cluster of particles by heating the liquid infused in the particles above the boiling point of the liquid at a prevailing system pressure and at a rate rapid enough to break the cluster of particles, wherein prior to said generating the internal force within the cluster of particles step, the infused cluster of particles is introduced into a dispersion medium immiscible with the liquid, wherein the dispersion medium can be heated above the boiling point of the liquid infused in the cluster of particles without substantially degrading, wherein the dispersion medium comprises one or more of an oil and a polymer, wherein the liquid infused in the cluster of particles comprises one or more of water and acetone, and wherein the particles comprise one or more of carbon black and carbon nanotubes.

2. The method according to claim 1 , wherein the particles comprise an additive, a filler, a pigment, a mechanical reinforcement, or a combination thereof, and wherein the cluster of particles has a size that ranges from a nanometer to a millimeter.

3. The method according to claim 1 , wherein the liquid is a low boiling point solvent having a boiling point that ranges from about 30° C. to about 200° C.

4. The method according to claim 3 , wherein the infused liquid has a boiling point of from about 40° C. to about 150° C.

5. The method according to claim 1 , wherein the dispersion medium encapsulates the cluster of particles, wherein said infusing step includes one or more of adding the liquid to the cluster of particles, immersing the particles in the liquid and condensing the liquid into the cluster of particles from a vapor, and wherein said heating comprises direct heating or application of microwave energy.

6. The method according to claim 1 , further including the steps of subjecting the particles to one or more of agitation, attrition, crushing, grinding, mixing, and ultrasonication.

7. The method according to claim 1 , wherein said liquid comprises two or more different liquids.

8. A method for dispersing clusters of particles, comprising the steps of:
incorporating a liquid into a cluster of particles;
placing the liquid-incorporated-cluster of particles in a fluid immiscible with the liquid to form a mixture; and
heating the mixture above a boiling point of the liquid within an effective period of time to reduce an average size of the cluster of particles, wherein the fluid immiscible with the liquid can be heated above the boiling point of the liquid without substantially degrading, wherein the liquid has a boiling point of from about 40° C. to about 150° C., wherein the fluid immiscible with the liquid comprises one or more of an oil and a polymer, wherein said liquid comprises one or more of water and acetone, and wherein said particles comprise carbon black and carbon nanotubes.

9. The method according to claim 8 , wherein the boiling point of the liquid ranges from about 30° C. to about 200° C., and wherein the average size of the cluster of particles ranges from a nanometer to a millimeter.

10. The method according to claim 9 , wherein the particles comprise an additive, a filler, a pigment, a mechanical reinforcement, or a combination thereof.

11. The method according to claim 10 , wherein during the heating step, the liquid incorporated into the cluster of particles vaporizes thereby generating internal pressure to reduce the average size of the cluster of particles.

12. The method according to claim 10 , wherein the fluid immiscible with the liquid encapsulates the cluster of particles, and wherein said incorporating step includes one or more of adding the liquid to the cluster of particles, immersing the cluster of particles in the liquid or condensing the liquid into the cluster of particles from a vapor.

13. The method according to claim 9 , wherein said liquid comprises two or more different liquids.

14. The method according to claim 9 , wherein the heating step comprises utilization of convection heating, conduction heating, or microwave energy, or a combination thereof.

15. The method according to claim 8 , wherein the method further includes the step of subjecting the mixture to one or more of agitation, attrition, crushing, grinding, mixing, and ultrasonic energy.

16. The method according to claim 8 , wherein the incorporating step results in forming a continuous paste comprising the liquid and the cluster of particles.

Assignees

• Feke Donald L
• Manas Zloczower Ica
• Loos Marcio Rodrigo
• Sing Michelle
• Univ Case Western Reserve

Inventors

• Feke Donald L
• Manas Zloczower Ica
• Loos Marcio Rodrigo
• Sing Michelle

Classifications

• B02C19/186 Primary

  Use of cold or heat for disintegrating (B02C4/44, B02C7/17, B02C11/08 take precedence) · CPC title

• B01F3/1207 Primary

  Operations & Transport · mapped topic

• B01F23/51 Primary

  Methods thereof · CPC title