One-step production of long-chain hydrocarbons from waste-biomass-derived chemicals

Patent metadata

Field	Value
Publication number	US-9890342-B2
Application number	US-201414580450-A
Country	US
Kind code	B2
Filing date	Dec 23, 2014
Priority date	Dec 23, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

Methods for deriving a high-C hydrocarbon fuel from an organic source feedstock are provided. The method can include: contacting a mixture of the organic source feedstock and an aldehyde with a catalytic material to produce a product stream comprising a high-C hydrocarbon fuel, and separating the high-C hydrocarbon fuel in the product stream from any remaining organic source feedstock or aldehyde. The catalytic material comprises a metal and a zeolite.

First claim

What is claimed:

1. A method for deriving a high-C hydrocarbon fuel from an organic source feedstock, the method comprising:
contacting a mixture of the organic source feedstock and an aldehyde with a catalytic material to produce a product stream comprising a high-C hydrocarbon fuel, wherein the catalytic material comprises a metal and a zeolite, wherein the catalytic material comprises the metal in a weight percent of about 0.01% to about 10% of the total weight of the catalytic material; and
separating the high-C hydrocarbon fuel in the product stream from any remaining organic source feedstock or aldehyde.

2. The method as in claim 1 , wherein the organic source feedstock comprises C 5 to C 6 molecules.

3. The method as in claim 1 , wherein the organic source feedstock comprises at least about 50% by weight of C 5 to C 6 molecules.

4. The method as in claim 1 , wherein the organic source feedstock comprises at least about 75% by weight of C 5 to C 6 molecules.

5. The method as in claim 1 , wherein the organic source feed stock comprises a furfural, a furfural derivatives, levulinic acid, derivatives of levulinic acid or mixtures thereof.

6. The method as in claim 1 , wherein the organic source feed stock comprises 2-furaldehyde, 5-hydroxymethylfurfural, furfuryl alcohol, methylfuran, tetrahydrofurfuryl alcohol, hydroxylmethylfurfural, 2-methlyhydrofuran, 2-methyltetrahydrofuran, tetrahydrofuran-5-dimethanol, furoic acid, 1,5-pentanediol, 1,2-pentanediol, 1,4-pentanediol, or mixtures thereof.

7. The method as in claim 1 , wherein the aldehyde comprises an aldehyde functional group attached to an organic group.

8. The method as in claim 7 , wherein the organic group comprises an alkyl chain, an alkyne chain, or an aromatic group.

9. The method as in claim 1 , wherein the aldehyde comprises formaldehyde, acetaldehyde, propionaldehyde, butraldehyde, a derivative of butanal, benzaldehyde, a benzaldehyde derivative, cinnamaldehyde, tolualdehyde, furfural, retinaldehyde, a carbohydrate, or derivatives thereof.

10. The method as in claim 1 , wherein the aldehyde comprises 2-methylbutanal.

11. The method as in claim 1 , wherein the metal of the catalytic material is deposited on a solid acid support.

12. The method as in claim 11 , wherein the solid acid support comprises a mesostructured silicate.

13. The method as in claim 11 , wherein the solid acid support comprises a mesostructured aluminosilicate.

14. The method as in claim 1 , wherein the metal of the catalytic material comprises Ce, Cu, Eu, Fe, Ga, Gd, In, Ir, La, Nd, Ni, Pd, Pr, Pt, Rh, Ru, Sm, Zn, Zr, or mixtures thereof.

15. The method as in claim 1 , wherein the metal of the catalytic material comprises Cu, Ni, Pd, Pt, or mixtures thereof.

16. The method as in claim 1 , wherein the catalytic material comprises the metal in a weight percent of about 0.05% to about 5% of the total weight of the catalytic material.

17. The method as in claim 1 , wherein the catalytic material comprises the metal in a weight percent of about 0.1% to about 2.5% of the total weight of the catalytic material.

18. The method as in claim 1 , wherein the mixture of the organic source feedstock and the aldehyde is contacted with the catalytic material as a gas.

19. The method as in claim 1 , wherein the mixture of the organic source feedstock and the aldehyde is contacted with the catalytic material at a reaction temperature of about 190° C. to about 350° C.

20. The method as in claim 1 , further comprising:
prior to contacting the mixture of the organic source feedstock and the aldehyde with the catalytic material, heating the mixture of the organic source feedstock and the aldehyde to a gaseous state.

21. The method as in claim 20 , wherein the mixture of the organic source feedstock and the aldehyde is heated to a reaction temperature of about 190° C. to about 350° C.

22. The method as in claim 1 , wherein separating the high-C hydrocarbon fuel in the product stream from any remaining organic source feedstock or aldehyde comprises: passing the product stream through a condenser to liquefy the high-C hydrocarbon fuel.

23. The method as in claim 22 , wherein the condenser has a condensing temperature of about −10° C. to about 20° C.

24. The method as in claim 1 , wherein the mixture of the organic source feedstock and the aldehyde is contacted with the catalytic material within a reactor.

25. The method as in claim 24 , wherein the mixture of the organic source feedstock and the aldehyde is introduced into the reactor as a continuous inflow stream.

26. The method as in claim 24 , wherein the aldehyde is introduced into the reactor as a continuous inflow stream.

27. The method as in claim 24 , wherein a continuous outflow of the product stream exits the reactor.

Assignees

• Lauterbach Jochen
• Hattrick Simpers Jason R
• Wen Cun
• Univ South Carolina

Inventors

• Lauterbach Jochen
• Hattrick Simpers Jason R
• Wen Cun

Classifications

• Y02P30/20

  using bio-feedstock · CPC title

• B01J29/043

  Noble metals · CPC title

• C10L1/06 Primary

  for spark ignition · CPC title

• C10L2270/02

  for internal combustion engines · CPC title

• C10G3/49

  containing crystalline aluminosilicates, e.g. molecular sieves · CPC title