Method of pressure swing adsorption with regulation

Patent metadata

Field	Value
Publication number	US-9895646-B2
Application number	US-201415027209-A
Country	US
Kind code	B2
Filing date	Oct 1, 2014
Priority date	Oct 4, 2013
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

A pressure swing adsorption process for producing a gas stream enriched in a compound X from a feed gas stream is provided. The process includes at least 2 adsorbers, with each adsorber being subjected to a pressure cycle having a high pressure and a low pressure. The process includes adsorption at the high pressure with production of the gas stream enriched in compound X, depressurization to the low pressure with production of at least one portion of an elution gas, c) elution at the low pressure, and repressurization to the high pressure. The pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers. The pressure of the pressure cycle is modified to keep the phase time of the PSA equal to or within ±5% of the nominal phase time.

First claim

The invention claimed is:

1. A pressure swing adsorption (PSA) process for producing a gas stream enriched in a compound X from a feed gas stream, the process comprising at least 2 adsorbers, each adsorber being subjected to a pressure cycle having a high pressure and a low pressure and comprising the following successive steps:
a) adsorption at the high pressure with production of the gas stream enriched in compound X,
b) depressurization to the low pressure with production of at least one portion of an elution gas,
c) elution at the low pressure by means of the elution gas,
d) repressurization to the high pressure,

wherein the pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers and the pressure of the pressure cycle, located between the high pressure and the low pressure, is modified so as to keep, during at least one portion of the range of variation of the operating conditions, the phase time of the PSA equal to or within ±5% of the nominal phase time, corresponding to the phase time of the PSA under the design conditions.

2. The process of claim 1 , wherein:
the pressure cycle comprises at least 1 equalization,
the depressurization step b) comprises at least a first sub-step of co-current depressurization and at least a second sub-step of counter-current depressurization, and the modified pressure of the pressure cycle, located between the high pressure and the low pressure, is selected between the pressures at the start or end of equalization, the pressures at the start or end of production of the elution gas, and the pressure at the start of counter-current depressurization, and
the compound X is a compound that is less adsorbable than CO 2 , with the CO 2 being produced during the blowdown and/or the elution.

3. The process of claim 2 , wherein the pressure selected from the pressure cycle, located between the high pressure and the low pressure, is modified via at least one of the residual pressure differences at the end of equalization.

4. The process of claim 2 , wherein at least one of the pressures at the start or end of one at least of the steps for production of the elution gas is modified, thus changing the quantity and/or the quality of the elution gas.

5. The process of claim 1 , wherein the elution gas comprises:
a fraction of a gas stream resulting from the depressurization of an adsorber, and
a fraction of the gas stream enriched in compound X or a fraction rich in compound X originating from another unit.

6. The process of claim 1 , wherein the phase time is kept constant from one cycle to the next, during at least one portion of the range of variation of the operating conditions.

7. The process of claim 1 , wherein the pressure cycle comprises 1 to 6 equalizations.

8. The process of claim 1 , wherein the compound X is hydrogen.

9. The process of claim 1 , wherein the compound X is a compound that is less adsorbable than CO 2 , the CO 2 being produced during the blowdown and/or the elution.

Assignees

• Air Liquide
• Lair Liquide Soc Pour Letude Et Lexploitation Des Procedes Georges Claude

Inventors

• Monereau Christian
• Lemaire Yann Pierrick
• Toulemonde Louis
• Silva Paulo

Classifications

• B01D53/047 Primary

  Pressure swing adsorption · CPC title

• B01D2259/40039

  with three sub-steps · CPC title

• B01D2259/40047

  with three sub-steps · CPC title

• B01D2256/16

  Hydrogen · CPC title

• B01D2257/504

  Carbon dioxide · CPC title