Coated optical fiber

Patent metadata

Field	Value
Publication number	US-9891381-B2
Application number	US-201414397983-A
Country	US
Kind code	B2
Filing date	Apr 10, 2014
Priority date	Apr 12, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

Provided is a coated optical fiber excellent in both characteristics of the microbending loss resistance and the low-temperature characteristic. The coated optical fiber 1 comprises an optical fiber 10 that has a cladding layer composed of glass formed on an outer periphery of a glass core, a primary coating layer 20 that coats an outer periphery of the optical fiber 10 , and a secondary coating layer 30 that coats an outer periphery of the primary coating layer 20 , wherein the primary coating layer 20 has a Young's modulus of 1.2 MPa or less, the secondary coating layer 30 has a Young's modulus of 700 MPa or more, and the primary coating layer 20 contains tin in a content of 70 ppm or less.

First claim

The invention claimed is:

1. A coated optical fiber comprising an optical fiber that has a cladding layer composed of glass formed on an outer periphery of a glass core, a primary coating layer that coats an outer periphery of the optical fiber, and a secondary coating layer that coats an outer periphery of the primary coating layer,
wherein the primary coating layer has a Young's modulus of 1.2 MPa or less, the secondary coating layer has a Young's modulus of 700 MPa or more, and the primary coating layer contains tin in a content of 10 ppm or more and 70 ppm or less and
wherein the primary coating layer is formed from an ultraviolet ray-curable resin composition containing an acylphosphine oxide-based photopolymerization reaction initiator but not a bisacylphosphine oxide-series photopolymerization initiator.

2. The coated optical fiber according to claim 1 , wherein the total tin content in the primary coating layer and the secondary coating layer is 10 ppm or more and 70 ppm or less.

3. The coated optical fiber according to claim 1 , wherein the tin content in the primary coating layer is 10 ppm or more and 50 ppm or less.

4. The coated optical fiber according to claim 3 , wherein the total tin content in the primary coating layer and the secondary coating layer is 10 ppm or more and 50 ppm or less.

5. The coated optical fiber according to claim 1 , wherein the Young's modulus of the primary coating layer is 1.0 MPa or less and the Young's modulus of the secondary coating layer is 800 MPa or more.

6. The coated optical fiber according to claim 1 , wherein the Young's modulus of the primary coating layer is 0.80 MPa or less and the Young's modulus of the secondary coating layer is 900 MPa or more.

7. The coated optical fiber according to claim 1 , wherein the coating layer contains an unreacted acylphosphine oxide-based photopolymerization reaction initiator in an amount of 0.5% by mass or less.

8. The coated optical fiber according to claim 1 , wherein the primary coating layer is formed from an ultraviolet ray-curable coating agent containing:
(A) a (meth)acryloyl group-containing urethane oligomer obtained by reacting an aliphatic polyol, an organic polyisocyanate, a hydroxyl group-containing (meth)acrylate, and a γ-mercaptopropyltrimethoxysilane;
(B) a reactive diluent; and
(C) a photopolymerization reaction initiator.

9. The coated optical fiber according to claim 1 , wherein the primary coating layer is formed from an ultraviolet ray-curable coating agent containing:
(A) a (meth)acryloyl group-containing urethane oligomer obtained by reacting an aliphatic polyol having a molecular weight of 3,500 or less, an organic polyisocyanate, a hydroxyl group-containing (meth)acrylate, and a γ-mercaptopropyltrimethoxysilane;
(B) at least one kind of a reactive diluent having a glass transition temperature of 0° C. or lower at the time of polymerization as a single substance; and
(C) a photopolymerization reaction initiator.

10. The coated optical fiber according to claim 1 , wherein a difference in the transmission loss at a wavelength of 1550 nm between those stored at a temperature of −60° C. and at a temperature of 25° C. at a relative humidity of 85% for 120 days is 0.03 dB/km or less.

11. The coated optical fiber according to claim 1 , wherein the photopolymerization reaction initiator is 2,4,6-trimethylbenzoyldiphenylphosphine oxide.

Assignees

• Sumitomo Electric Industries

Inventors

• Iwaguchi Noriaki
• Iida Masuo
• Tachibana Kumiko
• Takada Takashi
• Fujii Takashi

Classifications

• G02B6/03694 Primary

  Multiple layers differing in properties other than the refractive index, e.g. attenuation, diffusion, stress properties · CPC title

• G02B6/02395

  Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104) · CPC title

• C03C25/285

  Acrylic resins · CPC title

• C03C25/326

  Polyureas; Polyurethanes · CPC title

• C03C25/1065

  Multiple coatings · CPC title