Ultraviolet-curable liquid developer

Patent metadata

Field	Value
Publication number	US-9891546-B2
Application number	US-201615166614-A
Country	US
Kind code	B2
Filing date	May 27, 2016
Priority date	May 27, 2015
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

An ultraviolet-curable liquid developer containing a cationically polymerizable liquid monomer, a photoinitiator according to formula (1), and a toner particle.

In the developer the cationically polymerizable liquid monomer contains a vinyl ether compound, the molar average SP value of the cationically polymerizable liquid monomer is not more than 9.0, the molar average number of functional groups for the cationically polymerizable liquid monomer is at least 1.8, the photoinitiator contains a specified compound, and the content of the specified compound is at least 0.01 mass parts and not more than 5.00 mass parts per 100 mass parts of the cationically polymerizable liquid monomer.

First claim

What is claimed is:

1. An ultraviolet-curable liquid developer comprising;
a toner particle containing a binder resin and a colorant;
a cationically polymerizable liquid monomer which does not dissolve the binder resin in the toner particle; and
a photoinitiator, wherein
the cationically polymerizable liquid monomer contains a vinyl ether compound,
a molar average SP value of the cationically polymerizable liquid monomer is not more than 9.0,
a molar average number of functional groups for the cationically polymerizable liquid monomer is at least 1.8, and
the photoinitiator contains a compound represented by formula (1), a content of the compound represented by formula (1) being 0.01 to 5.00 mass parts per 100 mass parts of the cationically polymerizable liquid monomer,

wherein, R 1 and R 2 are bonded to each other to form a ring structure selected from the group consisting of a succinimide structure, a phthalimide structure, a norbornenedicarboximide structure, a naphthalenedicarboximide structure, a cyclohexanedicarboximide structure, and an epoxycyclohexenedicarboximide structure; x is an integer that of 1 to 8; and y is an integer of 3 to 17.

2. The ultraviolet-curable liquid developer according to claim 1 , wherein the content of the compound represented by formula (1) is 0.05 to 1.00 mass part per 100 mass parts of the cationically polymerizable liquid monomer.

3. The ultraviolet-curable liquid developer according to claim 1 , wherein the cationically polymerizable liquid monomer consists of said cationically polymerizable liquid monomer that has an SP value of not more than 9.0.

4. The ultraviolet-curable liquid developer according to claim 1 , wherein the cationically polymerizable liquid monomer consists of a cationically polymerizable liquid monomer that has at least two polymerizable functional groups per one molecule.

5. The ultraviolet-curable liquid developer according to claim 1 , wherein the compound represented by formula (1) is a compound represented by formula (2)

wherein x represents an integer of 1 to 8; y represents an integer of 3 to 17; R 3 and R 4 each independently represent an alkyl group, an alkyloxy group, an alkylthio group, an aryl group, an aryloxy group, or an arylthio group; o and p each independently represent an integer of 0 to 3 with the proviso that when o is equal to or greater than 2, a plurality of R 3 may be bonded to each other to form a ring structure, and when p is equal to or greater than 2, a plurality of R 4 may be bonded to each other to form a ring structure; and R 3 and R 4 may be bonded to each other to form a ring structure.

6. The ultraviolet-curable liquid developer according to claim 1 , further comprising a photopolymerization sensitizer containing a thioxanthone compound or an anthracene compound.

7. The ultraviolet-curable liquid developer according to claim 6 , further comprising a photopolymerization sensitizing aid containing a naphthalene compound.

Assignees

• Canon Kk

Inventors

• Ito Junji
• Aichi Yasuhiro
• Sato Naotake
• Tanabe Hiroshi

Classifications

• G03G9/125

  characterised by the liquid · CPC title

• G03G9/12

  in liquid developer mixtures · CPC title

• G03G9/131 Primary

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title