Method of preparing a metal matrix nanocomposite

Patent metadata

Field	Value
Publication number	US-9890442-B1
Application number	US-201715462459-A
Country	US
Kind code	B1
Filing date	Mar 17, 2017
Priority date	Mar 17, 2017
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

A method for synthesizing a metal matrix nanocomposite (MMNC) is an in-situ synthesis technique for preparing a metal matrix with ceramic reinforcements dispersed homogenously therein. The method includes mixing a base metal matrix material with two or more ceramic-forming elements to form a mixture; blending the mixture; drying the mixture; ball milling the mixture with a plurality of milling balls to form a milled mixture; using induction heating to form a melt flow and induce electromagnetic forces; and initiating a plurality of stirring vortexes in the melt flow to form the metal matrix nanocomposite.

First claim

We claim:

1. An in-situ method for synthesizing a metal matrix nanocomposite with ceramic reinforcements dispersed homogeneously therein, the method consisting of:
mixing a base metal matrix material with two or more distinct ceramic-forming elements in a degassed organic solvent to form a mixture;
blending the mixture, wherein the mixture is blended under ultrasonic conditions at a temperature of about 35° C.;
drying the mixture to remove the organic solvent;
ball-milling the mixture in a ball milling container using a plurality of milling balls to form a milled mixture;
using induction heating to form a melt flow from the milled mixture and to induce electromagnetic forces; and
initiating a plurality of stirring vortexes in the melt flow to produce the ceramic reinforcements in situ to form the metal matrix nanocomposite, wherein the stirring is initiated by electromagnetic forces induced by the induction heating.

2. The method for synthesizing a metal matrix nanocomposite according to claim 1 , wherein the electromagnetic forces include Lorentz forces.

3. The method for synthesizing a metal matrix nanocomposite according to claim 1 , wherein the step of drying the mixture occurs at a temperature of about 50° C. under vacuum for about 12 hours to evaporate the organic solvent.

4. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein melting of the mixture occurs at temperatures ranging from about 1300° C. to 1500° C., for a time period of about three minutes to about six minutes.

5. The method of synthesizing metal matrix nanocomposite according to claim 1 , wherein the organic solvent is acetone.

6. The method of synthesizing metal matrix nanocomposite according to claim 1 , wherein the base metal matrix is selected from the group consisting of Al, Mg and Zn.

7. The method of synthesizing metal matrix nanocomposite materials according to claim 1 , wherein the two or more ceramic-forming elements are selected from the group consisting of C, Zr, B, W, Si, Ti, and combinations thereof.

8. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein the ceramic-forming elements react within the base metal in-situ to form a ceramic reinforcement compound comprising at least one of TiC, TiB 2 , ZrC, ZrB 2 , WC, SiC, and B 4 C.

9. The method of synthesizing metal matrix nanocomposite according to claim 1 , wherein the plurality of milling balls include at least one of steel balls and tungsten carbide balls.

10. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein the ball milling is operated at a rotation speed of at least 1000 rotations per minute for at least one hour in at least two different axes directions.

11. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein the plurality of milling balls include a first plurality of balls having a first size, a second plurality of balls having a second size, and a third plurality of balls having a third size, the first size, second and third sizes being different.

12. The method of synthesizing metal matrix nanocomposite according to claim 11 , wherein the first plurality of balls are about 10 mm in diameter, the second plurality of balls are about 6 mm in diameter, and the third plurality of balls are 3 mm in diameter.

13. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein the ball milling container includes a stainless steel jar with a capacity of about 80 ml.

14. The method of synthesizing a metal matrix nanocomposite according to claim 1 , wherein a ball to mixture weight ratio in the ball milling container is about 10:1.

Assignees

• Univ King Saud

Inventors

• Nabawy Ahmed Mohammed Nabawy
• Sherif El Sayed M
• Khalil Khalil Abdelrazek

Classifications

• C22C1/10

  Alloys containing non-metals (C22C1/05, C22C1/08 take precedence) · CPC title

• C22C32/0073

  only borides · CPC title

• C22C32/0052

  only carbides · CPC title

• C22C32/0047

  with carbides, nitrides, borides or silicides as the main non-metallic constituents · CPC title

• C22C1/1068 Primary

  Making hard metals based on borides, carbides, nitrides, oxides or silicides · CPC title