Seal between two elements having different coefficients of thermal expansion

Patent metadata

Field	Value
Publication number	US-9890860-B2
Application number	US-201013501627-A
Country	US
Kind code	B2
Filing date	Oct 18, 2010
Priority date	Oct 20, 2009
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

The disclosure relates to a seal inserted between two elements having different coefficients of thermal expansion, the seal includes a first and a second metallic contact portion spaced along an axial stacking direction orthogonal with respect to a radial direction. Tight connection means between the first and second contact portions allow a relative movement between the first and second contact portions along the radial direction. A first and a second sliding part are respectively coupled in translation along the radial direction with the first and second contact portions and are stacked so as to be able to slide in relation to each other along the radial direction.

First claim

The invention claimed is:

1. A system comprising:
at least one electrochemical cell comprising an electrolyte arranged between an anode and a cathode, the at least one electrochemical cell further comprising an anodic interconnector and a cathodic interconnector connected to the anode and the cathode;
a first seal that contacts and is inserted between the electrolyte and the anodic interconnector; and
a second seal that contacts and is inserted between the electrolyte and the cathodic interconnector,
wherein the first seal and the second seal each comprise:
a first metallic contact portion and a second metallic contact portion each of which is spaced along an axial stacking direction;
tight connection means connecting the first metallic contact portion to the second metallic contact portion, the tight connection means allowing a relative movement between the first metallic contact portion and the second metallic contact portion along a radial direction of the seal; and
a first sliding part and a second sliding part arranged along the axial stacking direction between the first metallic contact portion and the second metallic contact portion, wherein the first sliding part and the second sliding part are respectively coupled in translation along the radial direction with the first metallic contact portion and the second metallic contact portion, and wherein the first sliding part and the second sliding part are configured to slide in relation to each other along the radial direction,

wherein the electrolyte has a different coefficient of thermal expansion than the anodic interconnector and the cathodic interconnector,
wherein, with respect to the first seal, a corresponding first sliding part has a coefficient of thermal expansion that is similar or identical to a coefficient of thermal expansion of the anodic interconnector, and a corresponding second sliding part has a coefficient of thermal expansion that is similar or identical to a coefficient of thermal expansion of the electrolyte,
wherein, with respect to the second seal, a corresponding other first sliding part has a coefficient of thermal expansion that is similar or identical to a coefficient of thermal expansion of the cathodic interconnector, and a corresponding other second sliding part has a coefficient of thermal expansion that is similar or identical to the coefficient of thermal expansion of the electrolyte.

2. The system according to claim 1 , wherein the first sliding part and the second sliding part are in contact with each other.

3. The system according to claim 1 , wherein each of the first metallic contact portion and the second metallic contact portion comprises a corresponding at least one tight contact member, each of the corresponding at least one tight contact members projecting in the axial stacking direction towards an outside of the seal, and wherein each of the first metallic contact portion and the second metallic contact portion comprises a corresponding at least one translational coupling member, each of the corresponding at least one translational coupling members projecting in the axial stacking direction towards an inside of the seal, wherein each of the corresponding at least one translational coupling members is housed in a complementary orifice produced in a corresponding one of the first sliding part and the second sliding part.

4. The system according to claim 1 , wherein the first metallic contact portion and the second metallic contact portion are made of an alloy comprising iron, chromium, and aluminum.

5. The system according to claim 1 , wherein the first sliding part is made of an alloy comprising Ni in a proportion of at least 72%, Cr in a proportion between 14% and 17%, and Fe in a proportion between 6% and 10%.

6. The system according to claim 1 , wherein the second sliding part is made of yttria-stabilised zirconia.

7. The system according to claim 1 , wherein the tight connection means is made of a same material as the first metallic contact portion and the second metallic contact portion.

8. The system according to claim 1 , wherein a ratio between a thickness of the first sliding part and a thickness of the first metallic contact portion is between 2 and 5, and wherein a ratio between a thickness of the second sliding part and a thickness of the second metallic contact portion is between 2 and 5.

9. The system according to claim 1 , wherein the anodic interconnector and the cathodic interconnector are metallic and wherein the electrolyte is ceramic.

10. The system according to claim 1 , wherein the at least one electrochemical cell is a high-temperature electrolyser or a high-temperature fuel cell.

Assignees

• Reytier Magali
• Besson Jacques
• Bruguiere Lionel
• JULIAA Jean François
• Commissariat Energie Atomique
• Technetics Group France Sas

Inventors

• Reytier Magali
• Besson Jacques
• Bruguiere Lionel
• JULIAA Jean François

Classifications

• H01M8/0271

  Sealing or supporting means around electrodes, matrices or membranes · CPC title

• H01M8/0282

  Inorganic material · CPC title

• H01M8/0276

  Sealing means characterised by their form (H01M8/0273 takes precedence) · CPC title

• Y10S277/936

  Composite · CPC title

• C25B9/00

  Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features · CPC title