Aliphatic polyester resin composition and aliphatic polyester resin molded article

Patent metadata

Field	Value
Publication number	US-9890279-B2
Application number	US-201415107687-A
Country	US
Kind code	B2
Filing date	Dec 4, 2014
Priority date	Dec 24, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

An object is to improve slow crystallization that is a drawback of polyhydroxyalkanoates, improve processability in mold processing, such as injection molding, improve processing speed, and suppress blooming from a obtaining molded article. Provided is an aliphatic polyester resin composition including a polyhydroxyalkanoate (A), a vinyl acetate-containing copolymer (B), and pentaerythritol (C), wherein the polyhydroxyalkanoate (A) and the vinyl acetate-containing copolymer (B) are immiscible.

First claim

The invention claimed is:

1. An aliphatic polyester resin composition, comprising:
a polyhydroxyalkanoate selected from the group consisting of poly(3-hydroxybutyrate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-4-hydroxybutyrate), and a combination thereof;
a vinyl acetate-containing copolymer; and
pentaerythritol,
wherein the polyhydroxyalkanoate and the vinyl acetate-containing copolymer are immiscible, and
the vinyl acetate-containing copolymer is included in an amount of from 0.5 to 5 parts by weight, and the pentaerythritol is included in an amount of from 0.05 to 20 parts by weight, with respect to 100 parts by weight of the polyhydroxyalkanoate.

2. The aliphatic polyester resin composition according to claim 1 , comprising from 0.7 to 3 parts by weight of the vinyl acetate-containing copolymer and from 0.5 to 8 parts by weight of the pentaerythritol with respect to 100 parts by weight of the polyhydroxyalkanoate.

3. The aliphatic polyester resin composition according to claim 1 , wherein the vinyl acetate-containing copolymer is an ethylene-vinyl acetate copolymer.

4. The aliphatic polyester resin composition according to claim 3 , wherein the ethylene-vinyl acetate copolymer has a vinyl acetate content of from 30 to 60 wt %.

5. The aliphatic polyester resin composition according to claim 1 , wherein the vinyl acetate-containing copolymer is an ethylene-vinyl acetate-carbon monoxide terpolymer.

6. The aliphatic polyester resin composition according to claim 5 , wherein the ethylene-vinyl acetate-carbon monoxide terpolymer has a vinyl acetate content of from 20 to 40 wt % and a carbon monoxide content of from 5 to 20 wt %.

7. An aliphatic polyester resin molded article, produced by molding the aliphatic polyester resin composition according to claim 1 .

8. The aliphatic polyester resin composition according to claim 2 , wherein the vinyl acetate-containing copolymer is an ethylene-vinyl acetate copolymer having a vinyl acetate content of from 30 to 60 wt %, or an ethylene-vinyl acetate-carbon monoxide terpolymer having a vinyl acetate content of from 20 to 40 wt % and a carbon monoxide content of from 5 to 20 wt %.

9. The aliphatic polyester resin composition according to claim 2 ,
wherein the vinyl acetate-containing copolymer is an ethylene-vinyl acetate copolymer having a vinyl acetate content of from 33 to 50 wt %, or an ethylene-vinyl acetate-carbon monoxide terpolymer having a vinyl acetate content of from 24 to 28.5 wt % and a carbon monoxide content of from 9 to 10 wt %.

10. The aliphatic polyester resin composition according to claim 1 , wherein the aliphatic polyester resin composition comprises from 0.7 to 5 parts by weight of the vinyl acetate-containing copolymer and from 0.1 to 10 parts by weight of the pentaerythritol with respect to 100 parts by weight of the polyhydroxyalkanoate.

11. The aliphatic polyester resin composition according to claim 1 , wherein the poly(3-hydroxybutyrate-co-3-hydroxyvalerate), the poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), the poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), and the poly(3-hydroxybutyrate-co-4-hydroxybutyrate) comprise 80 mol % or more of 3-hydroxybutyrate.

12. The aliphatic polyester resin composition according to claim 1 , wherein the polyhydroxyalkanoate has a weight-average molecular weight of from 200,000 to 2,500,000.

13. The aliphatic polyester resin composition according to claim 1 , further comprising:
at least one additive selected from the group consisting of a lubricant, a crystal nucleating agent other than the pentaerythritol, a plasticizer, a hydrolysis inhibitor, an antioxidant, a releasing agent, an ultraviolet absorber, a coloring agent, an inorganic filler, an organic filler, an inorganic fiber, an organic fiber, and a natural fiber.

14. The aliphatic polyester resin composition according to claim 1 , wherein the polyhydroxyalkanoate is at least one of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) comprising 80 mol % or more of 3-hydroxybutyrate and 20 mol % or less of 3-hydroxyhexanoate, and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) comprising 80 mol % or more of 3-hydroxybutyrate and 20 mol % or less of 4-hydroxybutyrate.

15. The aliphatic polyester resin composition according to claim 2 , wherein the poly(3-hydroxybutyrate-co-3-hydroxyvalerate), the poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), the poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), and the poly(3-hydroxybutyrate-co-4-hydroxybutyrate) comprise 80 mol % or more of 3-hydroxybutyrate.

16. The aliphatic polyester resin composition according to claim 1 , wherein the vinyl acetate-containing copolymer is an ethylene-vinyl acetate copolymer having a vinyl acetate content of from 30 to 60 wt %, or an ethylene-vinyl acetate-carbon monoxide terpolymer having a vinyl acetate content of from 20 to 40 wt % and a carbon monoxide content of from 5 to 20 wt %.

17. The aliphatic polyester resin composition according to claim 14 , wherein the vinyl acetate-containing copolymer is included in an amount of from 0.7 to 3 parts by weight, and the pentaerythritol is included in an amount of from 0.5 to 8 parts by weight, with respect to 100 parts by weight of the polyhydroxyalkanoate.

18. The aliphatic polyester resin composition according to claim 1 , wherein the polyhydroxyalkanoate has a weight-average molecular weight of from 250,000 to 2,000,000.

19. The aliphatic polyester resin composition according to claim 1 , wherein the polyhydroxyalkanoate has a weight-average molecular weight of from 300,000 to 1,000,000.

20. The aliphatic polyester resin composition according to claim 1 , wherein the polyhydroxyalkanoate is poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) or poly(3-hydroxybutyrate-co-4-hydroxybutyrate) comprising 86 to 94.4 mol % of 3-hydroxybutyrate.

Assignees

• Kaneka Corp

Inventors

• Minami Tetsuya
• Suzuki Noriyuki

Classifications

• C08L2205/24

  Crystallisation aids · CPC title

• C08L2205/06

  having improved processability or containing aids for moulding methods · CPC title

• C08L2201/06

  Biodegradable · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C08L67/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title