Composition and organic optoelectric device and display device

Patent metadata

Field	Value
Publication number	US-9893290-B2
Application number	US-201314106931-A
Country	US
Kind code	B2
Filing date	Dec 16, 2013
Priority date	Jul 1, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

A composition includes a first host compound including moieties represented by Chemical Formulae 1 to 3 that are sequentially bonded with each other, and a second host compound including at least one carbazole group with a substituent having hole characteristics,

First claim

What is claimed is:

1. A composition, comprising:
a first host compound including moieties represented by the following Chemical Formulae 1 to 3 that are sequentially bonded with each other, and
a second host compound represented by the following Chemical Formula 4,

wherein, in the Chemical Formulae 1 to 3,
X 1 is *—Y 1 -ET,
X 2 is *—Y 2 —Ar 1 ,
ET is a substituent for accepting an electron when an electric field is applied,
Ar 1 is a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof,
Y 1 and Y 2 are each independently a single bond, a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C2 to C20 alkenylene group, a substituted or unsubstituted C6 to C30 arylene group, a substituted or unsubstituted C2 to C30 heteroarylene group, or a combination thereof,
L is a substituted or unsubstituted C2 or C3 alkenylene group or a substituted or unsubstituted C6 to C20 arylene group, and
R 1 to R 4 are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof,

wherein, in the Chemical Formula 4,
Ar 2 and Ar 3 are each independently an unsubstituted C6 to C30 aryl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted fluorenyl group, or a combination thereof, provided that, when Ar 2 or Ar 3 is a substituted group, the substituted group has hole characteristics,
Y 3 and Y 4 are each independently a single bond, a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C2 to C20 alkenylene group, a substituted or unsubstituted C6 to C30 arylene group, a substituted or unsubstituted C2 to C30 heteroarylene group, or a combination thereof, and
R 7 to R 11 are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof.

2. The composition as claimed in claim 1 , wherein the ET is represented by the Chemical Formula 1a:

wherein, in the Chemical Formula 1a,
each X is independently N or CR a ,
at least one of X is N, and
R a is hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof.

3. The composition as claimed in claim 1 , wherein the ET is one of the substituents listed in the following Group 1:

wherein, in the Group 1,
R 5 and R 6 are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof.

4. The composition as claimed in claim 1 , wherein the X 1 is one of the substituents listed in the following Group 2:

5. The composition as claimed in claim 1 , wherein the moiety represented by the Chemical Formula 2 is represented by one of the following Chemical Formulae 2-1 to 2-3:

6. The composition as claimed in claim 1 , wherein the Ar 1 is a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthracenyl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted benzofuranyl group, a substituted or unsubstituted benzothiophenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted dibenzothiophenyl group, a substituted or unsubstituted dibenzofuranyl group, or a combination thereof.

7. The composition as claimed in claim 1 , wherein the X 2 is one of the substituents listed in the following Group 3:

8. The composition as claimed in claim 1 , wherein the first host compound is one of compounds listed in the following Group 4:

wherein, in the Group 4,
X 1 is *—Y 1 -ET,
X 2 is *—Y 2 —Ar,
ET is a substituent for accepting an electron when an electric field is applied,
Ar 1 is a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof, and
Y 1 and Y 2 are each independently a single bond, a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C2 to C20 alkenylene group, a substituted or unsubstituted C6 to C30 arylene group, a substituted or unsubstituted C2 to C30 heteroarylene group, or a combination thereof.

9. The composition as claimed in claim 1 , wherein Ar 2 and Ar 3 are each independently an unsubstituted phenyl group, an unsubstituted biphenyl group, an unsubstituted terphenyl group, an unsubstituted naphthyl group, an unsubstituted anthracenyl A group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted fluorenyl group, or a combination thereof.

10. The composition as claimed in claim 1 , wherein:
Chemical Formula 4 is one of structures listed in the following Group 5, and
the *—Y 3 —Ar 2 and *—Y 4 —Ar 3 in Chemical Formula 4 are each independently one of substituents listed in the following Group 3,

11. The composition as claimed in claim 1 , wherein the second host compound represented by Chemical Formula 4 is one of the compounds listed in the following Tables 12 to 21, wherein, in the Tabl

Assignees

• Min Soo Hyun
• Kang Gi Wook
• Kang Dong Min
• Kang Eui Su
• Kim Youn Hwan
• Yang Yong Tak
• Oh Jae Jin
• Lee Nam Heon
• Lui Jin Hyun
• Yu Eun Sun
• Jung Ho Kuk
• Jo Young Kyoung
• Cheil Ind Inc

Inventors

• Min Soo Hyun
• Kang Gi Wook
• Kang Dong Min
• Kang Eui Su
• Kim Youn Hwan
• Yang Yong Tak
• Oh Jae Jin
• Lee Nam Heon
• Lui Jin Hyun
• Yu Eun Sun
• Jung Ho Kuk
• Jo Young Kyoung

Classifications

• H01L51/0052

  Electricity · mapped topic

• C07D487/04

  Ortho-condensed systems · CPC title

• C07D409/04

  directly linked by a ring-member-to-ring-member bond · CPC title

• H01L51/0067

  Electricity · mapped topic

• H01L51/0072

  Electricity · mapped topic