Lithium secondary battery

Patent metadata

Field	Value
Publication number	US-9893350-B2
Application number	US-201414772341-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 5, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

The present invention relates to a lithium secondary battery, wherein a peak at 167 to 171 eV and a peak at 162 to 166 eV are present in XPS analysis of sulfur (S2p) of a positive electrode surface, and P169/P164 is in the range of 0.7 to 2.0 wherein the P 169/P 164 is the ratio between the intensity of the peak at 167 to 171 eV (P169) and the intensity of the peak at 162 to 166 eV (P164). The present invention can provide a lithium secondary battery having excellent cycle characteristics.

First claim

The invention claimed is:

1. A lithium secondary battery comprising: a positive electrode having a positive electrode surface, and an electrolyte solution comprising a sulfur compound, as an additive compound, selected from the group consisting of 1,3-propanesultone, 1,4-butanesultone, and methylene methane disulfonate; wherein a peak at 167 to 171 eV and a peak at 162 to 166 eV are present in XPS analysis of sulfur (S2p) of the positive electrode surface, and P169/P164 is in the range of 0.7 to 2.0, wherein the P169/P164 is the ratio between the intensity of the peak at 167 to 171 eV (P169) and the intensity of the peak at 162 to 166 eV (P164); and
wherein a positive electrode active material included in the positive electrode comprises sulfur in the range of 100 to 400 ppm.

2. A method for producing a lithium secondary battery comprising a positive electrode having a positive electrode surface, a negative electrode, and an electrolyte solution comprising a sulfur compound selected from the group consisting of 1,3-propanesultone, 1,4-butanesultone, and methylene methane disulfonate, the method comprising:
a step of producing an electrode element by arranging the positive electrode comprising a positive electrode active material comprising sulfur in the range of 100 to 400 ppm, and the negative electrode to face each other; and
a step of encapsulating the electrode element, and the electrolyte solution comprising an additive comprising the sulfur compound and a non-aqueous electrolytic solvent in an outer package, and performing charging;
whereby a peak at 167 to 171 eV and a peak at 162 to 166 eV are present in XPS analysis of sulfur (S2p) of the positive electrode surface, and P169/P164 is in the range of 0.7 to 2.0 wherein the P169/P164 is the ratio between the intensity of the peak at 167 to 171 eV (P169) and the intensity of the peak at 162 to 166 eV (P164).

3. The method of producing a lithium secondary battery according to claim 2 , wherein the charging is performed at a temperature of 39° C. or more.

Assignees

• Nec Corp

Inventors

• Iriyama Jiro

Classifications

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/366

  as layered products · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M4/5815

  Sulfides · CPC title

• H01M10/0567

  characterised by the additives · CPC title