Rubber composition for tire and pneumatic tire

Patent metadata

Field	Value
Publication number	US-9890271-B2
Application number	US-201414277279-A
Country	US
Kind code	B2
Filing date	May 14, 2014
Priority date	Jul 8, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

A rubber composition for a tire includes a rubber component, aluminum hydroxide particles having an average particle diameter in a range of 1.5 μm or smaller and a nitrogen adsorption specific surface area of 3˜60 m 2 /g, and wet silica. The aluminum hydroxide particles are in an amount of 1˜60 parts by mass relative to 100 parts by mass of the rubber component, and the rubber composition is obtained by a process including kneading at least the rubber component and the aluminum hydroxide particles at a discharge temperature in a range of 150° C. or higher.

First claim

What is claimed is:

1. A rubber composition for a tire, comprising:
a rubber component;
a plurality of aluminum hydroxide particles having an average particle diameter in a range of 1.5 μm or smaller and a nitrogen adsorption specific surface area in a range of 4.0 to 55 m 2 /g;
a silane coupling agent;
a wet silica; and
a carbon black,
wherein the aluminum hydroxide particles are in an amount in a range of 1 to 50 parts by mass relative to 100 parts by mass of the rubber component, the aluminum hydroxide particles, the wet silica, and the carbon black are in a total amount in a range of 85 to 140 parts by mass relative to 100 parts by mass of the rubber component, and the rubber composition is an unvulcanized rubber composition obtained by a process including kneading a mixture comprising the rubber component and the aluminum hydroxide particles and excluding sulfur and a vulcanization accelerator at a discharge temperature in a range of 155° C. or higher.

2. A rubber composition for a tire according to claim 1 , wherein the aluminum hydroxide particles have an average particle diameter in a range of 0.69 μm or smaller and a nitrogen adsorption specific surface area in a range of 4.0 to 50 m 2 /g, and the wet silica has a nitrogen adsorption specific surface area in a range of 80 to 300 m 2 /g, and is in an amount set in a range of 15 to 130 parts by mass relative to 100 parts by mass of the rubber component.

3. A rubber composition for a tire according to claim 2 , wherein the rubber composition has a Mooney viscosity, ML 1+4 , in a range of 50 or higher at 130° C. and satisfies an equation, 1.0×(an amount of a process oil in liquid phase at room temperature)+0.6×(an amount of resin having a softening point of lower than 51° C.)+0.4×(an amount of resin having a softening point in a range of 51 to 140° C.)≦35, where the amount of the process oil and the amounts of the resin represent parts by mass relative to 100 parts by mass of the rubber component, and the process oil is in liquid phase at room temperature.

4. A rubber composition for a tire according to claim 2 , wherein the silane coupling agent is in an amount in a range of 0.1 to 20 parts by mass relative to 100 parts by mass of the rubber component, and the silane coupling agent has formula, (C p H 2p+1 O) 3 Si—C q H 2q —S—CO—C k H 2k+1 , where p is a whole number in a range of 1 to 3, q is a whole number in a range of 1 to 5, and k is a whole number in a range of 5 to 12.

5. A rubber composition for a tire according to claim 1 , wherein the rubber composition has a Mooney viscosity, ML 1+4 , in a range of 50 or higher at 130° C. and satisfies an equation, 1.0×(an amount of a process oil in liquid phase at room temperature)+0.6×(an amount of resin having a softening point of lower than 51° C.)+0.4×(an amount of resin having a softening point in a range of 51 to 140° C.)≦35, where the amount of the process oil and the amounts of the resin represent parts by mass relative to 100 parts by mass of the rubber component, and the process oil is in liquid phase at room temperature.

6. A rubber composition for a tire according to claim 5 , wherein the silane coupling agent is in an amount in a range of 0.1 to 20 parts by mass relative to 100 parts by mass of the rubber component, and the silane coupling agent has formula, (C p H 2p+1 O) 3 Si—C q H 2q —S—CO—C k H 2k+1 , where p is a whole number in a range of 1 to 3, q is a whole number in a range of 1 to 5, and k is a whole number in a range of 5 to 12.

