Block-type supercapacitors and fabricating method for the same, graphene oxide-metal oxide composite and synthesizing method for the composite

Patent metadata

Field	Value
Publication number	US-9892871-B2
Application number	US-201414549902-A
Country	US
Kind code	B2
Filing date	Nov 21, 2014
Priority date	Nov 11, 2014
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

Disclosed is a block supercapacitor, including two or more unit cells configured such that electrodes having a layered structure are disposed to face each other in an in-plane structure, wherein the two or more unit cells comprises an electrode arranged adjacent to each other respectively and the electrodes adjacent to each other are connected in series. As the unit cells are connected in series, a high-voltage supercapacitor can be provided.

First claim

What is claimed is:

1. A block supercapacitor, comprising:
two or more unit cells, each unit cell comprising two electrodes, the electrodes each composed of a material having a layered structure and disposed to face each other in an in-plane structure in which the layered structure of the material of each electrode is exposed on each facing surface of the two electrodes and wherein an electrolyte is filled in a space between the facing surfaces of the two electrodes, and at least one metal wall formed on a space between the two or more unit cells to confine the electrolyte filled in the space between the facing surfaces of the two electrodes within the respective unit cell;
wherein the two or more unit cells are arranged adjacent to each other respectively and are connected in series by a connector; and
wherein the material having the layered structure is configured such that graphene oxide layers are laminated into the layered structure and metal oxide nanoparticles are dispersed between the graphene oxide layers, and the metal oxide nanoparticles comprise SnO 2 or Mn 3 O 4 .

2. The block supercapacitor of claim 1 , wherein the connector comprises a metal material and is formed between the electrodes arranged adjacent to each other of the two or more unit cells.

3. The block supercapacitor of claim 1 , wherein two electrodes of each of the unit cells are separated via patterning in any one shape selected from among an interdigitated shape, a straight shape, and a zigzag shape.

4. A method of manufacturing the supercapacitor of claim 1 , comprising:
forming an electrode member composed of the material having the layered structure on a surface of a substrate, wherein the material having the layered structure is configured such that graphene oxide layers are laminated into the layered structure and metal oxide nanoparticles are dispersed between the graphene oxide layers, and the metal oxide nanoparticles comprise SnO 2 or Mn 3 O 4 ;
separating the electrode member into two or more cell members;
forming the connector comprising a metal material in a space between the cell members;
filling the space between the cell members with a metal, thus forming the metal wall;
separating each of the separated cell members into two electrodes, thus each of the cell members forming unit cells, and
placing the electrolyte between the two electrodes in each of the unit cells,
wherein the electrodes of the unit cells adjacent to each other are electrically connected in series by the connector.

5. The method of claim 4 , wherein forming the metal wall is performed using any one process selected from among thin film deposition, plating, screen printing, casting, and film/plate/block attachment.

6. The method of claim 4 , further comprising forming a polymer coating for covering the electrode member, before separating the electrode member into the cell members.

7. The method of claim 4 , further comprising forming current collectors at both sides of the electrode member, after forming the electrode member.

8. The method of claim 7 , further comprising reinforcing contact portions between the electrode member and the current collectors via metal plating.

9. The method of claim 4 , wherein forming the unit cells is performed by patterning the cell members using any one process selected from among optical patterning, mechanical patterning, chemical etching, and imprinting, thus forming two separated electrodes.

10. The method of claim 4 , further comprising chemically reducing the separated electrodes of the unit cells.

11. The method of claim 10 , wherein chemically reducing the separated electrodes is performed using any one process selected from among exposure to a reducing gas, immersion in a reducing agent-containing aqueous solution, thermal treatment, microwave treatment, and optical treatment.

12. The method of claim 4 , further comprising introducing a functional group to the separated electrodes of the unit cells to obtain a pseudocapacitive effect.

13. The method of claim 12 , wherein introducing the functional group is performed by subjecting the separated electrodes to any one process selected from among immersion in a KOH solution, plasma treatment, optical treatment, and chemical synthesis.

14. A method of preparing a composite for use in electrode of the supercapacitor of claim 1 , comprising:
preparing a graphene oxide solution;
preparing a metal oxide precursor solution;
mixing the graphene oxide solution with the metal oxide precursor solution;
filtering the mixed solution via vacuum filtration using a membrane filter; and
reducing a filtered material, thus obtaining the composite constituting the material having the layered structure;
wherein the metal oxide precursor solution is a Sn oxide precursor solution or a Mn oxide precursor solution, and
wherein the Sn oxide precursor solution is obtained by dissolving SnCl 2 .2H 2 O in HCl and the Mn oxide precursor solution comprises a MnCl 2 .4H 2 O aqueous solution and a KMnO 4 aqueous solution.

15. The method of claim 13 , wherein mixing is performed by adding the metal oxide precursor solution dropwise to the graphene oxide solution.

Assignees

• Korea Inst Energy Res

Inventors

• Yoo Jung Joon
• Lee Chan Woo

Classifications

• H01G11/30

  characterised by their material · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01G11/26

  characterised by their structure, e.g. multi-layered, porosity or surface features · CPC title

• H01G11/36

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01G11/86 Primary

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title