7. A rubber composition for a tire according to claim 1 , wherein the discharge temperature is set in a range of 155° C. to 190° C.

8. A rubber composition for a tire according to claim 7 , wherein the silane coupling agent is in an amount in a range of 0.1 to 20 parts by mass relative to 100 parts by mass of the rubber component, and the silane coupling agent has formula, (C p H 2p+1 O) 3 Si—C q H 2q —S—CO—C k H 2k+1 , where p is a whole number in a range of 1 to 3, q is a whole number in a range of 1 to 5, and k is a whole number in a range of 5 to 12.

9. A rubber composition for a tire according to claim 1 , wherein the silane coupling agent is in an amount in a range of 0.1 to 20 parts by mass relative to 100 parts by mass of the rubber component, and the silane coupling agent has formula, (C p H 2p+1 O) 3 Si—C q H 2q —S—CO—C k H 2k+1 , where p is a whole number in a range of 1 to 3, q is a whole number in a range of 1 to 5, and k is a whole number in a range of 5 to 12.

10. A rubber composition for a tire according to claim 1 , wherein the discharge temperature is set in a range of 160° C. to 190° C.

11. A rubber composition for a tire according to claim 1 , wherein the discharge temperature is set in a range of 170° C. to 185° C.

12. A tire tread, comprising:
the rubber composition of claim 1 .

13. A pneumatic tire, comprising:
a tread comprising the rubber composition of claim 1 .

14. A pneumatic tire, comprising:
a tread comprising the rubber composition of claim 2 .

15. A method for producing a rubber composition for a tire, comprising:
combining a rubber component and a plurality of aluminum hydroxide particles having an average particle diameter in a range of 1.5 μm or smaller and a nitrogen adsorption specific surface area in a range of 4.0 to 55 m 2 /g; and
kneading a mixture comprising the rubber component and the aluminum hydroxide particles and excluding sulfur and a vulcanizing accelerator at a discharge temperature in a range of 155° C. or higher such that an unvulcanized rubber composition is obtained,
wherein the unvulcanized rubber composition includes the rubber component, the aluminum hydroxide particles, a silane coupling agent, a wet silica, and a carbon black, the aluminum hydroxide particles are in an amount in a range of 1 to 50 parts by mass relative to 100 parts by mass of the rubber component, and the aluminum hydroxide particles, the wet silica, and the carbon black are in a total amount in a range of 85 to 140 parts by mass relative to 100 parts by mass of the rubber component.

16. A method for producing a rubber composition for a tire according to claim 15 , wherein the aluminum hydroxide particles have an average particle diameter in a range of 0.69 μm or smaller and a nitrogen adsorption specific surface area in a range of 4.0 to 50 m 2 /g, and the wet silica has a nitrogen adsorption specific surface area in a range of 80 to 300 m 2 /g, and is in an amount set in a range of 15 to 130 parts by mass relative to 100 parts by mass of the rubber component.

17. A method for producing a rubber composition for a tire according to claim 15 , wherein the rubber composition has a Mooney viscosity, ML 1+4 , in a range of 50 or higher at 130° C. and satisfies an equation, 1.0×(an amount of a process oil in liquid phase at room temperature)+0.6×(an amount of resin having a softening point of lower than 51° C.)+0.4×(an amount of resin having a softening point in a range of 51 to 140° C.)≦35, where the amount of the process oil and the amounts of the resin represent parts by mass relative to 100 parts by mass of the rubber component, and the process oil is in liquid phase at room temperature.

18. A method for producing a rubber composition for a tire according to claim 15 , wherein the discharge temperature is set in a range of 155° C. to 190° C.

19. A method for producing a rubber composition for a tire according to claim 15 , wherein the silane coupling agent is in an amount in a range of 0.1 to 20 parts by mass relative to 100 parts by mass of the rubber component

Assignees

• Sumitomo Rubber Ind

Inventors

• Miyazaki Tatsuya

Classifications

• B60C1/0016

  Compositions of the tread · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08K5/548

  containing sulfur {(C08K5/5477 takes precedence)} · CPC title

• C08K3/06

  Sulfur · CPC title

• C08L91/06

  Waxes · CPC title